Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).     

Attenuation behaviour of tuffaceous sandstone and granite during microfracturing

Laboratory measurements of ultrasonic wave propagation in tuffaceous sandstone (Kimachi, Japan) and granite (Iidate, Japan) were performed during increasing fracturing of the samples. The fracturing was achieved by unconfined uniaxial compression up to and beyond the point of macrofracture of the specimen using a constant low strain rate. The observed variation of wave velocity (up to 40 per cent) due to the development of micro- and macrofractures in the rock is interpreted by rock models relating velocity changes to damage and crack density. The calculated density of the newly formed cracks reaches higher values for the sandstone than for the granite. Using the estimated crack densities, the attenuation behaviour is interpreted in terms of different attenuation mechanisms; that is, friction and scattering. Rayleigh scattering as described by the model of Hudson (1981 ) may explain the attenuation qualitatively if the largest plausible crack dimensions are assumed in modelling.     

Estimation of standing stock of chlorophylla and primary production from remote-sensed ocean color in the Oyashio region, the Western subarctic Pacific, during the spring bloom in 1997

In order to examine the applicability of remotely-sensed ocean color for the estimation of phytoplankton biomass and primary production in the Oyashio region, the western subarctic Pacific, vertical distributions of chlorophylla concentration and primary production were observed in April and May 1997. Spring bloom was observed in both April and May, and the surface concentration of chlorophylla exceeded 40 mg m⁻³. The relationship between the standing stocks of chlorophylla within the layer from the sea surface to one optical depth (0–1/k layer) and the surface chlorophylla concentration is expressed as a Michaelis-Menten equation. The mean ratio of the standing stock of chlorophylla in the euphotic layer to that in the 0–1/k layer was 4.41, this ratio did not significantly differ from 4.61 which was obtained at homogeneous distribution of chlorophylla within the euphotic layer. These facts suggest that the distribution of chlorophylla could be assumed to be homogeneous in the euphotic layer during the spring bloom. Results of primary production measurements by simulatedin situ method were compared with those by an algorithm with two variables; chlorphylla and non-spectral PAR. Daily primary production in the euphotic layer estimated by the algorithm varied in a range of 38–274% of that estimated by incubation, although the primary productions by the algorithm agreed with those by the incubation at a half of stations. Primary production within the euphotic layer calculated using simply the surface data was the same as that estimated using vertical distribution of chlorophylla. These results show that the primary production in the euphotic layer may be estimated from the remote sensed measurements during the spring bloom in the Oyashio region.     

Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.     

Submarine slope–fan sedimentation in an ancient forearc related to contemporaneous magmatism: The Upper Cretaceous Izumi Group,southwestern Japan

The Izumi Group in southwestern Japan is considered to represent deposits in a forearc basin along an active volcanic arc during the late Late Cretaceous. The group consists mainly of felsic volcanic and plutonic detritus, and overlies a Lower to Upper Cretaceous plutono‐metamorphic complex (the Ryoke complex). In order to reconstruct the depositional environments and constrain the age of deposition, sedimentary facies and U–Pb dating of zircon grains in tuff were studied for a drilled core obtained from the basal part of the Izumi Group. On the basis of the lithofacies associations, the core was subdivided into six units from base to top, as follows: mudstone‐dominated unit nonconformably deposited on the Ryoke granodiorite; tuffaceous mudstone‐dominated unit; tuff unit; tuffaceous sandstone–mudstone unit; sandstone–mudstone unit; and sandstone‐dominated unit. This succession suggests that the depositional system changed from non‐volcanic muddy slope or basin floor, to volcaniclastic sandy submarine fan. Based on a review of published radiometric age data of the surrounding region of the Ryoke complex and the Sanyo Belt which was an active volcanic front during deposition of the Izumi Group, the U–Pb age (82.7 ±0.5 Ma) of zircon grains in the tuff unit corresponds to those of felsic volcanic and pyroclastic rocks in the Sanyo Belt.     

Radiolarian‐based study on the fabric and the formation process of the Early Cretaceous mélange near Zhongba,Yarlung–Tsangpo Suture Zone,southern Tibet

The Yarlung–Tsangpo Suture Zone (YTSZ), as the southernmost and youngest among the sutures that subdivides the Tibetan Plateau into several east–west trending blocks, marks where the Neo‐Tethys was consumed as the Indian continent moved northward and collided against the Eurasian continent. Mélanges in the YTSZ represent the remnants of the oceanic plate through subduction and collision. Mélanges are characterized by a highly sheared volcanoclastic or siliceous mudstone matrix including blocks of chert, claystone, and basalt. Detailed radiolarian analyses are conducted on the mélange near Zhongba County. Macroscopic, mesoscopic, and microscopic observations are combined in order to elucidate the relationships among age, lithology, and structure of blocks in the mélange. Reconstructed ocean plate stratigraphy includes Lower Jurassic limestone within the chert sequence accumulated at a depth near the CCD (Unit 2), Upper Jurassic thin‐bedded chert interbedded with claystone deposited in the wide ocean basin (Unit 3), and Lower Cretaceous chert with siliceous mudstone (Units 4 and 5), representing the middle parts of ocean plate stratigraphy. The results highlight the fabric of brecciated chert on mesoscopic scale, which is thought to be due to localized overpressure. The formation of mesoscopic and microscopic block‐in‐matrix fabrics in the mélange is proposed for the chert and siliceous mudstone bearing different extents of consolidation and competence during the progressive deformation of accreted sediments at shallow‐level subduction.     

Variations in snowmelt energy and energy balance characteristics with larch forest density on Mt Iwate,Japan: observations and energy balance analyses

The variation in snowmelt energy and energy components were evaluated with respect to forest density. Surface snowmelt rates, surface evaporation from snow cover and meteorological elements were measured in the open and under sparse (411 trees/ha) and dense (1433 trees/ha) larch canopies. The surface snowmelt rate decreased as the forest density increased. Based on the observations and energy balance analyses, we concluded the following. (1) Albedo decreased while the bulk coefficient for latent heat increased with forest density. (2) The duration of snowmelt increased with forest density because the energy for nocturnal cooling of the snow cover decreased. (3) When comparing the open and forested sites, the changes in snowmelt energy with forest density were caused by sensible heat flux. However, the contribution of net radiation was highest in the forested sites. Therefore, the effects of forest cover on the snowmelt energy were different when comparing both the open and forested sites and the sparse and densely forested sites. (4) The ratio of net radiation to snowmelt energy increased with forest density; although both snowmelt energy and net radiation decreased with increased forest density, the snowmelt energy decreased more rapidly. Sensible heat also decreased as forest density increased. Both albedo and downward long‐wave radiation influenced net radiation. Copyright © 1999 John Wiley & Sons, Ltd.     

Remote effects of mixed layer development on ocean acidification in the subsurface layers of the North Pacific

Using the outputs of projections under the highest emission scenario of the representative concentration pathways performed by Earth system models (ESMs), we evaluate the ocean acidification rates of subsurface layers of the western North Pacific, where the strongest sink of atmospheric CO₂ is found in the mid-latitudes. The low potential vorticity water mass called the North Pacific Subtropical Mode Water (STMW) shows large dissolved inorganic carbon (DIC) concentration increase, and is advected southwestward, so that, in the sea to the south of Japan, DIC concentration increases and ocean acidification occurs faster than in adjacent regions. In the STMW of the Izu-Ogasawara region, the ocean acidification occurs with a pH decrease of ~0.004 year^?1 , a much higher rate than the previously estimated global average (0.0023 year^?1), so that the pH decreases by 0.3–0.4 during the twenty-first century and the saturation state of calcite (Ω_Ca) decreases from ~4.8 down to ~2.4. We find that the ESMs with a deeper mixed layer in the Kuroshio Extension region show a larger increase in DIC concentration within the Izu-Ogasawara region and within the Ryukyu Islands region. Comparing model results with the mixed layer depth obtained from the Argo dataset, we estimate that DIC concentration at a depth of ~200 m increases by 1.4–1.6 μmol kg^?1 year^?1 in the Izu-Ogasawara region and by 1.1–1.4 μmol kg^?1 year^?1 in the Ryukyu Islands region toward the end of this century.