United Arab Emirates limestones: impact of petrography on thermal behavior

The thermal behavior of selected limestones from representative localities of the United Arab Emirates is investigated for their suitability for soft-burnt lime production. The limestone samples were collected from the Ghalilah, Musandam, Shauiba, Muthaymimah, Dammam and Asmari formations. The samples were characterized for petrography, mineral and chemical composition, together with physico-mechanical characteristics. Investigative methods included transmitted light microscopy (TLM), cathodoluminescence (CLM) and scanning electron microscopy (SEM), as well as X-ray micro-tomography (μ-CT), XRD, XRF and Archimedes method. The limestone samples were fired in an electrical muffle furnace for 0.25, 0.5, 1 and 2 hours at 800, 900, 1,000 and 1,100 °C. After firing the lime grains were tested to determine their hydration rate and microfabric. The Ghalilah and Musandam limes show the lowest and highest maximum hydration rates, respectively, due mainly to the impure nature of the former, and the smaller lime crystallites and dominance of post-calcination micro-cracks of the latter. The Dammam and Asmari limes preserve a “ghost” microfabric of the original limestone. Higher allochem contents impose lower activation energy requirements for calcination, which implies earlier calcination of the allochems. The Musandam, Shauiba and Muthaymimah limestones may be useful for the production of reactive soft-burnt lime under the applied firing conditions, however, the Dammam and Asmari limestones need more advanced calcination conditions than the applied ones. The Ghalilah limestone was found to be unsuitable for the production of lime.     

Spatial and Temporal Variability of Sediment Organic Matter Recycling in Two Temperate Eutrophicated Estuaries

This paper deals with the spatial and seasonal recycling of organic matter in sediments of two temperate small estuaries (Elorn and Aulne, France). The spatio-temporal distribution of oxygen, nutrient and metal concentrations as well as the organic carbon and nitrogen contents in surficial sediments were determined and diffusive oxygen fluxes were calculated. In order to assess the source of organic carbon (OC) in the two estuaries, the isotopic composition of carbon (δ ¹³C) was also measured. The temporal variation of organic matter recycling was studied during four seasons in order to understand the driving forces of sediment mineralization and storage in these temperate estuaries. Low spatial variability of vertical profiles of oxygen, nutrient, and metal concentrations and diffusive oxygen fluxes were monitored at the station scale (within meters of the exact location) and cross-section scale. We observed diffusive oxygen fluxes around 15 mmol m^?2 day^?1 in the Elorn estuary and 10 mmol m^?2 day^?1 in the Aulne estuary. The outer (marine) stations of the two estuaries displayed similar diffusive O₂ fluxes. Suboxic and anoxic mineralization was large in the sediments from the two estuaries as shown by the rapid removal of very high bottom water concentrations of NO _x ^? (>200 μM) and the large NH₄ ⁺ increase at depth at all stations. OC contents and C/N ratios were high in upstream sediments (11–15 % d.w. and 4–6, respectively) and decreased downstream to values around 2 % d.w. and C/N ≤ 10. δ ¹³C values show that the organic matter has different origins in the two watersheds as exemplified by lower δ ¹³C values in the Aulne watershed. A high increase of δ ¹³C and C/N values was visible in the two estuaries from upstream to downstream indicating a progressive mixing of terrestrial with marine organic matter. The Elorn estuary is influenced by human activities in its watershed (urban area, animal farming) which suggest the input of labile organic matter, whereas the Aulne estuary displays larger river primary production which can be either mineralized in the water column or transferred to the lower estuary, thus leaving a lower mineralization in Aulne than Elorn estuary. This study highlights that (1) meter scale heterogeneity of benthic biogeochemical properties can be low in small and linear macrotidal estuaries, (2) two estuaries that are geographically close can show different pattern of organic matter origin and recycling related to human activities on watersheds, (3) small estuaries can have an important role in recycling and retention of organic matter.     

Nuclear geophysical logging for Gondwana coal exploration: a case study at Phulbari Coal Basin, northern part of Bangladesh

Different methods of lithology predictions from geophysical data have been developed in the last 15 years, among which the conventional logs are as follows: sonic, neutron–neutron, natural gamma, and density (backscattered gamma–gamma). This article concentrates on the nuclear geophysical suite, in particular, gamma and gamma–gamma logging, which, to date, provide the most accurate geophysical means of identifying coal seams and estimating their thickness. From the gamma and gamma–gamma logs of boreholes AEN 002, 007, 044, 045, 063, 085, and 105, which were carried out at the Phulbari Coal Basin of Bangladesh, two coal seams—upper and main with two lower seams of limited occurrence and of varying thickness—were identified, together with their regional occurrence.     

Application of VES and TDEM techniques to investigate sea water intrusion in Sidi Abdel Rahman area, northwestern coast of Egypt

The present study is an approach to detect the sea/freshwater interface in Sidi Abdel Rahman area, northwestern coast of Egypt using both vertical electrical sounding and time domain electromagnetic. The measured vertical electrical soundings are interpreted in 1D and 2D manner. The 1D inversion is carried out using the commercial software (RESIST), whereas 2D resistivity nonlinear iterative inversion scheme based on the finite element technique and regularization method was used. The time domain electromagnetic stations are interpreted using Temixxl-4 software by Interpex Ltd. To have the advantages of the vertical electrical sounding in shallow depths and time domain electromagnetic in deep depths, a joint inversion algorithm is applied for the electric profile and the nearby electromagnetic profile. Very low resistivity values have been observed near the coast as well as a considerable salt/fresh water interface. The tip-top portion of the interface lies approximately 1,000 m from the shore line.     

A typical weathering profile of granitic rock in Johor,Malaysia based on joint characterization

Arabian Journal of Geosciences - One of the most important challenges in the study of slope stability, foundation, and excavation in rocks is understanding the weathering states. This issue is more...     

Electromagnetic effects on the orbital motion of a charged spacecraft

This paper deals with the effects of electromagnetic forces on the orbital motion of a spacecraft.The electrostatic charge which a spacecraft generates on its surface in the Earth’s magnetic field will be subject to a perturbative Lorentz force.A model incorporating all Lorentz forces as a function of orbital elements has been developed on the basis of magnetic and electric fields.This Lorentz force can be used to modify or perturb the spacecraft’s orbits.Lagrange’s planetary equations in the Gauss variational form are derived using the Lorentz force as a perturbation to a Keplerian orbit.Our approach incorporates orbital inclination and the true anomaly.The numerical results of Lagrange’s planetary equations for some operational satellites show that the perturbation in the orbital elements of the spacecraft is a second order perturbation for a certain value of charge.The effect of the Lorentz force due to its magnetic component is three times that of the Lorentz force due to its electric component.In addition,the numerical results confirm that the strong effects are due to the Lorentz force in a polar orbit,which is consistent with realistic physical phenomena that occur in polar orbits.The results confirm that the magnitude of the Lorentz force depends on the amount of charge.This means that we can use artificial charging to create a force to control the attitude and orbital motion of a spacecraft.     

The Use of Polyphenolic Compounds from Black Tea for the Solid Phase Extraction and Determination of Trace Iron in Drinking Water

A simple and selective solid phase extraction procedure for the trace analysis of iron(III) in water samples has been developed. Sodium dodecyl sulfate coated alumina, modified with polyphenolic compounds (extracted from black tea) was used for the extraction and preconcentration of iron(III) from water samples before determination by flame atomic absorption spectrometry. Due to the complexation reaction between iron(III) and polyphenol compounds, iron(III) was quantitatively extracted on the proposed sorbent and then eluted by 2.0 mL of HCl (1.0 mol/L). The effects of extraction parameters, such as pH and volume of sample solution, amount of polyphenolic compounds, type of eluting agent and the effect of interfering ions on the extraction of iron(III), were investigated. It was found that the proposed method had a good linear range (15.0–100.0 μg/L) and a low detection limit (10.0 μg/L). The procedure was successfully applied for iron determination in drinking water samples.     

Feed forward neural network and interpolation function models to predict the soil and subsurface sediments distribution in Bam,Iran

An application of the artificial neural network (ANN) approach for predicting mean grain size using electric resistivity data from Bam city is presented. A feed forward back propagation network was developed employing 45 sets of input data. The input variables in the ANN model are the electrical resistivity, water table as a Boolean value and depth; the output is the mean grain size. To demonstrate the authenticity of this approach, the network predictions are compared with those from interpolation methods and the same data. This comparison shows that the ANN approach performs better results. The predicted and observed mean grain size values were compared and show high correlation coefficients. The ANN approach maps show a high degree of correlation with well data based grain size maps and can therefore be used conservatively to better understand the influence of input parameters on sedimentological predictions.     

Reproductive biology of blood cockle <Emphasis Type="Italic">Anadara granosa</Emphasis> (Bivalvia: Arcidae) in the northern region of the Strait of Malacca

A study on the reproductive cycle of the blood cockle Anadara granosa (Bivalvia: Arcidae) was conducted at three different areas in the northern region of the Strait of Malacca. A total of 1,920 samples of adult A. granosa (38–71 mm length) were collected from June 2009 until September 2010. Qualitative techniques (gonadal microscopic fresh smear test and histology analysis) as well as quantitative techniques (analysis of condition index and gonadal index) were used to predict monthly gonadal development stages of A. granosa. The gonadal index of A. granosa from Banda Aceh (Indonesia) (r = 0.469, P > 0.05) and Pulau Pinang (Malaysia) (r = 0.123, P > 0.05) did not show any correlation to their condition index, whereas the gonadal index of A. granosa from Lhokseumawe (Indonesia) (r = 0.609, P < 0.05) showed moderate positive correlation to the condition index. During the 16 month sampling period, four reproductive cycles were observed: each from three to six months. The process of releasing gametes is termed dribble spawning, and is the same in all populations. The principle component analysis (PCA) indicated that A. granosa reproduction was affected by interaction between internal physiological factors and indigenous environmental factors. In all sampling areas, phytoplankton density played a key role in the reproductive cycle in A. granosa. Information on the reproductive biology of this species is essential for species management and to improve the sustainability practices of the fisheries industry. These findings will provide basic information on the biology of the blood cockle A. granosa for stock management in the region.     

Ar-Ar Geochronology in a gneiss dome within the Zagros Orogénic Belt

Exhumation of the Tutak mantled gneiss dome without significant cooling has taken place in a doubly plunging anticline within the Sanandaj-Sirjan HP-LT metamorphic belt in the Zagros Thrust System of Iran. Reconstruction of structural evolution of the Tutak gneiss dome at the contact between Arabian and Iranian plates by ⁴⁰Ar/³⁹Ar geochronology exhibits history of the closure of Neo-Tethyan Ocean. There are two granites of different ages in the core of dome; the oldest corresponds to the central Iranian continental crust and was deformed at about 180 Ma. The younger granite was emplaced in the NE–SW transpression system. The timing of strain-related fabrics and exhumation history of the region illustrates the closure of Neo-Tethys and beginning of continent-continent collision at about 77 Ma, as constrained by a well defined plateau ⁴⁰Ar/³⁹Ar age obtained on biotite. Then, the biotite age corresponds to the second stage of emplacement of the Bendenow granite-gneiss which illustrating repeated orogenic events. Continuing deformation without interruption that by now has been created at about 77 Ma, was largely restricted to the transpression and high proportion of simple shear components relative to the pure shear components along the NE–SW.