Mesoscale and macroscale aspects of the morning Urban Heat Island around Athens,Greece

Summary This paper examines the characteristics of the morning Urban Heat Island (UHI) in Athens basin, Greece. The study is performed by using and analyzing mesoscale and synoptic data covering the period 1990–2001. The UHI was estimated using the 0600 Local Time (LT) minimum temperature differences between rural and urban areas of the city. The analysis results in 7 UHI classes. A strong UHI was found for the 1/3 of days. The specific meteorological characteristics (surface and upper air, cooling rate) of each UHI class were revealed and examined. The spatial and temporal characteristics of the UHI were also identified. The UHI is largest on nights with clear skies and low relative humidity. In all seasons the UHI switches on rapidly in afternoon. During spring and summer, sea breeze commonly reduces and delays the UHI. Cases documenting the sensitivity and rapidity of changes of the UHI to changes in classes (cloud cover, wind) are also presented. The cooling rate is higher in the urban area under negative and lower under positive UHI conditions. Mesoscale and macroscale phenomena were examined during the different UHI classes through a weather type scheme. It was emerged that high UHI classes are associated with anticyclonic conditions or advection in the lower troposphere, while low UHI classes are associated with strong northeasterly winds. Anticyclonic conditions which frequently occur in spring and early summer, reduce or reverse the UHI to Urban Cooling Island.     

Post-breakup basaltic magmatism along the East Greenland Tertiary rifted margin

Mafic and ultramafic intrusions in East Greenland adjacent to the offshore Greenland–Iceland ridge were emplaced 5–9 My after continental breakup at 55 Ma [1]. Rare earth element (REE) concentrations determined by secondary ion mass spectrometry are reported for cumulus clinopyroxene from these intrusions, and the data are used to estimate REE abundance in equilibrium melts using available partitioning data. Estimated equilibrium melts from intrusions have strongly fractionated REE patterns with Nd/Dy(N) in the range 2 to 5.6 and Yb/Dy(N) 0.55 to 0.92, similar to values for coeval basalts. These melts have markedly higher Nd/Dy(N) than earlier breakup related flood basalts. The moderately low Yb/Dy(N) for the post-breakup volcanism is indicative of residual garnet in the source, while their high Nd/Dy(N) ratios can best be explained by aggregating low degree melts from a light-REE-enriched garnet- and spinel-bearing mantle source. We also report He, Sr, and Nd isotopic data for the intrusions. The highest ³He/⁴He ratios (>10 R/R_a) are found in the samples whose REE data reflect the largest proportion of melts from a garnet-bearing source, and having Sr and Nd isotopic compositions identical with the radiogenic Sr and unradiogenic Nd isotope end of the Iceland compositional field. There is no indication of a MORB-type mantle in the source of the intrusions. We postulate that post-breakup volcanism along the East Greenland coastline reflects the increasing proximity of the mantle plume to the East Greenland continental margin. The low degree of melting at high mean pressure inferred for the parental melts for the intrusions may reflect re-thickening of the lithosphere, which in turn was caused by the vigorous volcanism during breakup, with accompanying depletion of upper mantle and underplating of the crust at the continental margin.     

Covariations in oceanic dimethyl sulfide,its oxidation products and rain acidity at Amsterdam Island in the Southern Indian Ocean

Simultaneous measurements of rain acidity and dimethyl sulfide (DMS) at the ocean surface and in the atmosphere were performed at Amsterdam Island over a 4 year period. During the last 2 years, measurements of sulfur dioxide (SO₂) in the atmosphere and of methane sulfonic acid (MSA) and non-sea-salt-sulfate (nss-SO₄ ^2-) in rainwater were also performed. Covariations are observed between the oceanic and atmospheric DMS concentrations, atmospheric SO₂ concentrations, wet deposition of MSA, nss-SO₄ ^2-, and rain acidity. A comparable summer to winter ratio of DMS and SO₂ in the atmosphere and MSA in precipitation were also observed. From the chemical composition of precipitation we estimate that DMS oxidation products contribute approximately 40% of the rain acidity. If we consider the acidity in excess, then DMS oxidation products contribute about 55%.     

Theoretical Modeling of the Regular Olivine Intergrowths in Mimetic Paramorphs from Ringwoodite and Wadsleyite

This work presents the results of theoretical modeling of regular misorientations of olivine grains in mimetic paramorphs from ringwoodite and wadsleyite, whose formation is expected during the rise of material from the mantle transition zone. The coordinates of the axes and angles of misorientation, which characterize ten operations of alignment in the pair intergrowths of olivine grains, eight of which are twins, are calculated. Possible conditions for the formation of the predicted mimetic paramorphs and the chances of their preservation are discussed. The calculated orientations are compared with the known olivine twin laws.     

Hydrodynamics and sediment dynamics of The Wash embayment, eastern England

Water and sediment movement in The Wash embayment has been determined from an extensive set of data, consisting of tidal current readings and suspended sediment concentration measurements. Instantaneous and residual currents in the embayment show a distinct lateral inhomogeneity, whereas vertically the water column is almost homogenous. The central deep water area (30–40 m) of the embayment is dominated by a residual landward water movement, whilst on the margins, the residual movement is seaward. Sediment is supplied predominantly in suspension from the north, through the northern extremity of Boston Deep. Suspended sediment pathways are coincident with the spring tide water movements and the subtidal channels act as the main conduits. Approximately 6·8 × 10⁶ tonnes yr^?1 of suspended sediments are supplied to the embayment from offshore areas. Bedload sediment supply is of lesser importance, ～ 1·4 × 10⁴ tonnes yr^?1. Whereas suspended sediment movement appears to be the dominant mode of transport throughout the embayment, bedload transport is important in reforming the sea bed into a variety of bedforms which are particularly well developed on the margins of channels and shoals.     

The stratospheric sulfate aerosol layer: Processes,models, observations,and simulations

After briefly reviewing the observational data on the stratospheric sulfate aerosol layer, the chemical and physical processes that are likely to fix the properties of the layer are discussed. We present appropriate continuity equations for aerosol particles, and show how to solve the equations on a digital computer. Simulations of the unperturbed aerosol layer by various published models are discussed and the sensitivity of layer characteristics to variations in several aerosol model parameters is studied. We discuss model applications to anthropogenic pollution problems and demonstrate that moderate levels of aerospace activity (supersonic transport and space shuttle operations) will probably have only a negligible effect on global climate. Finally, we evaluate the possible climatic effect of a ten-fold increase in the atmospheric abundance of carbonyl sulfide.     

Ar–Ar age determinations of eclogitic clinopyroxene and garnet inclusions in diamonds from the Venetia and Orapa kimberlites

Ar–Ar age measurements are reported for selected eclogitic clinopyroxene and garnet inclusions in Orapa diamonds and clinopyroxene inclusions in Venetia diamonds. Laser drilling of encapsulated clinopyroxene inclusions within Venetia diamonds released a maximum of 3% of the total ⁴⁰Ar, indicating little diffusive transfer and storage of radiogenic ⁴⁰Ar at the diamond–inclusion boundary. Apparent ages obtained during stepped heating of three diamonds are consistent with diamond crystallisation occurring just prior to the kimberlite eruption 520 Ma ago. Stepped heating of three clinopyroxene-bearing Orapa diamonds gave ages of 906–1032 Ma, significantly above the eruption age, but consistent with previously determined isotopic ages. A few higher apparent ages hint at the presence an older generation of Orapa diamonds that formed >2500 Ma ago. Orapa garnets also contain measurable K contents, and record a range of ages between 1000 and 2500 Ma. The old apparent ages and lack of significant interface ⁴⁰Ar released by the laser probe, suggests that pre-eruption radiogenic ⁴⁰Ar and mantle-derived ⁴⁰Ar components are trapped in microinclusions within the pyroxene and garnet inclusions.     

Lettau’s Contribution to the Obukhov Length Scale: A Scientific Historical Study

Boundary-Layer Meteorology - It has been repeatedly assumed that Heinz Lettau found the Obukhov length in 1949 independently of Obukhov in 1946. However, it was not the characteristic length scale,...