Polybrominated diphenyl ethers and their methoxylated analogs in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) from Bizerte Lagoon, Tunisia

Concentrations of ten polybrominated diphenyl ethers (PBDEs) and eight methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from the Bizerte Lagoon and the Mediterranean Sea were investigated. To the best of our knowledge, this is the first report of these compounds in marine fishes from Tunisia. The PBDE mean concentrations in fish from Bizerte Lagoon were 45.3 and 96.2 ng g(-1) lw respectively in mullet and sea bass, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea were 7.80 and 27.9 ng g(-1) lw respectively. MeO-PBDE concentrations in mullet and sea bass from Bizerte Lagoon ranged from 6.46 to 286 ng g(-1) lw and from 49.4 to 798 ng g(-1) lw respectively, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea ranged from 190 to 401 ng g(-1) lw and from 353 to 578 ng g(-1) lw respectively. The total PBDEs and total MeO-PBDEs concentration in fish from Bizerte Lagoon were similar or slightly lower than those reported for other species from other locations around the world.     

Mean and extreme characteristics of Moscow climate at the end of the 20th century

Characteristics are presented of climate in Moscow, as obtained from instrumental observations since 1879 at the stations of the Timiryazev Agricultural Academy and of Moscow State University’s Meteorological Observatory. Changes in meteorological elements are estimated for the period 1961–1990 along with tendencies of their changes during the 20th century and the first half of the 21st century.     

Mean wind-direction shear through a forest canopy

The equations of motion applying to the wind field in a forest canopy are simplified to a balance between the shearing stress gradient and either the form-drag of the leaves in the upper dense canopy, or the overall horizontal pressure gradient in the more open space beneath. The equations imply that, in descending through the forest, the stress and wind vectors turn through an angle which depends on the forest characteristics and on the stability and the speed of the airflow above the forest. The turning is roughly confirmed by an overall average measured on a very flat site near Thetford, Norfolk, covered by an extensive uniform pine forest.     

Some evaluations of drag and bulk transfer coefficients over water bodies of different sizes

Three recent experiments allow evaluation of the bulk transfer coefficients for momentum, water vapour and sensible heat over water bodies of different sizes. As part of a study of evaporation rates from a swamp, measurements of latent and sensible heat fluxes were made over Lake Wyangan in southern N.S.W., Australia. This lake is of several kilometers diameter. In a later experiment, Reynolds stress and sensible heat transfer were measured from a natural-gas platform standing in Bass Strait, south of mainland Australia. The most recent experiment involved the direct measurement of each of these turbulent fluxes from a fixed tower erected in Lake Michigan, U.S.A.Perhaps the most important of the results is the finding that drag coefficients measured over Bass Strait are not significantly different from those over Lake Michigan, despite the obvious differences in depth, fetch, and hence surface wave structure. At both locations, drag coefficients are found to increase slightly with increasing wind speed, while at low wind speeds they are not significantly different from those corresponding to aerodynamic smoothness.Near-neutral bulk transfer coefficients for sensible heat and for water vapour are found to be similar. An average value of about 1.4 × 10^–3 is obtained.It is emphasized that stability effects should be considered in any discussion of drag coefficients or bulk transfer coefficients. Large errors can result if near-neutrality is incorrectly assumed.     

Lake-Sediment Records of Recent Environmental Change on Svalbard: Results of Diatom Analysis

Surface sediments from 23 lakes on Svalbard were analysed for diatoms. About 182 taxa were found but samples generally have a low richness, with the majority of sites dominated by benthic genera such as Fragilaria, Navicula, and Achnanthes. Centric Cyclotella species occur at only three sites. Modern relationships between diatom abundance and water chemistry and other environmental variables were explored numerically and a preliminary transfer function for pH was developed. Lakes fell into three groups on the basis of their diatom assemblages: (1) high pH, high cation, high conductivity sites characterised by Amphora libyca, (2) shallow sites with relatively high nutrient values characterised by Fragilaria species, and (3) more acid and dilute sites with high amounts of snow cover in the catchments characterised by small Achnanthes species and Navicula digitulus. Five sediment cores representing the recent past were also analysed for diatoms. Three shallow sites were dominated by Fragilaria species throughout the period represented by the cores and no shifts in inferred pH were found. At two deeper sites (Arresjøen, Birgervatnet) major assemblage shifts are found which are unrelated to independent evidence for atmospheric contamination. Early (ca. 1200 AD) changes found at both sites are possibly related to the onset of the ‘Little Ice Age’. Later changes are neither synchronous nor similar in nature and might be best explained as individual responses to the recovery from the ‘Little Ice Age’ and subsequent climatic warming.     

Climatic control on the growth of gigantic gypsum crystals within hypogenic caves (Naica mine,Mexico)?

Three hypogenic caves within the Naica mine of Mexico (Cueva de los Cristales — CLC, Ojo de la Reina — OR, and Cueva de las Velas — CLV) host spectacular gypsum crystals up to 11 m in length. These caves are close to another shallow cave of the area (Cueva de las Espadas — CLE), with which they cover a 160 m-deep vertical section of the local drainage basin. Similar to other hypogenic caves, all these caves lack a direct connection with the land surface and should be unrelated with climate.A record of multi-technique fluid inclusion data and pollen spectra from cave and mine gypsum indicates surprisingly that climatic changes occurring at Naica could have controlled fluid composition in these caves, and hence crystal growth. Microthermometry and LA-ICP-Mass Spectrometry of fluid inclusions indicate that the shallow, chemically peculiar, saline fluid (up to 7.7 eq. wt.%NaCl) of CLE could have formed from evaporation, during a dry and hot climatic period. The fluid of the deep caves was instead of low salinity (～ 3.5 eq. wt.% NaCl) and chemically homogeneous, and was poorly affected by evaporation. We propose that mixing of these two fluids, generated at different depths of the Naica drainage basin, determined the stable supersaturation conditions for the gigantic gypsum crystals to grow. Fluid mixing was controlled by the hydraulic communication between CLE and the other deep caves, and must have taken place during cycles of warm-dry and fresh-wet climatic periods, which are known to have occurred in the region. Pollen grains from a 35 ka-old gypsum crystal of CLC corresponds to a fairly homogenous catchment basin made of a mixed broadleaf wet forest, which suggests precipitation during a fresh-wet climatic period and confirms our interpretation of the fluid inclusion data.The unusual combination of geological and geochemical factors of Naica suggests that other hypogenic caves found elsewhere may not host similar crystals. However, this work shows that fluid inclusions and pollen spectra represent a useful tool for cave studies in general, and if used in future studies might be essential to unravel the mechanisms of hypogenic deposition.     

Predicting lake water quality responses to load reduction: a three-dimensional modeling approach for total maximum daily load

Water quality restoration efforts often suffer the risk of ineffectiveness and failure due to lack of quantitative decision supports. During the past two decades, the restoration of one of China’s most heavily polluted lakes, Lake Dianchi, has experienced costly decision ineffectiveness with no detectable water quality improvement. The governments are planning to invest tremendous amount of funds in the next 5 years to continue the lake restoration process; however, without a quantitative understanding between the load reduction and the response in lake water quality, it is highly possible that these planned efforts would suffer the similar ineffectiveness as before. To provide scientifically sound decision support for guiding future load reduction efforts in Lake Dianchi Watershed, a sophisticated quantitative cause-and-effect response system was developed using a three-dimensional modeling approach. It incorporates the complex three dimensional hydrodynamics, fate and transport of nutrients, as well as nutrient-algae interactions into one holistic framework. The model results show that the model performs well in reproducing the observed spatial pattern and temporal trends in water quality. The model was then applied to three total maximum daily load scenarios and two refined restoration scheme scenarios to quantify phytoplankton responses to various external load reduction intensities. The results show that the algal bloom in Lake Dianchi responds to load reduction in a complex and nonlinear way, therefore, it is necessary to apply the developed system for future load reduction and lake restoration schemes for more informed decision making and effective management.     

Geostatistical characterization of soil moisture and chloride distribution in deep vadose profiles of the Badain Jaran Desert,Northwestern China

Geostatistical analysis of soil moisture and ion accumulation can provide a deep understanding of aspects of a region’s hydrology such as recharge rates and flow paths. By combining this approach with detrended canonical correspondence analysis, the present study investigated the vertical and spatial variation of soil moisture and chloride (Cl^?) in vadose profiles of megadunes near lakes in the southeastern Badain Jaran Desert, northwestern China. Soil moisture varied vertically within the dune profiles following exponential, logarithmic, or log-normal distributions at different sites as a result of regulation by different local controls. The main local controls for Cl^? concentration were slope and orientation of the dune. Cl^? was not affected by local controls at depths >5 m. Sills of spatial variation in soil moisture and Cl^? in the variogram analysis were highly sensitive to local controls in the top 4 m of the profiles, and the values were three times those at depths >4 m. The lag for soil moisture was insensitive to local controls, and was 50–60 m in the top 4 m of the profiles and 20 m in deeper layers, whereas the lag for Cl^? was about 20 m at all depths. The results demonstrate that understanding recharge rates using factors such as Cl^? accumulation requires a careful survey to ensure that the local controls that regulate these factors are adequately accounted for.