Development of a new connection for precast concrete walls subjected to cyclic loading

The Industrialized Building System (IBS) was recently introduced to minimize the time and cost of project construction. Accordingly, ensuring the integration of the connection of precast components in IBS structures is an important factor that ensures stability of buildings subjected to dynamic loads from earthquakes, vehicles, and machineries. However, structural engineers still lack knowledge on the proper connection and detailed joints of IBS structure construction. Therefore, this study proposes a special precast concrete wall-to-wall connection system for dynamic loads that resists multidirectional imposed loads and reduces vibration effects (PI2014701723). This system is designed to connect two adjacent precast wall panels by using two steel U-shaped channels (i.e., male and female joints). During casting, each joint is adapted for incorporation into a respective wall panel after considering the following conditions: one side of the steel channel opens into the thickness face of the panel; a U-shaped rubber is implemented between the two channels to dissipate the vibration effect; and bolts and nuts are used to create an extension between the two U-shaped male and female steel channels. The developed finite element model of the precast wall is subjected to cyclic loads to evaluate the performance of the proposed connection during an imposed dynamic load. Connection performance is then compared with conventional connections based on the energy dissipation, stress, deformation, and concrete damage in the plastic range. The proposed precast connection is capable of exceeding the energy absorption of precast walls subjected to dynamic load, thereby improving its resistance behavior in all principal directions.     

Seismic based characterization of total organic content from the marine Sembar shale,Lower Indus Basin,Pakistan

The exploration and production of unconventional resources has increased significantly over the past few years around the globe to fulfill growing energy demands. Hydrocarbon potential of these unconventional petroleum systems depends on the presence of significant organic matter; their thermal maturity and the quality of present hydrocarbons i.e. gas or oil shale. In this work, we present a workflow for estimating Total Organic Content (TOC) from seismic reflection data. To achieve the objective of this study, we have chosen a classic potential candidate for exploration of unconventional reserves, the shale of the Sembar Formation, Lower Indus Basin, Pakistan. Our method includes the estimation of TOC from the well data using the Passey’s ΔlogR and Schwarzkofp’s methods. From seismic data, maps of Relative Acoustic Impedance (RAI) are extracted at maximum and minimum TOC zones within the Sembar Formation. A geostatistical trend with good correlation coefficient (R²) for cross-plots between TOC and RAI at well locations is used for estimation of seismic based TOC at the reservoir scale. Our results suggest a good calibration of TOC values from seismic at well locations. The estimated TOC values range from 1 to 4% showing that the shale of the Sembar Formation lies in the range of good to excellent unconventional oil/gas play within the context of TOC. This methodology of source rock evaluation provides a spatial distribution of TOC at the reservoir scale as compared to the conventional distribution generated from samples collected over sparse wells. The approach presented in this work has wider applications for source rock evaluation in other similar petroliferous basins worldwide.     

An efficient Co-ZSM-5 catalyst for the abatement of volatile organics in air: effect of the synthesis protocol

Co supported on ZSM-5 (Co-ZSM-5) catalysts was synthesized by wet ion exchange (WIE), impregnation (IM), and in situ hydrothermal (IHT) methods. Their adsorptive catalytic activities for the removal of VOC’s [Benzene, Toluene, Ethylbenzene and Toluene (BTEX)] in air were tested. The physicochemical properties were investigated by XRD, FTIR, SEM, XPS, and low-temperature N₂ adsorption. The results indicate that the catalytic performance of Co-ZSM-5 for VOC’s abatement is effective and the synthesis methods reasonably influence the catalytic activity of Co-ZSM-5. Among three samples prepared by three different methods, the catalyst synthesized by the hydrothermal method possesses the highest adsorptive catalytic activity for BTEX oxidation. The optimized contact time was 60 min. The catalytic activities of the prepared catalysts are varied in the order of IHT > IM > WIE based on the combined removal capacity 59.24 > 34.46 > 23.82 (mg/g). For the Co-ZSM-5 WIE catalysts, the procedure has an evident effect on their catalytic performance. For example, the WIE catalysts prepared with cobalt chloride (II) by ion exchange have a higher acidity and surface area than the catalyst prepared with cobalt chloride (II) by impregnation method but less cobalt content. The excellent performance of IHT catalysts may be endorsed to the better availability of the oxidized form (Co³⁺), due to high content, higher surface area and acidity. Moreover, the Co-ZSM-5 catalyst synthesized by the IHT method shows high stability after being used.     

Effects of vegetation cover on summer climate in China during 1982–2001

In this paper, we apply lagged correlation analysis to study the effects of vegetation cover on the summer climate in different zones of China, using NOAA/AVHRR normalized difference vegetation index (NDVI) data during the time period from 1982 to 2001 and climate data of 365 meteorological stations across China (precipitation from 1982 to 2001 and temperature from 1982 to 1998). The results show that there are positive correlations between spring NDVI and summer climate (temperature and precipitation) in most zones of China; these suggest that, when the vegetation cover increases, the summer precipitation will increase, and the lagged correlations show a significant difference between zones. The stronger correlations between NDVI in previous season and summer climate occur in three zones (Mid-temperate zone, Warm-temperate zone and Plateau climate zone), and this implies that vegetation changes have more sensitive feedback effects on climate in the three zones in China. Supported by the National 973 Program of China (No.2006CB701300), the National Natural Science Foundation of China (No.40721001), the Sino-Germany Joint Project (No. 2006DFB91920), the Open Fund of Shanghai Leading Academic Discipline Project (T0102) and the Open Fund of LIESMARS, Wuhan University.     

Spatial trends of dry spells over Peninsular Malaysia during monsoon seasons

This study aims to trace changes in the dry spells over Peninsular Malaysia based on the daily rainfall data from 36 selected rainfall stations which include four subregions, namely northwest, west, southwest, and east for the periods of 1975 to 2004. Six dry spell indices comprising of the main characteristics of dry spells, the persistency of dry events, and the frequency of the short and long duration of dry spells will be used to identify whether or not these indices have increased or decreased over Peninsular Malaysia during the monsoon seasons. The findings of this study indicate that the northwestern areas of the Peninsular could be considered as the driest area since almost all the indices of dry spells over these areas are higher than in the other regions during the northeast (NE) monsoon. Based on the individual and the field significant trends, the results of the Mann–Kendall test indicate that as the total number of dry days, the maximum duration, the mean, and the persistency of dry days are decreased, the trend of the frequency of long dry spells of at least 4 days is also found to decrease in almost all the stations over the Peninsula; however, an increasing trend is observed in the frequency of short spells in these stations during the NE monsoon season. On the other hand, during the southwest monsoon, a positive trend is observed in the characteristics of dry spells including the persistency of two dry days in many stations over the Peninsula. The frequency of longer dry periods exhibits a decreasing trend in most stations over the western areas during both monsoon seasons for the periods of 1975 to 2004.     

Runoff Estimation and Morphometric Analysis for Hesaraghatta Watershed Using IRS–1D LISS III FCC Satellite Data

The study area, Hesaraghatta watershed is located between 77° 20′ to 77° 42′ E longitude and 13° 10′ to 13° 24′ N latitude with an area of 600.01 km². Thematic layers such as Land Use/Land Cover, drainage, soil and hydrological soil group were generated from IRS–1D LISS III satellite data (FCC). An attempt was made to estimate runoff using Soil Conservation Service (SCS) curve number model and it was estimated to be 1960, 2066, 1870 and 1810 mm for sub-watersheds 1, 2, 3 and 4 respectively. Quantitative morphometric analysis was carried out for the entire watershed and the four sub-watersheds independently by estimating their (a) linear aspects like stream order, stream length, stream length ratio, bifurcation ratio, length of overland flow, drainage pattern (b) aerial aspects like shape factor, circulatory ratio, elongation ratio and drainage density and (c) relief aspects like basin relief, relief ratio, relative relief and ruggedness number. Drainage density was estimated to be 1.23 km/km² designating the study area as a very coarse textured watershed.     

The geochronology and petrogenesis of Walash volcanic rocks,Mawat nappes: constraints on the evolution of the northwestern Zagros suture zone,Kurdistan Region,Iraq

Geological, geochemical, and geochronological investigations of the upper volcanics (UV) of Lower allochthon (LA) of Mawat nappes (MN) were used to elucidate the geologic relationships between the LA, the Qulqula Rise (i.e., accretionary complex terrane (ACT)) and peripheral Foreland Basin Assemblage (FBA), (Maastrichtian–Paleogene). The ⁴⁰Ar-³⁹Ar geochronological data suggest that the Middle to Late Paleogene magmatic history of Late Walash arc volcanic activity of UV can be divided into an early phase of andesitic volcanism around 43.1?±?0.3 Ma and subsequent extensional arc phase magmatism of a time lapse between 40.1?±?0.3and 32.3?±?0.4 Ma. The geochemical data establish the existence of gradients in trace element ratios (i.e., Ba/La, Th/Yb, U/La, Ba/Th, Rb/Y, Ba/Y, and Nb/Y) throughout the studied samples and reflect differences in the degree of mantle wedge depletion influenced by addition of a considerable proportion of sedimentary derived input of the subducting Arabian slab. The trace, rare earth elements and isotopes of the studied samples have emphasized differences in the geochemical characteristics of andesites in comparison with other members of Walash. The andesites have subduction-related signature with the isotope (low Nd and high Sr isotope ratios) characteristic of a melt component input from cratonically-derived sediments. The diabases intruding in the basalts and andesites have a transitional composition from andesitic to N-type mid-ocean ridge basalts geochemistry with a noticeable subduction-related signature, and are interpreted to form in an extensional arc evolving into back arc basin setting. As evidenced from infant arc magmatism (Albian–Cenomenian), MN recorded protracted kinematic at convergent plate margins with a most notable was the development of the ACT (i.e., Qulqula Rise) adhered to the Arabian platform carbonates (Albian–Cenomenian) leading to the inception of peripheral FBA occurred by the erosion and unroofing of advancing ACT. Notably, the volcano flysch of Walash and Nummulite carbonate of Naopurdan were still accumulating on the remaining oceanic lithosphere further to the northeast and in part coeval with Paleogene molasses sedimentation on flexural FBA further to the southwest of the ACT.     

Mean runoff coefficient estimation for ungauged streams in the Kingdom of Saudi Arabia

Runoff coefficient estimation in ungauged watersheds has a priority for rain water harvesting and management of runoff water, for domestic and agriculture activities, in semi-arid and arid regions. To estimate mean runoff coefficient (C _Re) for ungauged streams, Pearson's coefficient of linear correlation (r) was measured. The method of linear regression (y?=?mx?+?c) was applied for 16 gauged catchments representing several regions in the Kingdom of Saudi Arabia, such as Al Qassim, Al Madinah, Riyadh, Asir, Makkah, and Jazan. The studied catchments were equally divided into two groups based on their main streams slopes; group A includes eight gauged streams having main stream slope less than 0.01, where group B includes eight gauged streams having main stream slope equal to or greater than 0.01. The result yields the constant of the linear regression for each group and the mean runoff coefficient of basin by an independent value (basin slope) for group A and an independent value (stream slope) for group B. The results indicate that the measured runoff coefficient (C _Rm) and the estimated runoff coefficient (C _Re) are almost equal to each other.