Validation of the Meteosat Second Generation (MSG) fire monitoring product using ground observations over Turkey

Validation of the active fire monitoring (FIR) product from Spinning Enhanced Visible and Infrared Imager sensor of Meteosat Second Generation satellite is performed over Turkey. Ground truth data from the Ministry of Environment and Forestry for the years 2007, 2008, and 2009 is used by taking the active fire months of April–September into consideration. The contingency tables are obtained on a monthly basis and categorical statistics of probability of detection (POD) and false alarm rate (FAR) are derived. The results are introduced for each subclass, namely probable, possible, and combined cases. The highest POD amounts of 8.5, 1.93, and 9.4 % are obtained for the possible, probable, and combined cases, respectively, with the lowest FAR amounts of 70.9, 4.5, and 86.1 % for the same categories. FIR product validation with respect to predefined burnt area thresholds is introduced in the second part of the study in order to investigate burnt area effect in active fire detection. Increasing POD values with respect to burnt area amount is obtained with relatively higher values in probable than possible type. On the other hand, FAR variation is observed to be not correlated with the burnt area amount.     

A New Modification to the Chemical Mass Balance Receptor Model for Volatile Organic Compound Source Apportionment

In this study, a modification to the chemical mass balance (CMB) receptor model presented in an earlier work was expanded to account for the changes in volatile organic compound (VOC) source fingerprints due to atmospheric reactions of VOCs that take place after being emitted to the atmosphere. The photochemical reactions consume VOCs that participate in, causing changes in the source fingerprints. These changes are of considerable magnitude when the travel durations from the source to the receptor (measurement point) are considered. The current study focuses on expansion of the integrated reaction rates of VOCs with ambient reactive species such as OH ^? , O₃, NO₃, and O ^? in order to estimate the source emission profiles simultaneously at the receptor site. Two test cases with different travel times and with different ambient OH ^? , O₃, and NO₃ concentrations were also provided to compare the standard model, the modified model suggested in the previous work, and the current modification. F‐tests were also performed to determine whether the changes in source compositions are significant or not. The results from both the standard model and the modified model were evaluated in terms of χ², R², percent mass apportioned (MA), and a best fit (BF) measure. Maximum values of BF for the test cases from the three models were 0.70 ± 0.03, 0.74 ± 0.05, and 1.000 ± 0.00, respectively, indicating that the current modification increases the performance of two previous models and was better in explaining the effects of chemical reactions of VOCs.     

Evaluation of groundwater quality in the Cihanbeyli basin, Konya, Central Anatolia, Turkey

The Cihanbeyli basin is located in the northern part of Konya in the Central Anatolian region, Turkey and is characterized by semi-arid climatic conditions and scarcity in water resources. The suitability of groundwater quality for drinking and agricultural purposes in the Cihanbeyli basin was assessed by measuring physicochemical parameters, including major cation and anion compositions, pH, total dissolved solid, electrical conductivity, and total hardness. For this purpose, 54 samples were collected from different sources viz. deep wells, shallow wells, and springs. Results from hydrochemical analyses reveal that groundwater is mostly affected by salty and gypsiferous lithologies. Evaporite minerals such as gypsum, anhydrite, and chloride salts make high contributions from the recharge areas (west, northwest, and southwest parts) toward the discharge area (central and eastern parts). High values of total dissolved solids in groundwater are associated with high concentrations of all major ions. A comparison of groundwater quality in relation to drinking water standards showed that most of the water samples are not suitable for drinking. Based on sodium absorption ratio values and percent sodium, salinity appears to be responsible for the poor groundwater quality, rendering most of the samples unsuitable for irrigation usage. It is concluded that evaporation and mineral dissolution are the main processes that determine major ion compositions.     

The influence of capillarity on multiphase flow within porous media: a new model for interpreting fluid levels in groundwater monitoring wells in dynamic aquifers

A new approach is presented to calculate the volume of oil in the underground at an oil spill site from fluid levels in monitoring wells. The approach includes the effects of hysteresis due to irregular pore geometry and to phase entrapment. It is possible to explain the drastic changes in the oil thickness in a monitoring well due to the decrease and increase in the groundwater table. A correct evaluation of the oil volume infiltrated underground from an oil spill and the effective control of remediation works can only be done by using the newly developed approach with a consideration of the dynamic changes in the groundwater table.     

Evolution of the Palaeotethys in the Eastern Mediterranean: a multi-method approach to unravel the age,provenance and tectonic setting of the Upper Palaeozoic Konya Complex and its Mesozoic cover sequence (south-central Turkey)

ABSTRACT

Siliciclastic sediments from the Upper Palaeozoic Konya Complex and its Mesozoic cover were studied by a multi-method approach combining thin-section petrography, bulk-rock geochemistry, mineral chemistry of rutile, and U–Pb geochronology of detrital zircons. Provenance sensitive data of samples from the Upper Palaeozoic Hal?c? Formation indicate sediment supply from mainly low- to medium-grade metamorphosed sedimentary rocks of felsic character, while the contribution from volcanic rocks was rare. The detrital zircon record of sediments from the Hal?c? Formation documents sediment supply from different sources and excludes a similar provenance. Some samples show great similarities with Palaeozoic sandstones from the cover sequence of the Saharan Metacraton and the Arabian–Nubian Shield, while the other samples indicate a provenance that must be sought in units with a southern Eurasian affinity. The upper limit for sediment deposition in the Hal?c? Formation is mostly constrained by Early Palaeozoic zircon populations; however, sediment accumulation in Pennsylvanian–Cisuralian time is more likely, contemporaneously with the Upper Palaeozoic succession on the Karaburun Peninsula (western Turkey). The provenance of sediments from the Upper Triassic Ard?çl? Formation remains enigmatic, but the source should be sought nonetheless in units close to the depositional site. In any case, detrital zircon age spectra and compositional data exclude recycling of underlying rock units (i.e. Hal?c? Formation). Overall, our new provenance data reveal great similarities between the Konya Complex and comparable units (Chios, Karaburun) but also highlight distinct differences in terms of sediment composition and provenance.     

Geochemical and petrographic studies of Ta mineralization in the Nuweibi albite granite complex, Eastern Desert, Egypt

The Nuweibi albite granite is one of 14 known Sn-Ta-Nb bearing granitoids in the Eastern Desert region of Egypt. The granite is a highly leucocratic, albite-rich rock with accessory columbite-tantalite, cassiterite, microlite and ixiolite as well as topaz, garnet and white mica. Ages of 450–600 Ma were obtained from zircons by the ²⁰⁷Pb/²⁰⁶Pb evaporation method. Great uncertainty is caused by the small size and poor quality of the grains, but the precision is sufficient to indicate that the granite is late- or postorogenic with respect to the Panafrican orogeny. The Nuweibi granite is divided into a western and an eastern part by a regional fault. Both parts of the granite are compositionally similar but there are important differences and a clear compositional gap between them, so they are considered separate facies of an intrusive complex. The eastern part of the granite is more highly mineralized, has higher modal albite contents and higher Ta/Nb ratios, both in the whole rock and in the ore minerals. It is suggested that the two parts of the granite evolved from a common source and were emplaced sequentially, the eastern part representing a later, more fractionated magma. Textural evidence strongly suggests that the granite has a magmatic origin overall, but disturbance of geochemical trends at the whole-rock scale and at the scale of zoning profiles in individual grains of columbite-tantalite indicate post-magmatic overprinting. By analogy with other Ta-bearing albite granites, the sodic bulk composition of the Nuweibi granite can be explained by fluorine enrichment in the magma. Fluorine contents in the magma were high enough to stabilize topaz, and muscovites contain 2–4 wt.%. F. However, whole-rock F contents are low. We speculate that the low Ca, Al and P contents of the magma prevented abundant F-bearing minerals to form and led to loss of fluorine to now-eroded roof rocks. Received: 8 November 1995 / Accepted: 10 June 1996     

Nonlinear meta-models for conceptual seakeeping design of fishing vessels

The scope of this paper is to develop the nonlinear meta-models for seakeeping behaviour, considering the fishing vessels. These models are intended to be inserted either in a multiattribute design selection process or in a comprehensive multiobjective optimization procedure. For this purpose, seakeeping data of fishing vessels in regular head waves are used to develop meta-models of transfer functions of heave, pitch and vertical acceleration by nonlinear analysis. A home-made software considers two databases; the first is composed by the ship dimensions and coefficients of fishing vessels, and the second is their ship motion data obtained by employing a strip-theory calculation. The meta-models are proposed to predict the vertical motion characteristics for given ranges of speed and wave length during the concept design stage. The independent variables are hull size (Δ), main dimensions (L, B, T), and some hydrostatic parameters (C_WP, C_VP, LCB, LCF, etc.). The results estimated by the software show good correspondences with the ones achieved by direct computations. The study provides additional insight on the influence of hull form parameters on seakeeping performance of small vessels having form properties and parametric range corresponding to the investigated vessels.     

Spatially weighted principal component analysis (PCA) method for water quality analysis

Incorporating spatial information data into the principal component analysis is of importance. Some proposed methods of spatial weighting schemes to be applied to the ordinary PCA are reviewed and a new version of the method is proposed in the context of spatial analysis for geospatial multivariate analysis. In view of spatial variations in the hydrochemistry of rivers such combined version of the technique might be useful for reliable estimates.     

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 2: application to Taupo Volcanic Zone rhyolites

Constraining the pressure of crystallisation of large silicic magma bodies gives important insight into the depth and vertical extent of magmatic plumbing systems; however, it is notably difficult to constrain pressure at the level of detail necessary to understand shallow magmatic systems. In this study, we use the recently developed rhyolite-MELTS geobarometer to constrain the crystallisation pressures of rhyolites from the Taupo Volcanic Zone (TVZ). As sanidine is absent from the studied deposits, we calculate the pressures at which quartz and feldspar are found to be in equilibrium with melt now preserved as glass (the quartz +1 feldspar constraint of Gualda and Ghiorso, Contrib Mineral Petrol 168:1033. doi: 10.1007/s00410-014-1033-3. 2014). We use glass compositions (matrix glass and melt inclusions) from seven eruptive deposits dated between ~320 and 0.7 ka from four distinct calderas in the central TVZ, and we discuss advantages and limitations of the rhyolite-MELTS geobarometer in comparison with other geobarometers applied to the same eruptive deposits. Overall, there is good agreement with other pressure estimates from the literature (amphibole geobarometry and H₂O–CO₂ solubility models). One of the main advantages of this new geobarometer is that it can be applied to both matrix glass and melt inclusions—regardless of volatile saturation. The examples presented also emphasise the utility of this method to filter out spurious glass compositions. Pressure estimates obtained with the new rhyolite-MELTS geobarometer range between ~250 to ~50 MPa, with a large majority at ~100 MPa. These results confirm that the TVZ hosts some of the shallowest rhyolitic magma bodies on the planet, resulting from the extensional tectonic regime and thinning of the crust. Distinct populations with different equilibration pressures are also recognised, which is consistent with the idea that multiple batches of eruptible magma can be present in the crust at the same time and can be tapped simultaneously by large eruptive events.