Numerical modeling of three‐phase dissolution of underground cavities using a diffuse interface model

Natural evaporite dissolution in the subsurface can lead to cavities having critical dimensions in the sense of mechanical stability. Geomechanical effects may be significant for people and infrastructures because the underground dissolution may lead to subsidence or collapse (sinkholes). The knowledge of the cavity evolution in space and time is thus crucial in many cases. In this paper, we describe the use of a local nonequilibrium diffuse interface model for solving dissolution problems involving multimoving interfaces within three phases, that is, solid–liquid–gas as found in superficial aquifers and karsts. This paper generalizes developments achieved in the fluid–solid case, that is, the saturated case [1]. On one hand, a local nonequilibrium dissolution porous medium theory allows to describe the solid–liquid interface as a diffuse layer characterized by the evolution of a phase indicator (e.g., porosity). On the other hand, the liquid–gas interface evolution is computed using a classical porous medium two‐phase flow model involving a phase saturation, that is, generalized Darcy's laws. Such a diffuse interface model formulation is suitable for the implementation of a finite element or finite volume numerical model on a fixed grid without an explicit treatment of the interface movement. A numerical model has been implemented using a finite volume formulation with adaptive meshing (e.g., adaptive mesh refinement), which improves significantly the computational efficiency and accuracy because fine gridding may be attached to the dissolution front. Finally, some examples of three‐phase dissolution problems including density effects are also provided to illustrate the interest of the proposed theoretical and numerical framework. Copyright © 2014 John Wiley & Sons, Ltd.     

EFFECT OF SULPHATE-REDUCING BACTERIA ON ELECTRO-CHEMICAL CORROSION BEHAVIOR OF 16Mn STEEL IN SEA MUD

ＩＮＴＲＯＤＵＣＴＩＯＮＩｔｗａｓｇｅｎｅｒａｌｌｙｃｏｎｓｉｄｅｒｅｄｐｒｅｖｉｏｕｓｌｙｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｏｆｓｔｅｅｌｉｎｓｅａｍｕｄｗａｓｎｏｔｓｅｒｉｏｕｓ.Ｈｏｗｅｖｅｒ,ｉｔｗａｓｌａｔｅｒｆｏｕｎｄｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒａｔｅｏｆｓｔｅｅｌｉｎｓｏｍｅｓｅａｍｕｄｗａｓｈｉｇｈｅｒｔｈａｎｔｈａｔｉｎｓｅａｗａｔｅｒ(Ｋｉｎｇ,1980;Ｓｅｈｍｉｄｅ,1982;Ｇｕｏｅｔａｌ.,1997;Ｈｏｕ,1998).Ｔｈｅｒｅａｒｅｓｏｍｅｒｅｐｏｒｔｓｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒ…     

某些幔源矿物晶体中异常消光现象的显微喇曼谱研究

异常消光是一种在幔源晶体中常可观察到的物性改变现象,然而它与晶体的真实结构之间的内在联系却至今仍未被认识清楚。本项工作试图用一种灵敏的微区结构探测新技术——显微激光喇曼谱方法研究幔源晶体中由构造作用导致的异常消光现象的结构本质。实验结果说明:上地幔高温蠕变作用对橄榄石及辉石主要感应了晶体内微区晶轴取向的变化,还未能产生明显的结构相变;不同的异常消光现象反映晶轴扭转的单位大小不同,并主要依赖于矿物晶体本身的结构特性。     

丹江口水库叶绿素a浓度的时空特征及影响因子分析

2017年5月—2019年10月,对"南水北调"中线水源水库——丹江口水库库区水体7个监测位点、0～20 m间4个水层的垂向叶绿素a (Chl.a)浓度与水质因子进行了季度性调查,以期了解不同位点、不同水层Chl.a分布的主要驱动因子.结果表明,丹江口水库各位点营养状态指数(TSI)均为中营养化状态.水体Chl.a浓度具有逐年增加的趋势,且极高值有逐渐增加的趋势.营养盐和Chl.a浓度均存在较大的空间异质性,入库区具有较高的总磷和氨氮浓度,汉江库区具有最高的Chl.a浓度,源头污染源控制和监测仍然是丹江口水库管理的重中之重.不同位点Chl.a浓度的驱动因子存在较大差异,汉江入库和大坝区Chl.a浓度分别受到硝态氮和p H的影响,而出水口大坝位点主要受到了水深、水温和氨氮的影响.丹江入库区Chl.a浓度受到了水深、氨氮、总磷和水温的影响,但丹江库区表现出了与其他生态区较大的区别,其Chl.a浓度主要受到水深和有机质输入的影响.因此,对丹江口水库各位点的管理,应该分不同生态区采取针对性的管理措施.本研究旨在为南水北调中线工程可持续的生态调度提供基础生态数据支持,为完善水库水源地的有效管理提供理论支撑.     

Hazard degree identification and coupling analysis of the influencing factors on goafs

In China, there are a large number of mined-out area which bring a great hidden danger to the mine enterprise’s safety production and people’s life and property. Therefore, the stability evaluation and the mechanism analysis of goafs have become a hot issue in the study on sustainable development of mining industry. To solve the complexity, concealment, and uncertainty of goaf influencing factors, 14 factors, i.e., rock mass structure, goaf span, exposed area, and so on, were selected as the evaluation indexes according to an iron ore. Then, the hazard evaluation model of goaf was established by using the information entropy and the unascertained measurement (UM) theory to identify the hazard degree, and the hazard importance degree index was put forward by changing the influencing factors and its index value to quantitatively analyze the coupling degree of influencing factors. This paper takes the BFZ-8 goaf as an example to evaluate and analyze the goaf stability. The results show that the evaluation model about UM and the experimental schemes are feasible and practicability, and the UM evaluation grades are consistent with the fuzzy evaluation grades and the actual risk grades in the case of multi-factor coupling. And the experimental results quantitatively reflect the coupling degree of the influencing factors by comparing the relative change rate of the importance degree, and the coupling results are consistent with the actual situation. So, the method can guide the production safety of mine, protect life and property safety of miners, and provide technical support and a new method for hazard degree identification of the goaf.     

“海棠”台风(2005)暴雨过程数值模拟及位涡分析

采用WRF模式对2005年"海棠"台风登陆福建省前后24h内所造成的降水过程进行了数值模拟,在此基础上,利用模式输出结果,借助位涡理论分析位涡与台风低压流场及降水的关系,并结合对风场、相当位温、相对湿度等诊断量的分布特征分析,探讨了台风强降水的发展和维持机制。结果表明,310K等熵面上高位涡发展演变较好反映了台风低压系统路径移动以及强度变化的过程。暴雨中心主要出现在位涡大值区及其偏东北方向,且位涡气块回旋少动,与暴雨的发展维持密切相关。高位涡区主要位于等熵面坡度和梯度最大处,当等熵面上下贯通,对流层高层的高位涡沿等熵面下传,形成位涡柱时,有利于暴雨增幅。台风环流内水汽充足,上升运动强烈,也有助于此次台风降水强度持续强大。     

准噶尔盆地腹部侏罗系地层超压成因机制——以东道海子北凹陷为例

准噶尔盆地腹部地区侏罗系地层超压普遍发育,超压层段与声波时差、电阻率两者之间具有较好的响应关系,尤以电阻率响应最为显著,超压层段声波时差表现为异常高值,电阻率为异常低值的特征。利用准噶尔盆地腹部地区大量测井、测试及相关地质资料综合论述超压成因,指出泥岩和砂岩中发育的超压并非由压实不均衡、构造挤压等作用导致,而主要由生烃作用造成的。研究表明有以下几方面主要证据：1）超压泥岩密度不具有异常低值特征;2）超压段泥岩密度与岩石颗粒垂直有效应力之间不存在线性关系;3）超压砂岩不存在异常高地温梯度现象;4）超压顶界面深度范围为3 800～4 300 m,侏罗系烃源岩现今成熟度（Ro%）范围为0.6%～0.9%,温度范围分布在90 ℃～125 ℃;5）超压层段的侏罗系烃源岩现今生烃转化率最高可达70%,现今平均生油率可达90 mg/g·TOC,仍具有较强的生烃能力;6）泥质烃源岩本身对超压具有很好的封闭作用;7）侏罗系烃源岩内发育大量低角度或高角度微裂缝;8）超压储层主要以油层为主,无水层,准噶尔盆地东道海子北凹陷砂岩中超压主要是通过烃源岩中排出的高压流体运移至储层发生超压传递的结果。     

有限区域变分四维同化系统的设计和试验

使用共轭码技术，构造了中尺度模式的伴随模式，研究了模式侧边界条件。基于伴随模式技术的原理，设计了伴随同化和Derber同化方法两套方案；下降算法采用共轭梯度法，使用准真实资料，进行子同化数值试验和预报试验。结果表明，两套同化方案都取得了一定的同化效果，Derber同化方法比伴随同化更令人满意。证明了变分同化是提高预报准确率的一种非常有效的手段。     

南极海冰的年际变化对中国东部夏季降水的影响

根据Hadley中心提供的1969—1998年的南极海冰再分析资料和其它多种观测资料，分析了南极海冰的年际和季节变化，指出南极海冰具有显著的年际变化，但与ENSO的关系则较为复杂。南极海冰维持了南半球高纬地区大气环流的季节持续性，因而对短期气候预测有较大帮助。相关分析和时间序列分析均证实中国东部夏季降水与南极海冰的年际变化有关，当北半球春夏季南极海冰增多时，华北降水增多而华南和东北降水减少。研究还表明，此种雨型分布与南极海冰变化引起的东亚夏季风环流变化有关。     

河南省区域经济、金融空间结构变化对比分析

基于泰尔指数和GIS地图分析技术,对河南区域经济和区域金融空间结构变化做对比分析.结果表明:金融业的空间集聚度远大于一般产业,在强大的金融集聚经济作用下,区域经济发展与区域金融发展会表现出显著差异.2000年以来,河南省辖市市区经济实力相对下降,而金融集聚功能上升;县域经济显著发展,而金融发展普遍滞后,郑州市日益成为全省金融服务业的集聚地.金融空间流动带来现代城市的快速成长、功能彰显和激烈竞争,而此种努力的结果往往会抑制一些区域的金融发展,特别是县域和农村地区,需要统筹区域金融中心和乡村普惠金融建设.