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911.
We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite
to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol)
has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical
signals on the amount of substance undergoing the reduction process.
Received December 21, 1995/Revised, accepted June 29, 1996 相似文献
912.
We present a solid solution model, able to take into account short-range interactions up to the third nearest neighbor. This
model has been applied to illite/smectite mixed-layer clay minerals and tests the relative thermodynamic stability of each
illite/smectite stacking sequence. The non-ideal energy terms have been calculated, showing a strong decrease of the interaction
energy as the distance between elements grows. From ΔG
m calculations the model predicts the following succession in I/S stacking sequences as X
i
tends to 1:R1, R2 and then R3. This succession agrees well with some mineralogical observations in natural series.
Received: July 12, 1996 / Revised, accepted: March 21, 1997 相似文献
913.
Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds
varying in SiVI:SiIV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported
by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of SiVI/(SiVI+SiIV): (1) A linear relationship between the L2,3-L1 splitting and SiVI/(SiVI+SiIV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied
to both Si K- and L-edge ELNES spectra.
Received: February 10, 1997 / Revised, accepted: May 23, 1997 相似文献
914.
915.
916.
C. Peirce R. B. Whitmarsh R. A. Scrutton B. Pontoise F. Sage J. Mascle 《Geophysical Journal International》1996,125(3):781-795
During May 1990 and January-February 1991, an extensive geophysical data set was collected over the Côte d'Ivoire-Ghana continental margin, located along the equatorial coast of West Africa. The Ghana margin is a transform continental margin running subparallel to the Romanche Fracture Zone and its associated marginal ridge—the Côte d'Ivoire-Ghana Ridge. From this data set, an explosive refraction line running ∼ 150 km, ENE-WSW between 3°55'N, 3°21'W and 4°23'N, 2°4'W, has been modelled together with wide-angle airgun profiles, and seismic reflection and gravity data. This study is centred on the Côte d'Ivoire Basin located just to the north of the Côte d'Ivoire-Ghana Ridge, where bathymetric data suggest that a component of normal rifting occurred, rather than the transform motion observed along the majority of the equatorial West African margin.
Traveltime and amplitude modelling of the ocean-bottom seismometer data shows that the continental Moho beneath the margin rises in an oceanward direction, from ∼ 24 km below sea level to ∼ 17 km. In the centre of the line where the crust thins most rapidly, there exists a region of anomalously high velocity at the base of the crust, reaching some 8 km in thickness. This higher-velocity region is thought to represent an area of localized underplating related to rifting. Modelling of marine gravity data, collected coincident with the seismic line, has been used to test the best-fitting seismic model. This modelling has shown that the observed free-air anomaly is dominated by the effects of crustal thickness, and that a region of higher density is required at the base of the crust to fit the observed data. This higher-density region is consistent in size and location with the high velocities required to fit the seismic data. 相似文献
Traveltime and amplitude modelling of the ocean-bottom seismometer data shows that the continental Moho beneath the margin rises in an oceanward direction, from ∼ 24 km below sea level to ∼ 17 km. In the centre of the line where the crust thins most rapidly, there exists a region of anomalously high velocity at the base of the crust, reaching some 8 km in thickness. This higher-velocity region is thought to represent an area of localized underplating related to rifting. Modelling of marine gravity data, collected coincident with the seismic line, has been used to test the best-fitting seismic model. This modelling has shown that the observed free-air anomaly is dominated by the effects of crustal thickness, and that a region of higher density is required at the base of the crust to fit the observed data. This higher-density region is consistent in size and location with the high velocities required to fit the seismic data. 相似文献
917.
Periodicity of magnetic intensities in magnetic anomaly profiles: the Cenozoic of the South Atlantic
Spectral analyses of several published magnetic anomaly profiles from Candé & Kent (1992a) were undertaken prior to analysing, in the same way, raw magnetic anomaly data from similar parts of the South Atlantic. It was found that similar and distinct medium and short wavelengths were present in both the published and raw data. When these are converted into the time domain using the average rate of spreading for each profile, these periodicities appear similar, possibly identical, to those expected from the long-term eccentricity orbital parameters (Fischer, DeBoer & Premoli Silva 1990). While such correlations are not necessarily causative, they suggest that magnetohydro-dynamical processes near the core-mantle boundary may be affected by gravitational changes due to planetary orbital perturbations. 相似文献
918.
Vineyards in New Zealand are pushing further south than anywhere else in the Southern Hemisphere, this despite poor understanding of the latitudinal limits of grape growing. European experience shows a limit of 50oN. Valuable pointers and cautionary tales from Germany encourage a view that the southern limit in New Zealand may be 45oS. This is broadly confirmed by comparative climate data from Germany and New Zealand. 相似文献
919.
Both ‘tanka’ and ‘beri’, the well-like structures made for storing drinking water fetched from distant places or superficially charged from the runoff water of the monsoon rains, are considered integral components of rural communities in the Thar Desert of Rajasthan State in north-western India.A. stephensi, the confirmed malaria vector in desert regions, breeds in these structures predominantly. 相似文献
920.
Coloradoapos;s 1992 vote on Amendment Two was the first meaningful, broad-based test of attitudes on gay rights within the United States. Analysis of voting results distinguishes places of tolerance from places of rejection. Social differences separating these places reflect typical contrasts between “traditionalists” and “modernizers” found in cultural conflicts at the national level. Places showing support for gay rights are recreational-based mountain communities, urban areas, and university communities. Those showing opposition are rural, agriculturally based communities. Suburban areas produced a more ambivalent vote. 相似文献