Petrology and shock history of the first depleted-like poikilitic shergottite Asuka 12325

Asuka (A) 12325 is the first poikilitic shergottite having a depleted pattern in light rare earth elements (REE). Compared with known poikilitic shergottites, A 12325 has smaller but more abundant pyroxene oikocrysts with remarkable Fe-rich pigeonite rims, indicating that A 12325 cooled relatively faster at a shallower part of the crust. The redox condition (logfO₂ = IW + 0.6-IW + 1.7) and Fe-rich chemical compositions of each mineral in A 12325 are close to enriched shergottites. The intermediate shergottites could not form by a simple mixing between parent magmas of A 12325 and enriched shergottites. Although A 12325 contains various high-pressure minerals such as majorite and ringwoodite, plagioclase is only partly maskelynitized. Therefore, the maximum shock pressure may be within 17–22 GPa. Thermal conduction and ringwoodite growth calculation around a shock vein revealed that the shock dwell time of A 12325 is at least 40 ms. The weaker shock pressure and longer shock dwell time in A 12325 may be attained by an impact event similar to those of nakhlites and Northwest Africa (NWA) 8159. Such a weak shock ejection event may be as common on Mars as a severe shock event recorded in shergottites. Alteration of sulfide observed in A 12325 may imply the presence of magmatic fluid in its reservoir on Mars. A 12325 expands a chemical variety of Martian rocks and has a unique shock history among poikilitic shergottites while A 12325 also implies that poikilitic shergottites are common rocks on Mars regardless of their sources.     

Light utilization efficiency of phytoplankton in the Western Subarctic Gyre of the North Pacific during summer

We investigated the water-column light utilization efficiency (Ψ) of phytoplankton photosynthesis in the Western Subarctic Gyre (WSG) of the North Pacific during summer 2008. The Ψ values (0.64–1.86 g C [g Chl a]^?1 [mol photon]^?1 m²) obtained were observed to increase significantly with decreasing daily photosynthetic available radiation (PAR) and were generally higher than those of previous studies, not only from the subarctic Pacific but also from the world’s oceans. To examine the effect of iron availability on Ψ in the WSG, Ψ values were estimated from the data of two in situ iron fertilization experiments: the Subarctic Pacific Iron Experiment for Ecosystem Dynamics Study I (SEEDS-I) and II (SEEDS-II). We found that iron availability did not affect Ψ values. Overall, this study revealed that Ψ values changed remarkably in the WSG during the summer, and that higher values were found at the stations where moderate PAR levels (ca. 10–30 mol photons m^?2 day^?1) were observed and where autotrophic flagellates predominated in the phytoplankton assemblages.     

Application of an optical disdrometer to characterize simulated rainfall and measure drop-size distribution

ABSTRACT

Knowledge of rainfall characteristics such as drop-size distribution is essential for the development of erosion-mitigation strategies and models. This research used an optical disdrometer to elucidate the relationships between raindrop-size distribution, median volume drop diameter (D₅₀), kinetic energy and radar reflectivity (dBz) of simulated rainfall of different intensities. The D₅₀ values were higher for the simulated rain than for natural rain at almost all rainfall intensities, perhaps due to variations in rainfall types and the turbulence in natural rain that breaks up large drops. The kinetic energy ranged from 26.67 to 5955.51 J m^?2 h ^?1, while the median volume drop diameter (D₅₀) was in the range 1.94–7.25 mm, for intensities between 1.5 and 202.6 mm h^?1. The relationship between radar reflectivity (Z) and the intensity (R) of the simulated rain was best described by a power law function (Z = aR^b), with a and b coefficients in the ranges 162–706 and 0.94–2.46, respectively, throughout the range of rainfall intensities (1.5–202.6 mm h^?1).     

Instability of a geostrophic front and its energetics

Abstract

The instability of a current with a geostrophic surface density front is investigated by means of a reduced gravity model having a velocity profile with nearly uniform potential vorticity. It is shown that currents are unstable when the mean potential vorticity decreases toward the surface front at the critical point of the frontal trapped waves investigated by Paldor (1983). This instability is identical with that demonstrated by Killworth (1983) in the longwave limit.

The cross-stream component of mass flux and the rates of energy conversions among the five energy forms defined by Orlanski (1968) are also calculated. The main results are as follows, (a) The mass flux toward the surface front is positive near the front and negative around the critical point. The positive mass flux near the front does not vanish at the position of the undisturbed surface front, so that the mean position of the front moves outward and the region of the strong current spreads. (b) The potential energy of the mean flow integrated over the fluid is released through the work done by the force of the pressure gradient of the mean flow on the fluid, and is converted into the kinetic energy of the mean flow. (c) In the critical layer, the mean flow is rapidly accelerated with the growth of the unstable wave. This acceleration is caused by the rapid phase shift of the unstable wave in the critical layer.     

Use of a time-domain electromagnetic method with geochemical tracers to explore the salinity anomalies in a small coastal aquifer in north-eastern Tunisia

The study area is a small coastal plain in north-eastern Tunisia. It is drained by an ephemeral stream network and is subject to several pollutant discharges such as oilfield brine coming from a neighboring oil company and wastewater from Somâa city, located in the upstream of the plain. Furthermore, a hydraulic head near the coastal part of the aquifer is below sea level, suggesting that seawater intrusion may occur. A time-domain electromagnetic (TDEM) survey, based on 28 soundings, was conducted in Wadi Al Ayn and Daroufa plains to delineate the saline groundwater. Based on longitudinal and transversal resistivity two-dimensional pseudosections calibrated with boring data, the extent of saline water was identified. Geochemical tracers were combined with the resistivity dataset to differentiate the origin of groundwater salinization. In the upstream part of the plain, the infiltration of oilfield brine through the sandy bed of Wadi Al Ayn seems to have a considerable effect on groundwater salinization. However, in the coastal part of the aquifer, groundwater salinization is due to seawater intrusion and the saltwater is reaching an inland extent around 1.3 km from the shoreline. The contribution ratios of saline water bodies derived from the inverted chloride data vary for the oilfield brine from 1 to 13 % and for the seawater from 2 to 21 %.     

A compound-specific n-alkane δC and δD approach for assessing source and delivery processes of terrestrial organic matter within a forested watershed in northern Japan

We measured molecular distributions and compound-specific hydrogen (δD) and stable carbon isotopic ratios (δ¹³C) of mid- and long-chain n-alkanes in forest soils, wetland peats and lake sediments within the Dorokawa watershed, Hokkaido, Japan, to better understand sources and processes associate with delivery of terrestrial organic matter into the lake sediments. δ¹³C values of odd carbon numbered C₂₃-C₃₃n-alkanes ranged from −37.2‰ to −31.5‰, while δD values of these alkanes showed a large degree of variability that ranged from −244‰ to −180‰. Molecular distributions in combination with stable carbon isotopic compositions indicate a large contribution of C3 trees as the main source of n-alkanes in forested soils whereas n-alkanes in wetland soil are exclusively derived from marsh grass and/or moss. We found that the n-alkane δD values are much higher in forest soils than wetland peat. The higher δD values in forest samples could be explained by the enrichment of deuterium in leaf and soil waters due to increased evapotranspiration in the forest or differences in physiology of source plants between wetland and forest. A δ¹³C vs. δD diagram of n-alkanes among forest, wetland and lake samples showed that C₂₅-C₃₁n-alkanes deposited in lake sediments are mainly derived from tree leaves due to the preferential transport of the forest soil organic matter over the wetland or an increased contribution of atmospheric input of tree leaf wax in the offshore sites. This study demonstrates that compound-specific δD analysis provides a useful approach for better understanding source and transport of terrestrial biomarkers in a C3 plant-dominated catchment.