Occupational health and safety hazards in Atlantic Canadian aquaculture: Laying the groundwork for prevention

The growing aquaculture industry is projected to feature ever more prominently in the lives and economies of rural coastal communities in Atlantic Canada and around the world. Both private industry and government have a responsibility to ensure employment opportunities created in aquaculture take place in healthy, safe environments. However, systematic occupational health and safety (OHS) research within this industry, an important prevention tool, is still in its infancy. With particular emphasis on marine aquaculture in Atlantic Canada, we provide a detailed outline of the structure of the industry from feed production through to processing, identify potential OHS hazards associated with each of these activities and make recommendations for future research and action.     

The accumulation of Cu, Zn, Cd, and Pb in the aquatic biomass of sulphide tailing ponds

Flooding mine tailings to limit the oxidation of sulfides provides a habitat for aquatic organisms, such as plants, plankton, insects, and fish, which can uptake metals and, thus, threats for local ecosystems and influence the cycling of elements in biogeocenosis. An aquatic ecosystem developed naturally in sulphide tailing ponds containing cyanidation wastes of the Salair ore-refining plant (SORP), Russia, was studied. The objectives of this research were to: (i) reveal the level of contamination of living organisms in the tailing ponds compared to a natural control site and (ii) calculate the weight of metals in aquatic biomass to estimate the amount of metals transferring from the tailing ponds into the biogechemical cycle. The concentration of Cu, Zn, Cd, and Pb in the sediments of the tailing ponds is significantly higher than from the control site. Concentrations of Cu, Zn, Cd, and Pb in plant shoots were significantly higher than in the control and accumulated mainly in cell envelopes and membranes. The concentration of Pb in fish liver and eggs were 41 and 7.5 times higher, respectively, than maximum allowable concentrations. The biomass distribution between producers and consumers of the tailing pond ecosystem is similar to those of natural pond ecosystems. However, the weights of Cu, Zn, Cd, and Pb in all trophic levels per hectare of the tailing pond are orders of magnitude higher than those for Lake Baikal. The largest portion of metal circulates within the ecosystem of the Dyukov Ravine Pond with a maximum of 5 to 13% of this amount transferred into the surrounding environment through the food chains.     

Tektites - volcanic ejecta from the moon?

The problem of the origin of the enigmatic tektites is still unsolved. The two leading hypotheses - viz., ejecta from terrestrial impacts, and ejecta from lunar volcanoes or lunar impacts, each encounters serious difficulties. The former has ballistic and water content difficulties, while the latter has some compositional difficulties, especially in the trace elements, as determined from the returned samples. It is possible that the latter problem may be met through lunar volcanic ejecta from sites suggesting more differentiation than the majority of the Moon. That such features may exist is suggested from the identity of some granitic material in the returned rocks and soil samples implying fairly sizable source regions on the Moon. The rare terrestrial strewn tektite fields require restrictive ballistic trajectories from the Moon. Calculations reveal that ellipses of varying, decreasing sizes which depend on velocity of vertical ejection from which ejecta will intersect the earth at low-entrance angles occur on the nearside of the Moon. Reasonable velocities were chosen (2.55 to 3.0 km s^?1) and these ellipses circumscribe areas with longitudes between 30 and 50° east and latitudes between 7° north and south of the Moon's equator. These areas were searched for evidence of volcanism. As tektites have compositions ranging from acidic (major tektites) to basic (micro-tektites) contents of silica (SiO₂) both acidic and basic volcanic features were sought. Since tektites range in age from about 30 million to 700000 yr old, they imply recent volcanism. Lunar Transient Phenomena (LTP) and data from various Apollo missions indicate that mild internal activity may still be occurring on the Moon. LTP sites are logical sources to investigate, of which four occur within the above delimited regions. These and their surroundings were examined and a number of possible explosive volcanism sites were found. These sites are identified and discussed after a review of the manifestations found from the various kinds of terrestrial volcanism for which lunar counterparts were sought.     

Climate change in lowland Central America during the late deglacial and early Holocene

The transition from arid glacial to moist early Holocene conditions represented a profound change in northern lowland Neotropical climate. Here we report a detailed record of changes in moisture availability during the latter part of this transition (～11 250 to 7500 cal. yr BP) inferred from sediment cores retrieved in Lake Petén Itzá, northern Guatemala. Pollen assemblages demonstrate that a mesic forest had been largely established by ～11 250 cal. yr BP, but sediment properties indicate that lake level was more than 35 m below modern stage. From 11 250 to 10 350 cal. yr BP, during the Preboreal period, lithologic changes in sediments from deep‐water cores (>50 m below modern water level) indicate several wet–dry cycles that suggest distinct changes in effective moisture. Four dry events (designated PBE1‐4) occurred centred at 11 200, 10 900, 10 700 and 10 400 cal. yr BP and correlate with similar variability observed in the Cariaco Basin titanium record and glacial meltwater pulses into the Gulf of Mexico. After 10 350 cal. yr BP, multiple sediment proxies suggest a shift to a more persistently moist early Holocene climate. Comparison of results from Lake Petén Itzá with other records from the circum‐Caribbean demonstrates a coherent climate response during the entire span of our record. Furthermore, lowland Neotropical climate during the late deglacial and early Holocene period appears to be tightly linked to climate change in the high‐latitude North Atlantic. We speculate that the observed changes in lowland Neotropical precipitation were related to the intensity of the annual cycle and associated displacements in the mean latitudinal position of the Intertropical Convergence Zone and Azores–Bermuda high‐pressure system. This mechanism operated on millennial‐to‐submillennial timescales and may have responded to changes in solar radiation, glacial meltwater, North Atlantic sea ice, and the Atlantic meridional overturning circulation (MOC). Copyright © 2005 John Wiley & Sons, Ltd.     

Future trends in transport and fate of diffuse contaminants in catchments,with special emphasis on stable isotope applications

A summary is provided of the first of a series of proposed Integrated Science Initiative workshops supported by the UNESCO International Hydrological Programme. The workshop brought together hydrologists, environmental chemists, microbiologists, stable isotope specialists and natural resource managers with the purpose of communicating new ideas on ways to assess microbial degradation processes and reactive transport at catchment scales. The focus was on diffuse contamination at catchment scales and the application of compound‐specific isotope analysis (CSIA) in the assessment of biological degradation processes of agrochemicals. Major outcomes were identifying the linkage between water residence time distribution and rates of contaminant degradation, identifying the need for better information on compound specific microbial degradation isotope fractionation factors and the potential of CSIA in identifying key degradative processes. In the natural resource management context, a framework was developed where CSIA techniques were identified as practically unique in their capacity to serve as distributed integrating indicators of process across a range of scales (micro to diffuse) of relevance to the problem of diffuse pollution assessment. Copyright © 2006 John Wiley & Sons, Ltd.     

Uncertainty in Carbon Capture and Storage (CCS) deployment projections: a cross-model comparison exercise

Carbon Capture and Storage (CCS) can be a valuable CO₂ mitigation option, but what role CCS will play in the future is uncertain. In this paper we analyze the results of different integrated assessment models (IAMs) taking part in the 27th round of the Energy Modeling Forum (EMF) with respect to the role of CCS in long term mitigation scenarios. Specifically we look into the use of CCS as a function of time, mitigation targets, availability of renewables and its use with different fuels. Furthermore, we explore the possibility to relate model results to general and CCS specific model assumptions. The results show a wide range of cumulative capture in the 2010–2100 period (600–3050 GtCO₂), but the fact that no model projects less than 600 GtCO₂ indicates that CCS is considered to be important by all these models. Interestingly, CCS storage rates are often projected to be still increasing in the second half of this century. Depending on the scenario, at least six out of eight, up to all models show higher storage rates in 2100 than in 2050. CCS shares in cumulative primary energy use are in most models increasing with the stringency of the target or under conservative availability of renewables. The strong variations of CCS deployment projection rates could not be related to the reported differences in the assumptions of the models by means of a cross-model comparison in this sample.     

Geographical information system approach for environmental management in coastal area (Hardelot-Plage,France)

The use of geographic information system (GIS) minimizes the effort and improves the efficiency of numerical models. The GIS provides a platform for high capacity collection, management, manipulation, analysis, modeling and display of spatial data. The conceptual model is created using GIS objects including points, arcs and polygons so that it can accurately represent real world condition. According to the research problem, the geographical model is based on Hypergraph Based Data Structure method, and a conceptual data model has been created from which a physical data model was elaborated in ArcGIS9.3 platform. The groundwater modeling system (GMS) provides a powerful tool for hydrodynamics modeling and it is able to solve complex problems such as the groundwater flow and seawater intrusion. The sand-dune system of Hardelot-Plage (North of France) suffers from a lack of well-developed foredune. This problem is linked to the almost constant saturation of beach sand which is the potential source of dune nourishment. In the south of Hardelot, the coastline is slowly, but constantly retreating. To remedy this situation, a coupling between a GIS and GMS was adopted, in order to find the possible scenarios which could lower the piezometric surface in the concerned area and allow dune nourishment again. The GMS used supports the Modflow-2000 code. A direct approach to designing Modflow finite difference model is tedious and less intuitive, specifically for complex boundary and initial conditions. Therefore, a Modflow model can be developed either using a grid or conceptual model approach. The preparation of input data modeling is tedious and takes a long time. The model created in GMS was calibrated against the historical and observed water level data for 1995–2006. Then a hydrodispersive model (MT3d code in GMS) was launched for evaluating sea-water intrusion. The model was run to generate groundwater and salt concentration scenario during pumping tests.     

Geology and diamond distribution of the 140/141 kimberlite, Fort à la Corne, central Saskatchewan, Canada

The Cretaceous age Fort à la Corne (FALC) kimberlite province comprises at least 70 bodies, which were emplaced near the edge of the Western Canadian Interior Seaway during cycles of marine transgression and regression. Many of the bodies were formed during a marine regression by a two-stage process, firstly the excavation of shallow, but wide, craters and then subsequent infilling by xenolith-poor, crater-facies, subaerial, primary pyroclastic kimberlite. The bodies range in size up to 2000 m in diameter but are mainly less than 200 m thick and thus comprise relatively thin, but high volume, pyroclastic kimberlite deposits. Each body is composed of contrasting types of kimberlite reflecting different volcanic histories and, therefore, are considered separately.

The 140/141 kimberlite is the largest delineated body in the province, estimated to have an areal extent below glacial Quaternary sediments in excess of 200 ha. The infilling of the 140/141 crater is complex, resulting from multiple phases of kimberlite. The central part of the infill is dominated by several contrasting phases of kimberlite. One of these phases is a primary pyroclastic airfall mega-graded bed up to 130 m in thickness. The constituents grade in size from very fine to coarse macrocrystic kimberlite, through to a basal breccia. The mega-graded bed is a widespread feature within parts of the body examined to date and at this current stage of evaluation appears to explain a variable diamond distribution within a tested portion of the pipe. A second different phase of kimberlite is interpreted as representing a younger nested crater within the mega-graded bed. Centrally located thicker intersections (>450 m) of this younger kimberlite may indicate a vent for the kimberlite crater. The thickness of the mega-graded bed increases with proximity to the younger kimberlite in the study area.

Macrodiamond minibulk sample grades from the mega-graded bed have been obtained from nine large diameter drill holes, located within the northwest part of the body from an area of 20 ha, which represents approximately 10% of the currently modeled kimberlite outline. Diamond grade increases with depth within the mega-graded bed and also increases, within the same unit, towards the centrally positioned younger kimberlite. Macrodiamond sample grades vary from low at the top of the mega-graded bed, to considerably higher grades near the base. Total sample grade per drill hole varies from moderate near the vent feature to lower grades 200–300 m from the vent feature. Macrodiamond stone frequency measured in stones per tonne shows a pronounced relationship with depth and proximity to the vent feature within the mega-graded bed. There is a strong correlation between depth and increased stones per tonne, and a similar correlation between stones per tonne and proximity to the vent feature. The data supports the emplacement model of the mega-graded bed and, in turn, this information is useful in understanding the macrodiamond distribution within this bed.     

Fingerprinting upland sediment sources: particle size‐specific magnetic linkages between soils,lake sediments and suspended sediments

Accelerated erosion of fine‐grained sediment is an environmental problem of international dimensions. Erosion control strategies and targeting of mitigation measures require robust and quantitative identification of sediment sources. Here, we use magnetic ‘fingerprinting’ to characterize soils, and examine their affinity with and contribution to suspended sediments transported within two subcatchments feeding Bassenthwaite Lake, northwest England. A high‐resolution soil magnetic susceptibility survey was made using a field susceptometer (ZH Instruments, SM400 probe). Combining the spatial and vertical (down‐profile) soil magnetic data, a subset of soil profiles was selected for detailed, laboratory‐based magnetic remanence analyses. The magnetic properties of the catchment soils are highly particle size‐dependent. Magnetic analyses were performed on the 31–63 µm fraction, for particle size‐specific comparison both with the suspended sediments and lake sediments. Fuzzy cluster analysis groups the soil magnetic data into six clusters, apparently reflecting variations in parent material and horizon type, with three magnetically hard soils as unclassified outliers. Examination of the cluster affinity of the soils, suspended sediments and lake sediments indicates that topsoils of the upper Newlands Valley and subsoils around Keskadale Beck are a major source of the Newlands Beck suspended load, and the recent (post‐nineteenth century) sediments in the deep lake basin. Older lake sediments show strong affinity with a small number of the Derwent suspended sediments and one of the Glenderamackin soils. A large number of Derwent suspended sediments show no affinity with any of the soils or lake sediments, instead forming a coherent, discrete and statistically unclassified group, possibly resulting from mixing between the magnetically hard subsoils of the medium to high‐altitude Glenderamackin and Troutbeck areas and softer, lower altitude Glenderamackin soils. The lack of any affinity of these suspended sediments with the lake sediments may indicate deposition along the Derwent flood plain and/or in the shallow delta of Lake Bassenthwaite. Particle size‐specific magnetic fingerprinting is thus shown to be both highly discriminatory and quantitatively robust even within the homogeneous geological units of this catchment area. Such a methodological approach has important implications for small–large scale catchment management where sources of sediment arising from areas with uniform geology have been difficult to determine using other approaches, such as geochemical or radionuclide analyses. Copyright © 2009 John Wiley & Sons, Ltd.