Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

Mid-ultraviolet and optical photometry of helium stars

Mid-ultraviolet and optical photometric analysis of helium stars are presented. A linear relation exists between the effective temperature derived from model atmospheres and (1965-V)₀ index. The effective temperatures derived from (1965-V)₀ index are somewhat higher than that of MK spectral type estimates especially for late B-type helium objects.     

The significance of Messinian occurrences of Globorotalia margaritae and Globorotalia puncticulata in Sicily

Globorotalia puncticulata and Globorotalia margaritae are critical species that define internationally recognized planktonic foraminiferal biozones in the Pliocene. These biozones are defined from stratotype sections on Sicily and their fauna are commonly considered to have been introduced to the Mediterranean after an influx of Atlantic water that terminated the late Miocene desiccation of the basin. Herein new discoveries of these species in rocks that predate the late Miocene desiccation are described. These data are supported by magneto- and lithostratigraphy that have been integrated at a single continuous section. Not only do these discoveries question the existing foraminiferal biozone stratigraphy, they also suggest new models for the dispersal of planktonic species. It is proposed that Globorotalia puncticulata and perhaps even Globorotalia margaritae evolved in the Mediterranean during earliest Messinian times (during or before chron C3Bn1n) and dispersed into the Atlantic. This suggests that a marine connection remained between the two sea areas until at least chron C3An.1n. Using the existing geomagnetic polarity time scale, these occurrences are some 2 Myr earlier than previously recorded in the Mediterranean. The distribution of G. margaritae and G. puncticulata in Mediterranean sections is likely to reflect palaeoenvironment or the preservation of deposits rather than the absolute age of the sediments.     

Metamorphic decarbonation, silicate weathering and the long-term carbon cycle

The seawater ⁸⁷Sr/⁸⁶Sr curve implies a 50–100 Myr episodicity in weathering rate which requires a corresponding variation in CO₂ degassing from the solid earth to the atmosphere. It is proposed that this is caused by orogenesis, which both produces CO₂ as a result of metamorphic decarbonation reactions, and consumes extra CO₂ as a consequence of erosion-enhanced weathering. Global climate on the geological time-scale is therefore contTolled by the difference between the relatively large and variable orogenic-moderated degassing and weathering CO₂ fluxes.     

Nutrient (P, N) dynamics in the southwestern Kattegat, Scandinavia: sedimentation and resuspension effects

 The yearly nutrient supply from land and atmosphere to the study area in SW Kattegat is 10 900 tons of N and 365 tons of P. This is only few percent of the supply from adjacent marine areas, as the yearly transport through the study area is 218 000 tons of N and 18 250 tons of P. Yearly net deposition makes up 1340 tons of N (on average 2.5 g m^–2 yr^–1) and 477 ton of P (on average 0.9 g m^–2 yr^–1). Shallow-water parts of the study area have no net deposition because of frequent (>35% of the year) resuspension. Resuspension frequency in deep water is <1% of the year. Resuspension rates, as averages for the study area, are 10–17 times higher than net deposition rates. Because of resuspension, shallow-water sediments are coarse lag deposits with small amounts of organic matter (1.1%) and nutrients (0.04% N and 0.02% P). Deep-water sediments, in contrast, are fine grained with high levels of organic matter (11.7%) and nutrients (0.43% N and 0.15% P). Laboratory studies showed that resuspension changes the diffusive sediment water fluxes of nutrients, oxygen consumption, and penetration into the sediment. Fluxes of dissolved reactive phosphate from sediment to water after resuspension were negative in organic-rich sediments (13.2% organic matter) with low porosity (56) and close to zero in coarse sediments with a low organic matter content (2.3%) and high porosity (73). Fluxes of inorganic N after resuspension were reduced to 70% and 0–20% in relation to the rates before resuspension, respectively. Received: 10 July 1995 · Accepted: 19 January 1996     

Initial phase of chromospheric evaporation in a solar flare

In this paper we discuss the initial phase of chromospheric evaporation during a solar flare observed with instruments on the Solar Maximum Mission on May 21, 1980 at 20:53 UT. Images of the flaring region taken with the Hard X-Ray Imaging Spectrometer in the energy bands from 3.5 to 8 keV and from 16 to 30 keV show that early in the event both the soft and hard X-ray emissions are localized near the footpoints, while they are weaker from the rest of the flaring loop system. This implies that there is no evidence for heating taking place at the top of the loops, but energy is deposited mainly at their base. The spectral analysis of the soft X-ray emission detected with the Bent Crystal Spectrometer evidences an initial phase of the flare, before the impulsive increase in hard X-ray emission, during which most of the thermal plasma at 10⁷ K was moving toward the observer with a mean velocity of about 80 km s^-1. At this time the plasma was highly turbulent. In a second phase, in coincidence with the impulsive rise in hard X-ray emission during the major burst, high-velocity (370 km s^-1) upward motions were observed. At this time, soft X-rays were still predominantly emitted near the loop footpoints. The energy deposition in the chromosphere by electrons accelerated in the flare region to energies above 25 keV, at the onset of the high-velocity upflows, was of the order of 4 × 10¹⁰ erg s^-1 cm^-2. These observations provide further support for interpreting the plasma upflows as the mechanism responsible for the formation of the soft X-ray flare, identified with chromospheric evaporation. Early in the flare soft X-rays are mainly from evaporating material close to the footpoints, while the magnetically confined coronal region is at lower density. The site where upflows originate is identified with the base of the loop system. Moreover, we can conclude that evaporation occurred in two regimes: an initial slow evaporation, observed as a motion of most of the thermal plasma, followed by a high-speed evaporation lasting as long as the soft X-ray emission of the flare was increasing, that is as long as plasma accumulation was observed in corona.     

The three-dimensional geometry of the heliospheric current sheet

The three-dimensional geometry of the heliospheric current sheet seen from fixed points in interplanetary space is constructed for idealized (sinusoidal) magnetic neutral lines (equators) and for an observed magnetic equator on the basis of the “kinematic method” developed by Hakamada and Akasofu (1982). The cross-sections of the wavy current sheet at distances 1, 2 and 5 a.u. are also constructed for the idealized magnetic neutral lines.