Th sorption and export models in the water column: A review

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.     

Regime shifts and fishery management

Understanding regime shifts is important to management. Optimal allocation of fishery effort can be improved if it were known whether or not the regime was positive or negative. This determination is difficult because a high recruitment, when the stock is at a low level of abundance (or vice versa), may be the indication of the onset of a multidecadal regime shift, or just a chance occurrence. Accordingly, the determination of an increase or decrease in productivity from observations independent of those made directly on fish populations is important.     

On the calculation of the depth of the upper mixed layer in the equatorial ocean

The equation for the turbulence kinetic energy balance as applied to the horizontally-inhomogeneous upper ocean layer encompassing the equatorial zone is analysed. A partial solution of the equation has been derived for the equilibrium conditions. Using the equatorial Atlantic as an example, the prime importance of considering the effect of horizontal heterogeneity in calculating the upper mixed layer thickness is shown.Translated by Vladimir A. Puchkin.     

Late Quaternary Evolution of Amvrakikos Gulf,Western Greece

Amvrakikos Gulf is a Neogene basin, formed during a late extensional tectonic phase within the Plio-Quaternary period. It is a semienclosed embayment, separated from the Ionian Sea by a shallow (< 10 m) channel. The analysis of 3.5-kHz seismic reflection profiles shows that, during the last (Würm) glacial period, the parts of the Gulf that lie at water depths >41 m (below present sea level) were a paleo-lake while the rest were exposed to subaerial erosion. Subsequent offshore depositional sequences accumulated at rates of 1.2–2.3 m/ka.     

Response of the blue mussel Mytilus edulis L. following exposure to PAHs or contaminated sediment

The polycyclic aromatic hydrocarbons fluoranthene and benzo(a)pyrene significantly reduced the feeding rate of mussels. For both compounds the tissue concentration resulting in a 50% reduction of the clearance rate (TEC₅₀) was calculated. At high tissue concentrations both aromatic compounds reduced the tolerance of mussels to aerial exposure, whereas at low tissue concentrations an improved response was noticed. The activities of the antioxidant enzymes Superoxide dismutase (SOD) and catalase were elevated only at low tissue concentrations of fluoranthene and benzo(a)pyrene. At the highest measured tissue concentrations the activity of both enzymes was reduced, possibly due to a narcotic effect. The reproductive success rate of mussels appeared to be affected negatively by the investigated hydrocarbons. The results of a pilot experiment indicate that mussels can be used also for the testing of contaminated sediments.     

An overview and general results of the Lopez island OBS experiment

The purpose of the experiment was to determine the effects of coupling and bottom currents on ocean bottom seismometers. Twelve operational OBSs, three specially designed three-component systems, and a hydrophone were compared with each other. Unlike seismometers placed on hard rock at land stations, ocean bottom seismometers can be affected by soft sediments (which act as lossy mechanical springs) and by buoyancy. Coupling through soft sediments can modify the response to ground motion much as a low pass filter does, and high buoyancy tends to counteract this effect. These effects are observed in the Lopez data, which consist of signals from mechanical transient tests, cap shots, airgun pulses, and general background noise. The modification of response is pronounced for some instruments and barely noticeable in others. Instruments that stand high in the water relative to their base width tend to be susceptible to rocking motion that shows up as a mechanical cross coupling between horizontal and vertical motion. Correlation of Lopez results with coupling theory suggests that it is possible to design ocean bottom seismometers that will couple well to any sediment. Current levels at the Lopez site (<5 cm s^-1) were too small to produce noticeable effect on any of the instruments; however, the same design criteria that will minimize coupling problems will also lessen problems caused by ocean currents.Hawaii Institute of Geophysics Contribution No. 1171.     

Topography and a magnetic analysis of an area south-east of the Azores (36°N, 23°W)

A detailed survey of a 1°×1°-square of seafloor 100 miles south-east of the Azores shows a strong correlation between directions of regional topographic and magnetic lineations. The area is dissected by the East Azores Fracture Zone at 36°55BASELINE" BORDER="0">N, identified as the active Eurasian-African plate boundary, and by another large, non-active fracture zone at 36°10BASELINE" BORDER="0">N. Both fracture zones strike 265° and are accompanied by large amplitude magnetic anomalies. The general strike in the area in between is 000°–015°. The skewing effect at this magnetic latitude is very sensitive to variations in strike of the magnetic contrasts. This effect was eliminated by a non-linear transformation which also gives the positions of magnetic contrasts. Some N-S contrasts were identified as sea floor spreading polarity contrasts (anomalies 31 and 32). Weak contrasts could be identified as topographic effects and gave a magnetization intensity of 5 A m^-1. The identified sea floor spreading anomalies to both sides of the fracture zone at 36°10BASELINE" BORDER="0">N agree very well, also quantatively, with a three-dimensional model for the fracture zone anomalies. This model describes the non-linear anomalies as end effects of the magnetic layer which is divided in blocks of alternating polarity.     

Radium and lead-210 in marine barite

Measurements of ²²⁶Ra and ²¹⁰Pb in barite samples separated from different depths of a piston core from the eastern equatorial Pacific are reported. ²²⁶Ra is enriched in the barite as would be expected from the chemistries of Ra and Ba; the ${}^{226}\text{Ra}\text{<font color="red">B</font>a}$ ratio centers around 1.5 · 10¹⁴ atoms/mole. The results suggest that barite is concentrating Ra at a rate comparable to its decay rate, viz. 5.78 · 10^?3 yr^?1. The gross ²¹⁰Pb depletion with respect to ²²⁶Ra is indicative of ²²²Rn loss due to the smallness of the barite crystals.