Ab initio study on carbon Kinetic Isotope Effect (KIE) in the reaction of CH4+Cl•

Recent studies suggest that the destruction of methane by Cl in the marine boundary layer could be accounted for as another major sink besides the methane destruction by OH. High level ab initio molecular orbital calculations have been carried out to study the CH₄+Cl reaction, the carbon Kinetic Isotope Effect (KIE) is calculated using Conventional Transition-State Theory (CTST) plus Wigner and Eckart semiclassical tunneling corrections. The calculated KIE is around 1.026 at 300 K and has a small temperature variation. This is by far the largest KIE among different processes involving atmospheric methane destruction (e.g., OH, soil). A calculated mass balance of atmospheric methane including the KIE for the CH₄+Cl reaction is found to favor those methane budgets with enhanced biological methane sources, which have relatively lighter carbon isotope composition.     

Distribution of Planetesimals around a Protoplanet in the Nebula Gas

We have developed a semi-analytic method of calculating the changes in heliocentric Keplerian orbital elements due to gravitational scattering by a protoplanet as a three-body problem. In encounters with high incident velocities, either the gravity of the protoplanet or the solar gravity can be regarded as perturbation force. In close encounters, by taking into account the solar gravity as a perturbation, we modified the two-body gravitational scattering. On the other hand, in slightly distant encounters, we apply the perturbing force of the protoplanet to the heliocentric Keplerian orbit of planetesimals. As a result, as for high-velocity encounters, the three-body problem is semi-analytically solvable. Our semi-analytic method can reproduce the numerical result of the orbital changes of individual planetesimals for the broad range of high-energy encounters with surprising high accuracy. We found that our method is valid under the conditions (i)b₀? 2 and (ii) (e²₀+i²₀− b²₀)^1/2? 4, wheree₀andi₀are eccentricity and inclination of relative motion normalized by the reduced Hill radius andb₀is the difference between semimajor axes normalized by the Hill radius. Though our method needs some numerical procedure, its cpu time is negligibly short compared with that of the direct orbital integration. In simulation of orbital evolution of planetesimals around a protoplanet in the gas, which we will perform in the subsequent paper, most encounters can be calculated by the semi-analytic method. This makes it possible to perform the long term (∼10⁵years) orbital calculation of ∼10^3–4planetesimals.     

Tephra dispersal from Myojinsho, Japan, during its shallow submarine eruption of 1952–1953

 A new and detailed bathymetric map of the Myojinsho shallow submarine volcano provides a framework to interpret the physical volcanology of its 1952–1953 eruption, especially how the silicic pyroclasts, both primary and reworked, enlarged the volcano and were dispersed into the surrounding marine environment. Myojinsho, 420 km south of Tokyo along the Izu–Ogasawara arc, was the site of approximately 1000 phreatomagmatic explosions during the 12.5-month eruption. These explosions shattered growing dacite domes, producing dense clasts that immediately sank into the sea; minor amounts of pumice floated on the sea surface after some of these events. The Myojinsho cone has slopes of almost precisely 21° in the depth range 300–700 m.We interpret this to be the result of angle-of-repose deposition of submarine pyroclastic gravity flows that traveled downslope in all directions. Many of these gravity flows resulted from explosions and associated dome collapse, but others were likely triggered by the remobilization of debris temporarily deposited on the summit and steep upper slopes of the cone. Tephra was repeatedly carried into air in subaerial eruption columns and fell into the sea within 1–2 km of the volcano's summit, entering water as deep as 400 m. Because the fall velocity of single particles decreased by a factor of ∼30 in passing from air into the sea, we expect that the upper part of the water column was repeatedly choked with hyperconcentrations of fallout tephra. Gravitational instabilities within these tephra-choked regions could have formed vertical density currents that descended at velocities greater than those of the individual particles they contained. Upon reaching the sea floor, many of these currents probably continued to move downslope along Myojinsho's submarine slopes. Fine tephra was elutriated from the rubbly summit of the volcano by upwelling plumes of heated seawater that persisted for the entire duration of the eruption. Ocean currents carried this tephra to distal areas, where it presumably forms a pyroclastic component of deep-sea sediment. Received: 5 December 1996 / Accepted: 17 September 1997     

Gaseous formic and acetic acids in the atmosphere of Yokohama,Japan

Gaseous formic acid (HCOOH_g) and acetic acid (CH₃COOH_g) were measured every 30 minutes during a 10 hour daylight period in August, and a 24 hour period in October, 1990 in the urban atmosphere of Yokohama, Japan. An aqueous nebulizer sampler and ion-chromatography exclusion (ICE) were used for the measurements. In the August experiment (0800–1800 local time) the mean HCOOH_g concentration was found to be 7.3±2.5 ppbv. The mean CH₃COOH_g concentration was 3.8±1.2 ppbv. In the 24 hour experiment in October, concentrations of both acids were lower between 0800–1800 than during the same time-period in August (mean HCOOH_g=4.4±2.7 ppbv, mean CH₃COOH_g=1.4±0.5 ppbv). In October, concentrations of both acids were higher in daylight hours than at night; sporadic high HCOOH_g concentrations were observed. In both experiments the ratio HCOOH_g/CH₃COOH_g of individual samples was usually 2.0 (mean ratio of 2.0 in August, 3.1 in October).     

ANS observations of Cygnus X-1

Cygnus X-1 was observed from 3 November until 9 November, 1974, using the hard X-ray (1–28 keV) and soft X-ray (1–8 keV) experiment on board the Astronomical Netherlands Satellite. On three occasions, on 4 and 5 November, the X-ray spectrum was observed to be harder, while the flux intensity in the 1–7 keV ranges decreased by 50% from its quiescent value. These events occurred near and following the time of superior conjunction of the likely optical counterpart HDE 226 868. These events appear to be the same as previously reported absorption dips and reveal this phenomenon to be more complex than had been believed. A systematic study of the X-ray spectral variations in these energy bands, on a time scale of 64 seconds over the period of the spectroscopic binary, is presented.Paper presented at the COSPAR Symposium on Fast Transients in X-and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.On leave from Institute of Space and Aeronautical Science, University of Tokyo.     

Measurement and analysis of magnetic field variation during a class 2b flare

We report a digital analysis of high-time-resolution videomagnetograms taken during a class 2b flare that occurred at 60° east. The data were obtained at the Big Bear Observatory and calibrated by a Mt. Wilson magnetogram. Changes of weak magnetic fields (less than 100 G) with an amplitude from 30 to 100% have been detected over 55% of the optical flare region, apparently taking place at the initial phase of the flare. Statistical considerations suggest a real flare association with most of these changes.H observations show that large changes took place over the footpoints of heavily inclined structures like penumbral fibrils, while smaller changes took place over the plage region. An apparent polarity reversal was found at the feet of erupted fibrils.Based on force-free field calculations these changes can be reasonably explained as a transformation of the current-carrying fields to potential fields which produced large changes in the field line inclination and rotation.Visiting Associate, Summer 1977.     

Heat-Mitigation Effects of Irrigated Rice-Paddy Fields Under Changing Atmospheric Carbon Dioxide Based on a Coupled Atmosphere and Crop Energy-Balance Model

Boundary-Layer Meteorology - Known as the heat-mitigation effect, irrigated rice-paddy fields distribute a large fraction of their received energy to the latent heat during the growing season. The...     

Submarine flank eruption preceding caldera subsidence during the 2000 eruption of Miyakejima Volcano, Japan

During the early part of a seismic swarm preceding eruption and caldera formation at Miyakejima Volcano, discoloured sea surfaces were observed 1.5 km off the western coast of Miyakejima on 27 June 2000. A later survey of the area using a multi-beam side scan sonar and a remotely operated small submarine revealed four craters of 20–30 m diameter aligned east-west in a 100×10–30 m area on the seafloor, with hot water at 140°C being released from one of the centres. Each crater consists of submarine spatter overlain in part by scoria lapilli. Dredged spatter from the craters was fresh, and there was no evidence of activity of marine organisms on the spatter surface, indicating that the discoloured sea surface resulted from magmatic eruption on the seafloor. This eruption occurred when a westward-propagating seismic swarm, initiated beneath Miyakejimas summit, passed through the area. Finding new magma on the seafloor demonstrates that this seismic swarm was associated with intruding magma, moving outward from beneath Miyakejima. Submarine spatter shows flattened shapes with a brittle crust formed by cooling in water, and its composition is aphyric andesite of 54 wt% SiO₂. The spatter is similar in whole rock and mineral composition to spatter erupted in 1983. However, the wide range of Cl in melt inclusions in plagioclase of the 27 June submarine spatter shows that it is not simply a remnant of the 1983 magma, which has only high Cl melt inclusions in plagioclase. The mixed character of melt inclusions suggests involvement of a magma with low Cl melt inclusions. The magma erupted explosively on 18 August from Miyakejimas summit, considered as the second juvenile magma in this eruption, contains low Cl melt inclusions in plagioclase. Based on these observations and the eruption sequence, we present the following model: (1) A shallow magma chamber was filled with a remnant of 1983 magma that had evolved to a composition of 54–55 wt% SiO₂. (2) Injection of the 18 August magma into this chamber generated a mixed magma having a wide range of Cl in melt inclusions contained plagioclase. The magma mixing might have occurred shortly before the submarine eruption and could have been a trigger for the initiation of the removal of magma from the chamber as an extensive dyke, which eventually led to caldera subsidence.Editorial responsibility: S Nakada, T Druitt     

Seed supply for coastal brackishwater shrimp farming: environmental impacts and sustainability

Globally, shrimp farming has been a significant agro-based economic activity since the early 1970s. Because it offered a huge immediate economic return, shrimp farming showed a booming expansion and soon became a multimillion dollar industry. However, it has been under extreme criticism because of its devastating ecological and socio-economic impacts. Because seed is the primary input, the impact from farming has started from the source of seed supply, so that not only are natural stocks of shrimp seeds now overexploited worldwide but seed collection activities also significantly reduce stocks of other living resources. Although hatcheries were developed as potential alternative and have replaced the natural seed source to a great extent, large-scale hatchery productions provide a potential source of coastal pollution. However, this area is still poorly studied. The present paper provides a review of the environmental impacts of the wild shrimp seed fishery as well as the possibility of environmental degradation from artificial shrimp seed production in hatcheries.     

Geographical Variation of Body Size of Neocalanus cristatus, N. plumchrus and N. flemingeri in the Subarctic Pacific and Its Marginal Seas: Implications for the Origin of Large Form of N. flemingeri in the Oyashio Area

Size distributions of Neocalanus cristatus, N. flemingeri and N. plumchrus were investigated in the eastern and the western subarctic gyres and three marginal seas of the North Pacific during the diapause period to examine the geographical variation in body size of Neocalanus species and to clarify the origin of the large biennial N. flemingeri which has been observed in the Oyashio region. There were significant among region variations in body sizes for all three species of Neocalanus. Generally, the body sizes of the copepods were larger in the marginal seas and marginal areas of the open ocean. In the open ocean, the body sizes increased westward. These patterns of variation in the body sizes roughly correlated with local food availability. Distribution of biennial N. flemingeri was restricted to the Sea of Japan, the Okhotsk Sea and the Oyashio region. The large-sized biennial N. flemingeri were abundantly observed in the Okhotsk Sea, and the medium-sized biennial individuals were observed in the Sea of Japan. These facts strongly suggest that the large biennial N. flemingeri in the Oyashio region are advected from the Okhotsk Sea.