A mechanism for preferential H2O leakage from fluid inclusions in quartz,based on TEM observations

Preferential leakage of H₂O from fluid inclusions containing multiple gas components has been suspected in natural metamorphic rocks and has been demonstrated experimentally for synthetic H₂O-CO₂-rich inclusions in natural quartz. Knowledge of the physical and chemical characteristics of the leakage mechanism, which may be very complex, increases the value of natural fluid inclusions to metamorphic geology. It is proposed that crystal defects play a major role in nondecrepitative preferential H₂O leakage through quartz, and remain effective during metamorphism. Inclusions with either an internal overpressure or underpressure produce strain in the adjacent quartz crystal via the nucleation of many dislocations and planar defects (like Dauphiné twin boundaries). These defects allow preferential loss of H₂O from H₂O-CO₂-rich inclusions at supercritical conditions. The transport capacity of this leakage mechanism is enhanced by nucleation of small bubbles on defect structures. The nucleation of these bubbles seems to be a recovery process in strained crystals. Solubility gradients of quartz in water in a crystal with internally underpressurized inclusions may result in optical visible implosion halos in a three dimensional spatial arrangement, caused by the growth of small bubbles at the expense of the larger original fluid inclusion. Natural fluid inclusions from Naxos (Greece) are always associated with numerous interlinked dislocations. These dislocations may have been produced by plastic derormation or by crystal growth related processes (e.g. crack healing). The presence of small bubbles on these dislocations indicates that a similar leakage mechanism for H₂O must have occurred in these rocks.     

A New Operational Paradigm for Small‐Scale ASR in Saline Aquifers

A new operational paradigm is presented for small‐scale aquifer storage and recovery systems (ASR) in saline aquifers. Regular ASR is often not feasible for small‐scale storage in saline aquifers because fresh water floats to the top of the aquifer where it is unrecoverable. In the new paradigm, fresh water storage is combined with salt water extraction from below the fresh water cone. The salt water extraction counteracts the buoyancy due to the density difference between fresh water and salt water, thus preventing the fresh water from floating up. The proposed approach is applied to assess the feasibility of ASR for the seasonal storage of fresh water produced by desalination plants in tourist resorts along the Egyptian Red Sea coast. In these situations, the continuous extraction of salt water can be used for desalination purposes. An analytical Dupuit solution is presented for the steady flow of salt water toward a well with a volume of fresh water floating on top of the cone of depression. The required salt water discharge for the storage of a given volume of fresh water can be computed with the analytical solution. Numerical modeling is applied to determine how the stored fresh water can be recovered. Three recovery approaches are examined. Fresh water recovery rates on the order of 70% are achievable when salt water is extracted in high volumes, subsurface impermeable barriers are constructed at a distance from the well, or several fresh water recovery drains are used. The effect of ambient flow and interruptions of salt water pumping on the recovery efficiency are reported.     

Synthetic Experiments Dealing with Anisotropic Model Building

It has been shown in the past that the interval-NMO velocity and the non-ellipticity parameter largely control the P-wave reflection time moveout of VTI media. To invert for these two parameters, one needs either reasonably large offsets, or some structure in the subsurface in combination with relatively mild lateral velocity variation.This paper deals with a simulation of an inversion approach, building on the assumption that accurately measured V _NMO, as defined by small offset asymptotics for a particular reflector, were available. Instead of such measurements we take synthetically computed data. First, an isotropic model is constructed which explains these V _NMO. Subsequently, residual moveout in common image gathers is modelled by ray tracing (replacing real data), along with its sensitivity for changes in the interval-NMO velocity and the non-ellipticity parameter under the constraint that V _NMO is preserved. This enables iterative updating of the non-ellipticity parameter and the interval-NMO velocity in a layer that can be laterally inhomogeneous.This approach is successfully applied for a mildly dipping reflector at the bottom of a layer with laterally varying medium parameters. With the exact V _NMO assumed to be given, lateral inhomogeneity and anisotropy can be distinguished for such a situation. However, for another example with a homogeneous VTI layer overlying a curved reflector with dip up to 30°, there appears to be an ambiguity which can be understood by theoretical analysis. Consistently with existing theory using the NMO-ellipse, the presented approach is successfully applied to the latter example if V _NMO in the strike direction is combined with residual moveout in dip direction.     

Erodibility of soft freshwater sediments in Markermeer: the role of bioturbation by meiobenthic fauna

The Markermeer is a large and shallow man-made freshwater lake in the Netherlands, characterized by its high turbidity. As part of a study aiming to mitigate this high turbidity, we studied the water–bed exchange processes of the lake’s muddy bed. The upper centimeter’s–decimeter’s of the lake bed sediments mainly consists of soft anoxic mud. Recent measurements have proved the existence of a thin oxic layer on top of this soft anoxic mud. This oxic layer, which is much easier to be eroded than the anoxic mud, is believed to be related with Markermeer’s high-turbidity levels. Our hypothesis is that the thin oxic layer develops from the anoxic mud, enhanced by bioturbation. Actually, we will demonstrate that it is the bioturbated state of the bed that increases its erodability, and not the oxidation state of the sediments. In particular, we will refer to bioturbation caused by meiobenthic fauna. The objective of this study is therefore to determine the influence of the development of the thin oxic layer on the water–bed exchange processes, as well as to establish the role of bioturbation on those processes. This is done by quantifying the erosion rate as a function of bed shear stresses, and at different stages of the development of the oxic layer. Our experiments show that bioturbation increases the rate at which Markermeer sediments are eroded by almost an order of magnitude. The short-term fine sediment dynamics in Markermeer are found to be driven by the complex and highly dynamic interactions between physics, chemistry, and biology. Finally, the long-term fine sediment dynamics are driven by the erosion of the historical deposits in the lake’s bed, which is only possible after bioturbation, and which leads to an increase of the stock of sediments in the lake’s muddy bed.     

Revisiting the morphological method in two-dimensions to quantify bed-material transport in braided rivers

Research in the 1990s showed that bed-material transport rates could be estimated at the reach scale in both one-dimension and, over small spatial scales (10s of m), in two-dimensions. The limit on the latter was the spatial scale over which it was possible to obtain distributed data on morphological change. Here, we revisit the morphological method given progress in both topographical data acquisition and hydraulic modelling. The bed-material transport needed to conserve mass is calculated in both one and two dimensions for a 1600 m × 300 m Alpine braided river “laboratory”. High-resolution topographical data were acquired by laser scanning to quantify Digital Elevation Models (DEMs), and morphological changes caused by the flushing of the water intake were derived from repeated surveys. Based on DEMs of differences, 1D bed-material transport rates were calculated using the morphological method. Then, a 2D hydraulic model was combined with a topographic correction to route sediment through the network of braided channels and to obtain a spatially variable estimate of transport in both downstream and cross-stream directions. Monte Carlo simulation was applied to the routing model parameters, allowing identification of the most probable parameter values needed to minimize negative transport. The results show that within-section spatial compensation of erosion and deposition using the 1D treatment leads to substantial local errors in transport rate estimates, to a degree related to braiding intensity. Even though the 2D application showed that a large proportion of the total transport was actually concentrated into one main channel during the studied low flow event, the proportion of transport in secondary anabranches is substantial when the river starts braiding. Investigations of the effects of DEM resolution, competent flow duration and survey frequency related to ‘travelling bedload’ and sequential erosion-deposition emphasized the critical importance of careful data collection in the application of the morphological method. © 2019 John Wiley & Sons, Ltd.     

Circumstellar Molecular Spectra Towards Evolved Stars

In this paper we discuss the relevance, and possible scientific gains, which can be acquired from studying circumstellar molecular spectra toward evolved stars. Where can we expect circumstellar molecular spectra, why would we want to study these spectra, which molecules might be present, and what can we learn from these studies? We present an overview of reported detections, and discuss some of the results.     

Tectonic and sedimentary history of a late Cenozoic intramontane basin (The Pitalito Basin, Colombia)

Abstract The Pitaiito Basin is an intramontane basin (15 × 20 km²) situated at the junction of the Central and Eastern Cordillera in the southern part of the Colombian Andes. Tectonic structures, evolution of the basin and distribution of the sediments suggest that the basin was formed adjacent to an active dextral strike-slip fault. Based on sedimentation rates it is estimated that subsidence started around 4.5 Ma. The basin can be divided into a relatively shallow western part (c. 300 m deep) and a deep eastern part (c. 1200 m deep). The transition between both areas is sharp and is delineated by a NW/SE-oriented fault. The position of this fault is reflected by the areal distribution of the deep non-exposed sediments as well as sediments at the surface: west of this fault the basin infill consists of coarse to medium elastics (conglomerates and sand) whereas in the eastern part fine elastics (clay and peat) are present. The lateral transition between both types of sediment is abrupt and its position is stable in time. The surface and near surface sediments in the Pitalito Basin reflect the last stage of sedimentary infill which came to a halt between 17,000 and 7500 years bp . These sediments were deposited by an eastward prograding fluvial system. The western upstream part of this system differs significantly from that of the eastern part which forms the downstream continuation. The western part exhibits unstable, shallow fluvial channels that wandered freely over the surface which predominantly consists of clayey overbank sediments. The alluvial architecture in the eastern half is characterized by stable channels and thick accumulations of organic-rich flood basin sediments and resembles an anastomosing river. The transition between both alluvial systems also coincides with the N/S-oriented normal fault. Palaeoclimatic conditions over the last c. 61,500 years were determined by means of a pollen record. From c. 61,500 to 20,000 years BP the mean annual temperature fluctuated considerably and decreased by 2–3^oC during the relatively warm periods (interstadials) and by 6–8^oC during the cold periods (stadials) in comparison with modern temperatures. These changes led to a displacement of the zonal vegetation belts from c. 200 m during the stadials to c. 1500 m in interstadial times without significant effects on the fluvial system present in the Pitaiito Basin until c. 20,000 years BP. Around this period the organic-rich eastern flood basins were choked with sediments and peat growth came to an end. Palynological and sedimentological data suggest that around that period the climate was cold (Δ 6–8^oC) and very dry and that a sparse vegetation cover was present around the basin. In these semi-arid climatic conditions the river system changed from an anastomosing pattern to one with ephemeral stream characteristics. This may have lasted until at least 17,000 years BP. Somewhere between 17,000 and 7500 years BP the eastward-flowing infilling river system changed into a NW-flowing erosive river system due to climatic or tectonic control and the present state was reached.     

Where do periodic variations in the discharge of a well become negligible?

A rule of thumb is presented to determine where variations in the discharge of a pumping well have a significant influence on the flow in an aquifer. The rule of thumb relates the period of the variation of the discharge to the distance from the well beyond which the transient effect on the flow in the aquifer is insignificant. For example, when an irrigation well pumps intermittently during the growing season, the rule may be applied to determine the distance from the well beyond which flow in the aquifer can be simulated with an average discharge during the growing season; the distance from the well beyond which flow can be simulated with a steady, yearly averaged discharge can also be computed.     

Archipelagos and networks: urbanization and water privatization in the South

This paper examines the interrelationship between urbanization and water supply privatization in cities in the global South. The purpose of the paper is not to evaluate the impacts of privatization; rather, the paper analyses the differences in pathways and modes of water supply privatization, focusing on urban and contrasting with rural areas. A distinction is drawn between privatization (organizational change) and commercialization (institutional change) of water supply. Emphasis is placed upon the interrelationship between regulatory change (a shift from public to private management of water supply systems), human use of and access to water, and urban waterscapes. In contrast to metaphors of 'networks' so often applied in analyses of water management, the 'archipelago' is posited as a metaphor which better captures the complex overlapping strategies of water supply provision in urban areas in the South. Building on this metaphor, and in response to the 'public–private' dualism often invoked in studies of privatization, the paper outlines an alternative typology of water management in urban areas in the South. This typology foregrounds the concepts of the territorialization of corporate power as a means of understanding the articulation between privatization and urbanization processes in the South.