热处理天然金红石的微结构研究

利用粉晶X射线衍射(XRD)、透射电镜(TEM)等分析手段对在氩气气氛中加热、退火的天然金红石样品的微结构进行了研究.研究表明样品在热处理后,晶格发生膨胀,并且在900 ℃和1000 ℃的样品中出现了钛铁矿物相.钛铁矿也是一种天然半导体矿物,沿与金红石(010)面网成大约31°夹角的方向生长,与金红石形成了二元复合半导体.紫外漫反射实验结果表明热处理后,金红石中出现的钛铁矿相有效地促进了光催化效果.     

Results for Rarely Determined Elements in MPI-DING, USGS and NIST SRM Glasses Using Laser Ablation ICP-MS

New analytical results are reported for rarely determined elements Be, B, Ge, As, Mo, Rh, Pd, Ag, Cd, In, Sn, Sb, W, Re, Ir, Pt, Au, Tl and Bi in MPI‐DING and USGS (BCR‐2G, BHVO‐2G, BIR‐1G) silicate glasses and the NIST SRM 610‐614 synthetic soda‐lime glasses using 193 nm ArF excimer laser ablation and quadrupole ICP‐MS. The method used involved external calibration against GOR132‐G for Ir and NIST SRM 610 for other elements, internal standardisation using Ca, and ablation with a crater diameter of 160 μm and a pulsed laser repetition rate of 10 Hz. Small amounts of nitrogen (5 ml min^?1) were added to the central channel gas of the plasma to improve the limits of detection for most of these elements by a factor of 1.2–2.5 and to reduce the oxide interference level to 0.02% (ThO⁺/Th⁺). Under these conditions, the LODs for most of these rarely determined elements were within the range 0.1 to 10 ng g^?1. The operating conditions that were required to minimise ICP‐induced fractionation (U⁺/Th⁺≈ 1) in the mode without nitrogen were accompanied by a 50–60% reduction in sensitivity for elements such as Ca, Au and Pt. In contrast, ICP‐induced fractionation could be minimised (U⁺/Th⁺≈ 1) with no loss of analyte sensitivity in the nitrogen mode. Interferences of CuAr⁺, ZnAr⁺, Cd⁺, Pb²⁺ and Sn⁺ on Pd⁺, Rh⁺, Cd⁺ and In⁺ were corrected. Oxide interferences were not considered due to their lower production rate. Analytical precision, as given by one relative standard deviation (% RSD) was less than 15% for most of the elements present at concentrations greater than 0.1 μg g^?1. A significant negative correlation was found between logarithmic concentration and logarithmic RSD, with a correlation coefficient of ?0.76. This trend indicates that possible chemical heterogeneities for most of these elements are smaller than the analytical uncertainty. Our results for Be, B, Ge, Sb and W are generally in good agreement with their reference values. In contrast, other elements in many of the reference glasses have only information values, upper limits or even no values, which restrict any detailed evaluation of the accuracy of the determined values. However, concentrations from multiple isotopes of one element analysed in this study showed excellent agreement, which guarantee the quality of our data to a certain extent.     

Physical properties of ultrahigh-pressure metamorphic rocks from the Sulu terrain, eastern central China: implications for the seismic structure at the Donghai (CCSD) drilling site

About 30 samples representing major lithologies of Sulu ultrahigh-pressure (UHP) metamorphic rocks were collected from surface exposures and exploration wells, and compressional (Vp) and shear wave (Vs) velocities and their directional dependence (anisotropy) were determined over a range of constant confining pressures up to 600 MPa and temperatures ranging from 20 to 600 °C. Samples range in composition from acidic to ultramafic. P- and S-wave velocities measured at 600 MPa vary from 5.08 to 8.64 km/s and 2.34 to 4.93 km/s, respectively. Densities are in the range from 2.60 to 3.68 g/cm³. To make a direct tie between seismic measurements (refraction and reflection) and subsurface lithologies, the experimental velocity data (corresponding to shallow depths) were used to calculate velocity profiles for the different lithologies and profiles of reflection coefficients at possible lithologic interfaces across the projected 5000-m Chinese Continental Scientific Drilling Program (CCSD) crustal segment. Comparison of calculated in situ velocities with respective intrinsic velocities suggests that the in situ velocities at shallow depths are lowered by an increased abundance of open microcracks. The strongly reflective zone beneath the Donghai drill site can be explained by the impedance contrasts between the different lithologies. Contacts between eclogite/peridotite and felsic rocks (gt-gneiss, granitic gneiss), in particular, may give rise to strong seismic reflections. In addition, shear-induced (lattice preferred orientation (LPO)-related) seismic anisotropy can increase reflectivity. For the explanation of the high velocity bodies (>6.4 km/s) around 1000 m and below 3200-m depth, large proportions of eclogite/peridotite (about 40 and 30 vol.%, respectively) are needed.     

高压下天然菱铁矿的压缩性和电子结构研究

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。     

地球内部物质电学性质原位测量的影响因素和导电机制——以地壳矿物为例

高温高压下矿物岩石电导率的实验研究数据,不仅是人们了解地球内部物质组成及其演化过程的重要窗口,而且可以为野外大地电磁测深和地磁测深反演提供重要约束.重点介绍了温度、压力、水含量、铁含量、氧逸度、熔融等矿物岩石电导率的影响因素,深入阐述了存在于矿物岩石的4种主要导电机制,即离子、质子、小极化子和大极化子.回顾近年来地壳主要造岩矿物(长石、石英和辉石)的电导率实验研究取得的新成果,讨论了它们的导电机制和地球物理意义,并对其目前存在的问题及尚需进一步展开的工作进行了探讨.     

河西走廊疏勒河流域水资源管理问题分析

从水资源管理体制、配置程序、市场化管理等方面探讨了河西走廊疏勒河流域水资源管理及存在的问题。目前流域已建成较健全的用水者协会体系,水价和水权在不断调整以适应水资源管理的需求。其管理存在以下问题：受地方行政、企业等多方权力博弈的影响,地表水和地下水处于双线管理状态,未能实现流域水资源的全面统一管理;用水者协会的职能未得到充分发挥,公众参与水资源管理不积极;流域内水价、水权制度不完善。建议如下：应在甘肃省水利厅和酒泉市政府之间形成协调机制,以协调各相关方的权益,完善流域管理局和地方政府统一协调的水资源管理体系,实现流域水资源的集成管理;加强流域机构立法,实现流域水资源的统一管理与调配;将协会的职责和义务融入到村委会的职务中,并完善水价制度,建立水权交易市场,以调动公众的自我管理和实现水资源的高效利用。     

地质工程专业发展战略研究

从地质工程人才培养角度,重点分析了地质工程专业教育的现状,根据社会对人才的需求、科技进步和地质工程所面临的发展实际,从可持续发展战略的高度阐述了地质工程素质人才教育所需要采取的对策.     

Study on Strength Influence Mechanism of Fiber-Reinforced Expansive Soil Using Jute

This study was undertaken to research the effects of jute fiber content, fiber length, water content and dry density of reinforced and unreinforced soil on the strength influence mechanism by implementing a series of laboratory tests and analysis. The most efficient fiber reinforcement effects was achieved by means of adding jute fiber with content of 0.6 % and length of 6 mm into expansive soil specimen prepared at maximum dry density and optimum moisture content. The cohesion of reinforced specimens increased first with increasing fiber content and fiber length and then decreased with further increase in fiber content and fiber length. The internal friction angle of reinforced specimens were not affected significantly by fiber content and fiber length. Higher water content reduces the fiber reinforcement effects by means of acting as lubricant in the interface of fiber and soil particles. Fiber reinforcement effects is more prominent for specimens prepared at higher dry density by increasing the effective contact area of fiber/soil. The application prospect of soil reinforcement using natural fiber is impeded by the hydrophilic nature and biodegradability of natural fiber, thus, studies on using chemical additive to do surface treatment for natural fiber are needed to improve the interfacial interaction of fiber/soil so as to widen the application of natural fiber.     

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.     

赤峰托河盆地流纹岩年代学、地球化学特征及其地质意义

赤峰托河火山盆地位于大兴安岭南端内蒙古赤峰市克什克腾旗境内,处于西拉木伦河-长春缝合带以南、康宝-围场-赤 峰-开源断裂带以北的辽源地块,盆地中的长英质火山岩系角度不整合于下二叠统额里图组、于家北沟组之上,并被新近系汉诺 坝组玄武岩不整合覆盖。SHRIMP 锆石U-Pb年龄表明,盆地火山岩系中流纹岩锆石的206Pb/238U年龄为158.5±1.3 Ma,属晚侏罗 世早期岩浆活动的产物,应归入新民组。托河流纹岩具有较高的SiO2含量（68.6%~72.6%）,A/CNK值<1.1,标准矿物刚玉的含量< 1%;ΣREE含量较高,轻稀土富集,负铕异常显著;(87Sr/86Sr)i= 0.709244~0.713168,εNd(t)=-8.76~-8.42,TDM2=1656~1629Ma,(206Pb/ 204Pb)i=17.271~17.326,(207Pb/204Pb)i=15.401~15.413,(208Pb/204Pb)i=37.614~37.696,δ18OV-SMOW=4.1‰~4.5‰。经对比托河盆地流纹岩与 红山子盆地、芝瑞盆地流纹岩、流纹斑岩,它们主量元素、微量元素和Sr-Nd-Pb-O同位素地球化学特征基本一致,指示各盆地的 物质来源相同。文章证实赞同前人提出的物质来源既与地壳（特别是下地壳）有关,也与地幔特别是EMI型地幔有关的观点。在 (Yb+Ta)-Rb和Y-Nb图解上,托河盆地流纹岩均显示板內拉张的构造环境。类比红山子盆地的岩石组合、地质时代、同位素组 成、铀矿化特征等,提出托河盆地条件更优越,认为今后盆地内的铀矿勘查工作可参照红山子铀钼矿床的模式开展。