Denitrification capacity in a subterranean estuary below a Rhode Island fringing salt marsh

Coastal waters are severely threatened by nitrogen (N) loading from direct groundwater discharge. The subterranean estuary, the mixing zone of fresh groundwater and sea water in a coastal aquifer, has a high potential to remove substantial N. A network of piezometers was used to characterize the denitrification capacity and groundwater flow paths in the subterranean estuary below a Rhode Island fringing salt marsh.¹⁵N-enriched nitrate was injected into the subterranean estuary (in situ push-pull method) to evaluate the denitrification capacity of the saturated zone at multiple depths (125–300 cm) below different zones (upland-marsh transition zone, high marsh, and low marsh). From the upland to low marsh, the water table became shallower, groundwater dissolved oxygen decreased, and groundwater pH, soil organic carbon, and total root biomass increased. As groundwater approached the high and low marsh, the hydraulic gradient increased and deep groundwater upwelled. In the warm season (groundwater temperature >12 °C), elevated groundwater denitrification capacity within each zone was observed. The warm season low marsh groundwater denitrification capacity was significantly higher than all other zones and depths. In the cool season (groundwater temperature <10.5 °C), elevated groundwater denitrification capacity was only found in the low marsh. Additions of dissolved organic carbon did not alter groundwater denitrification capacity suggesting that an alternative electron donor, possibly transported by tidal inundation from the root zone, may be limiting. Combining flow paths with denitrification capacity and saturated porewater residence time, we estimated that as much as 29–60 mg N could be removed from 11 of water flowing through the subterranean estuary below the low marsh, arguing for the significance of subterranean estuaries in annual watershed scale N budgets.     

The yield and isotopic composition of radiolytic H2, a potential energy source for the deep subsurface biosphere

The production rate and isotopic composition of H₂ derived from radiolytic reactions in H₂O were measured to assess the importance of radiolytic H₂ in subsurface environments and to determine whether its isotopic signature can be used as a diagnostic tool. Saline and pure, aerobic and anaerobic water samples with pH values of 4, 7, and 10 were irradiated in sealed vials at room temperature with an artificial γ source, and the H₂ abundance in the headspace and its isotopic composition were measured. The H₂ concentrations were observed to increase linearly with dosage at a rate of 0.40 ± 0.04 molecules (100 eV)⁻¹ within the dosage range of 900 to 3500 Gray (Gy; Gy = 1 J Kg⁻¹) with no indication of a maximum limit on H₂ concentration. At ∼2000 Gy, the H₂ concentration varied only by 16% across the experimental range of pH, salinity, and O₂. Based upon this measured yield and H₂ yields for α and β particles, a radiolytic H₂ production rate of 10⁻⁹ to 10⁻⁴ nM s⁻¹ was estimated for the range of radioactive element concentrations and porosities typical of crustal rocks. The δD of H₂ was independent of the dosage, pH (except for pH 4), salinity, and O₂ and yielded an αD_H2O-H2 of 2.05 ± 0.07 (αD_H2O-H2 = (D/H)_H2O to (D/H)_H2), slightly less than predicted radiolytic models. Although this radiolytic fractionation value is significantly heavier than that of equilibrium isotopic exchange between H₂ and H₂O, the isotopic exchange rate between H₂ and H₂O will erase the heavy δD of radiolytic H₂ if the age of the groundwater is greater than ∼10³ to 10⁴ yr. The millimolar concentrations of H₂ observed in the groundwater of several Precambrian Shields are consistent with radiolysis of water that has resided in the subsurface for a few million years. These concentrations are well above those required to support H₂-utilizing microorganisms and to inhibit H₂-producing, fermentative microorganisms.     

Microbial populations in contaminant plumes

Received, May 1999/Revised, October 1999/Accepted, October 1999     

Macrocrystal phlogopite Rb–Sr dates for the Ekati property kimberlites, Slave Province, Canada: evidence for multiple intrusive episodes in the Paleocene and Eocene

New Rb–Sr age determinations using macrocrystal phlogopite are presented for 27 kimberlites from the Ekati property of the Lac de Gras region, Slave Province, Canada. These new data show that kimberlite magmatism at Ekati ranges in age from at least Late Paleocene (61 Ma) to Middle Eocene time (45 Ma). Older, perovskite-bearing kimberlites from Ekati extend this age range to Late Cretaceous time (74 Ma). Within this age range, emplacement episodes at 48, 51–53, 55–56 and 59–61 Ma can be recognized. Middle Eocene kimberlite magmatism of the previously dated Mark kimberlite (47.5 Ma) is shown to include four other pipes from the east-central Ekati property. A single kimberlite (Aaron) may be younger than the 47.5 Ma Mark kimberlite. The economically important Panda kimberlite is precisely dated in this study to be 53.3±0.6 Ma using the phlogopite isochron method, and up to six additional kimberlites from the central Ekati property have Early Eocene ages indistinguishable from that of Panda, including the Koala and Koala North occurrences. Late Paleocene 55–56 Ma kimberlite magmatism, represented by the Diavik kimberlite pipes adjacent to the southeastern Ekati property, is shown to extend onto the southeastern Ekati property and includes three, and possibly four, kimberlites. A precise eight-point phlogopite isochron for the Cobra South kimberlite yields an emplacement age of 59.7±0.4 Ma; eight other kimberlites from across the Ekati property have similar Late Paleocene Rb–Sr model ages. The addition of 27 new emplacement ages for kimberlites from the Ekati property confirms that kimberlite magmatism from the central Slave Province is geologically young, despite ages ranging back to Cambrian time from elsewhere in the Slave Province. With the available geochronologic database, Lac de Gras kimberlites with the highest diamond potential are currently restricted to the 51–53 and 55–56 Ma periods of kimberlite magmatism.     

Lead isotopic compositions of South Sandwich Island volcanic rocks and their bearing on magmagenesis in intra-oceanic island arcs

Pb isotope ratios have been measured in 12 volcanic rocks from the South Sandwich Islands. The ranges are ${}^{206}\text{Pb}{}^{204}\text{Pb}\text{= 18.51–18.66;}{}^{207}\text{Pb}{}^{204}\text{Pb}\text{= 15.55–15.64;}{}^{208}\text{Pb}{}^{204}\text{Pb}\text{= 38.42–38.64}$. In ${}^{207}\text{Pb}{}^{204}\text{Pb}\text{-}{}^{206}\text{Pb}{}^{204}\text{Pb}$ and ${}^{208}\text{Pb}{}^{204}\text{Pb}\text{-}{}^{206}\text{Pb}{}^{204}\text{Pb}$ correlation diagrams, the South Sandwich data plot distinctly above the fields for ocean ridge basalts, and yield trends showing apparent mixing with a sedimentary end member similar to South Atlantic pelagic sediments as reported by Chow and Patterson (1962) and this study. Armstrong and Cooper (1971) have likewise shown that volcanics from the Lesser Antilles show mixing trends with North Atlantic sediments in Pb isotope correlation diagrams. The North Atlantic sediments have distinctly higher ${}^{206}\text{Pb}{}^{204}\text{Pb}$ and ${}^{208}\text{Pb}{}^{204}\text{Pb}$ ratios compared to the South Atlantic sediments. The parallel relationships between sediments and volcanic island arc rocks of the North and South Atlantic provide strong evidence for a component of Pb from subducted sediments in the lavas of the west Atlantic basin. In contrast to these data, lavas from the Mariana Arc in the western Pacific show little or no component of Pb from pelagic sediments. The reason for the different behaviors in the two settings is speculative.     

Extending the known distribution of the Younger Dryas Vedde Ash into northwestern Russia

The known distribution of wind‐blown Vedde Ash (ca. 10.3 ka BP) has been extended to the Karelian Isthmus in northwestern Russia. This has been possible as the result of a density separation technique that separates the rhyolitic Vedde Ash shards from the minerogenic host sediment. The Vedde Ash occurs in the middle of a pollen zone with high percentages of, for example, Artemisia and Chenopodiaceae, suggesting that the Younger Dryas (or GS‐I in the GRIP ice‐core event stratigraphy) was cold and dry throughout its duration. This is in agreement with sites in south Sweden where the Vedde Ash also occurs in the middle of a pollen zone dominated by Artemisia, Chenopodiaceae and Cyperaceae. Copyright © 2000 John Wiley & Sons, Ltd.     

Oxygen isotopes from Chinese caves: records not of monsoon rainfall but of circulation regime

Oxygen isotope variations in Chinese stalagmites have been widely interpreted as a record of the amount of East Asian summer monsoonal rainfall. This interpretation infers decreasing monsoonal rainfall from the mid‐Holocene and large, dipolar rainfall oscillations within glaciations. However, the speleothem δ¹⁸O variations conflict with independent palaeoclimate proxies (cave δ¹³C, loess/palaeosol magnetic properties, δ¹³C alkanes), which indicate no systematic decline in rainfall from the mid‐Holocene, and no glacial rainfall maxima. Using mass balance calculations (which incorporate seasonality effects in both δ¹⁸O concentration and amount of precipitation), we demonstrate that the cave δ¹⁸O variations cannot be accounted for by summer rainfall changes, or rainfall seasonality or winter cooling, but instead reflect changes in moisture source. A possible driver of the δ¹⁸O variations in Chinese stalagmites is precessional forcing of inter‐hemispheric temperature gradients, and resultant shifts in the position and intensity of the subtropical pressure cells. Through such forcing, Indian monsoon‐sourced δ¹⁸O may have dominated at times of high boreal summer insolation, and local Pacific‐sourced moisture at low insolation. Suppression of summer monsoonal rainfall during glacial stages may reflect diminished sea and land surface temperatures and the radiative impacts of increased regional dust fluxes. Copyright © 2012 John Wiley & Sons, Ltd.     

Depositional history of the Tyne valley associated with retreat and stagnation of Late Devensian Ice Streams

This paper provides sedimentological and morphological data from an investigation of the Late Devensian glacigenic deposits along the Tyne valley, northeast England. The area lies in the central sector of the British-Irish Ice Sheet, with the lowlands influenced by both the Tyne Gap and Tweed-Cheviot ice streams. The sequences here provide insights into the existence of complex, multi-phase activity within the British-Irish Ice Sheet. Field mapping of the area reveals kamiform topography in the Tyne lowlands and lower South Tyne valley, whilst the mid Tyne is characterised by high-level sandur terraces. Inset below the glacial features are river terraces. The sedimentary sequence comprises diamicton overlain by gravel and sandy gravels; sands, muddy sands and gravels; laminated silty sands and muds; and well sorted sands and gravel. The depositional environments indicate ice-contact, subaqueous and terrestrial sedimentation, with supraglacial, proglacial, subaquatic and paraglacial landsystems. Following the onset of deglaciation, westward retreat of Tyne Gap ice resulted in land to the east and southeast of its margin becoming ice-free. Continued/renewed southward flow of ice along the North Sea coast formed a persistent barrier to sediment-charged meltwaters draining the Tyne Gap ice margin. The separation of these two ice masses allowed a glacial lake to develop in the lower Tyne fed by a large proglacial sandur system, which with ice marginal retreat subsequently merged with Glacial Lake Wear. The sediment sequences record the final waning of the Tyne Gap ice stream, and are contiguous with sediments that extend west through the Tyne Gap and into the Cumbrian lowlands.     

Community-based responses to climate hazards: typology and global analysis

Climatic Change - The severity and frequency of climate change hazards are increasing around the world. Because the impacts are most acutely felt in local communities, it is critical to improve...     

Abundance, diversity and succession of aquatic Coleoptera and Heteroptera in a cluster of artificial ponds in the North German Lowlands

Our study describes and evaluates environmental influences on assemblages of aquatic Coleoptera and Heteroptera in artificial ponds situated near Lake Steinhude in Lower Saxony (Germany). We determined temporal dynamics and colonization patterns for 14 ponds of different age. In total, we recorded 4941 individuals that represented 87 species of aquatic beetles and bugs. Between 30 and 40 species were found in most of the ponds. Heteropteran species of the families Corixidae and Notonectidae acted as pioneer species in new ponds, while aquatic coleopterans predominated in older ponds. The results of Canonical Correspondence Analyses (CCA) showed that among the key factors affecting community structure were land use, vegetation cover, water chemistry and the age of the ponds. We found that the distribution of adjacent ponds on areas with different land use has a positive influence on the diversity and abundance of the aquatic insect fauna.