Comparison of Two Sample Preparation Methods for X‐Ray Fluorescence Spectrometry in the Determination of Ni and Cr

Pressed powder pellets and fused beads or glass disks are routinely used in X‐ray fluorescence spectrometry for the determination of major and trace elements, respectively, in geological materials. In order to evaluate the performance of these two sample preparation methods, we determined Ni and Cr concentrations of fourteen RMs from Japan, France and South Africa, and eighty‐five igneous and three sedimentary rock samples from Mexico in both powder pellets and glass beads. We also computed new values of statistical parameters for RMs from an outlier‐based multiple‐test method and compared them with the literature mean and confidence limit values. The results showed that the multiple‐test method provided more reliable central tendency and dispersion parameters for RMs than those obtained previously from the two or three standard deviation method, or from robust methods. The powder pellet and fused bead sample preparation methods provided consistent results for Ni and Cr at concentration levels > 50 μg g^?1 in this application; for lower concentration levels, however, these methods showed somewhat greater differences. For quantitative comparisons, both ordinary and weighted least‐squares linear regression models were used to show that the two sample preparation methods provided generally unbiased results.     

Selection of bioindicators in coal-contaminated soils of Dhanbad,India

Coal handling, crushing, washing, and other processes of coal beneficiation liberate coal particulate matter, which would ultimately contaminate the nearby soils. In this study, an attempt was made to determine the status of soil bio-indicators in the surroundings of a coal beneficiation plant, (in relation to a control site). The coal beneficiation plant is located at Sudamudih, and the control site is 5 km away from the contaminated site, which is located in the colony of Central Institute of Mining and Fuel Research Institute, Digwadih, Dhanbad. In order to estimate the impact of coal deposition on soil biochemical characteristics and to identify the most sensitive indicator, soil samples were taken from the contaminated and the control sites, and analyzed for soil organic carbon (SOC), soil N, soil basal respiration (BSR), substrate-induced respiration (SIR), and soil enzymes like dehydrogenase (DHA), catalase (CAT), phenol oxidase (PHE), and peroxidase (PER). Coal deposition on soils improved the SOC from 10.65 to 50.17 g kg⁻¹, CAT from 418.1 to 804.11 μg H₂O₂ g⁻¹ h⁻¹, BSR from 8.5 to 36.15 mg CO₂–C kg⁻¹ day⁻¹, and SIR from 24.3 to 117.14 mg CO₂–C kg⁻¹ day⁻¹. Soils receiving coal particles exhibited significant decrease in DHA (36.6 to 4.22 μg TPF g⁻¹ h⁻¹), PHE (0.031 to 0.017 μM g⁻¹ h⁻¹), PER (0.153 to 0.006 μM g⁻¹ h⁻¹), and soil N (55.82 to 26.18 kg ha⁻¹). Coal depositions significantly (P < 0.01) decreased the DHA to 8.8 times, PHE to 1.8 times, and PER to 25.5 times, but increased the SOC to 4.71 times, CAT to 1.9 times, SIR to 4.82 times, and BSR to 4.22 times. Based on principal component analysis and sensitivity test, soil peroxidase (an enzyme that plays a vital role in the degradation of the aromatic organic compounds) is found to be the most important indicator that could be considered as biomarkers for coal-contaminated soils.     

Phylogenetic diversity of carbohydrate degrading culturable bacteria from Mandovi and Zuari estuaries,Goa, west coast of India

Coastal and estuarine waters are highly productive and dynamic ecosystems. The complex carbohydrate composition of the ecosystem would lead to colonisation of microbial communities with abilities to produce an array of complex carbohydrate degrading enzymes. We have examined the abundance and phylogenetic diversity of culturable bacteria with abilities to produce complex carbohydrate degrading enzymes in the Mondovi and Zuari eustauri. It was interesting to note that 65% of isolated bacteria could produce complex carbohydrate degrading enzymes. A majority of these bacteria belonged to Bacillus genera followed by Vibrio, Marinobacter, Exiquinobacterium, Alteromonas, Enterobacter and Aeromonas. Most abundant bacterial genus to degrade hemicellulose and cellulose were Bacillus and Vibrio respectively. Most abundant bacterial genus to degrade hemicellulose and cellulose were Bacillus and Vibrio respectively. It was seen that 46% of Bacillus had ability to degrade both the substrate while only 14% of Vibrio had bifunctionality.     

Bianchi type-II,VIII, and IX cosmological models with matter and electromagnetic fields

We present analytic solutions of the Einstein-Maxwell equations for cosmological models of LRS Bianchi type-II, VIII, and IX. The solutions represent anisotropic universes with source-free electromagnetic fields and perfect fluids matter satisfying the equation of state that is a function of the cosmic-time. Some physical properties of the models have been discussed.     

Early Cosmological Models with Bulk Viscosity in Brans-Dicke Theory

The effect of time dependent bulk viscosity on the evolution of Friedmann models with zero curvature in Brans-Dicke theory is studied. The solutions of the field equations with ‘gamma-law’ equation of state p = (γ-1) ρ, where γ varies continuously as the Universe expands, are obtained by using the power-law relation φ = bR ⁿ , which lead to models with constant deceleration parameter. We obtain solutions for the inflationary period and radiation dominated era of the universe. The physical properties of cosmological solutions are also discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Heat and mass transfer in rotating fluid with Hall current,I

Hall effects on the hydromagnetic free convection resulting from the combined effects of thermal and mass diffusion of an electrically conducting liquid past an infinite vertical porous plate in a rotating system have been analysed. The expressions for the mean velocity, mean temperature in the boundary layer and the mean skin friction, the mean rate of heat transfer on the plate are derived. The effects of magnetic parameterM, Hall parameterm, Schmidt number Sc, and Ekman numberE on the flow field, are discussed with the help of graphs and tables.     

Plane symmetric vacuum bianchi type I cosmological model in Brans-Dicke theory

The paper presents an exact solution of the vacuum Brans-Dicke field equations for the metric tensor of a spatially homogeneous and anisotropic cosmological model. The Kasner metric is shown as a special case. Some physical properties of the model are discussed.     

Waiting Time Distribution of Emissions in Complex Coronal Mass Ejections

The waiting time distribution of emissions in Coronal Mass Ejections (CMEs) with several emissions is examined. We define the waiting time as the time interval between the commencement of an emission and the commencement of the next emission considered as parts of a unique CME. The distribution seems to follow a power-law. Two classes of CMEs several emissions are considered: “close” and “separate” depending on angular distance between emissions.     

Photometry of the galactic cluster NGC 2169

The results of photoelectricU, B, V photometry of the galactic cluster NGC 2169 are presented. The colour excessE(B-V) is 0^m.18. The distance modulus to the cluster and its age are respectively estimated at 9^m.6 and 0.9×10⁷ yr. Star No. 10 is found to be variable.