Arsenic removal from aqueous solutions by mixed magnetite–maghemite nanoparticles

In this study, magnetite–maghemite nanoparticles were used to treat arsenic-contaminated water. X-ray photoelectron spectroscopy (XPS) studies showed the presence of arsenic on the surface of magnetite–maghemite nanoparticles. Theoretical multiplet analysis of the magnetite–maghemite mixture (Fe₃O₄-γFe₂O₃) reported 30.8% of maghemite and 69.2% of magnetite. The results show that redox reaction occurred on magnetite–maghemite mixture surface when arsenic was introduced. The study showed that, apart from pH, the removal of arsenic from contaminated water also depends on contact time and initial concentration of arsenic. Equilibrium was achieved in 3 h in the case of 2 mg/L of As(V) and As(III) concentrations at pH 6.5. The results further suggest that arsenic adsorption involved the formation of weak arsenic-iron oxide complexes at the magnetite–maghemite surface. In groundwater, arsenic adsorption capacity of magnetite–maghemite nanoparticles at room temperature, calculated from the Langmuir isotherm, was 80 μmol/g and Gibbs free energy (∆G⁰, kJ/mol) for arsenic removal was −35 kJ/mol, indicating the spontaneous nature of adsorption on magnetite–maghemite nanoparticles.     

Back reaction and quantum gravity corrections of Hawking radiation from Schwarzschild-de Sitter black hole

Following the Parikh and Wilczek semiclassical tunneling method of massless particle, hawking radiation of Schwarzschild-de Sitter (SdS) black hole have been computed using null geodesic method. Purely thermal and quantum gravity corrections have been made and have shown that both the corrections give the same results and all the tunneling rates are related to change of Bekenstein-Hawking entropy of SdS black hole. The results obtained for SdS black hole are also in accordance with Parikh and Wilczek’s opinion and gives a correction to the Hawking radiation of SdS black hole.     

Legitimacy of Different Knowledge Types in Natural Resource Governance and Their Functions in Inter-Institutional Gaps

Abstract

This study expands the Inter-Institutional Gaps (IIGs) framework to conceptualize the legitimacy associated with different types of ecological knowledge (e.g., scientific, traditional and local) used in natural resource governance. We draw on primary qualitative data, and document analysis to examine a case of inland fisheries management in the north-eastern floodplain of Bangladesh. We posit that the pragmatic, moral, cognitive, and regulative legitimacy for different types of ecological knowledge are repeatedly reevaluated by rule-makers and resource users in the process of rule-devising. Results show that inter-institutional gaps may be perpetuated when formal rules do not sufficiently consider traditional and local ecological knowledge. While it is widely proposed that systematically incorporating different knowledge types can better address local-national policy problems, this study underscores that the source of legitimacies for different knowledge types often differs across formal and informal institutional actors. Recognizing the differences is critical to fishers’ resource management.     

Petrology, geochemistry and remote sensing data of island arc assemblage along Wadi Abu Marawat, Central Eastern Desert, Egypt

The basement rocks of Abu Marawat area comprise serpentinites (oldest), metavolcanics and their equivalent pyroclastics, intrusive metagabbro–diorite complex, synkinematic granitoids, Hammamat sediments and basic intrusion (youngest). Remote sensing ETM+ data of Abu Marawat area were analyzed, and band ratios technique was applied to discriminate between different varieties of these basement rocks. Serpentinites are represented by lensoidal bodies tectonically incorporated in the metavolcanics. On band ratio 5/7 image, they are characterized by very bright image signature. The metavolcanics comprise basalts, andesite and subordinate dacites together with their equivalent pyroclastics. They were regionally metamorphosed up to the greenschist facies and exhibit dark grey image signatures on band ratio 5/7 image. The metagabbro–diorite complex is made up of metagabbros, diorites and quartz diorites, whereas the synkinematic granitoids are formed of tonalites and granodiorites. The band ratio 5/7 image illustrates tonalites with dark image signature, whereas metagabbro–diorites and granodiorites exhibit grey image signature. The metavolcanic suites are of island arc setting, where metabasalts are of tholeiitic affinity, while the meta-andesites and metadacites are of calc-alkaline character. The metagabbroic and granitoid rocks are of I-type, calc-alkaline affinity and were formed in arc tectonic setting. They are enriched in LIL elements and depleted in Nb and HFS elements, a characteristic feature of subduction-related magmatism. The regular variation trends among the major and trace elements as well as the coincidence of the plotted samples favor the assumption that they are comagmatic and formed by processes such as fractional crystallization.     

Long-term trend analysis of water table using ‘MAKESENS’ model and sustainability of groundwater resources in drought prone Barind area,NW Bangladesh

In Bangladesh, agriculture plays a major role in the national economy. In the drought prone Barind area in NW Bangladesh, cropping intensity has increased almost double since late eighties of last century (from 1985) because of the introduction of groundwater irrigation. Long-term behavior of groundwater table (GWT) in the drought prone Barind area has been studied using MAKESENS model in the wake of massive installation of tube-wells. The study reveals that the maximum and minimum depths to GWT during 1991-2010 show on average declining trend of 4.51 m and 4.73 m. The long-term prediction for the period of 2020-50 assuming the current rate of groundwater withdrawal is that the declining trend will be 1.16 to 1.59 and 1.07 to 1.82 times more for maximum and minimum groundwater depths respectively in comparison to the present. The rigorous exploitation of groundwater for irrigation, decreasing rainfall and surface geological attributes lead towards declining trend of GWT. This will hamper the country’s food security and ultimately threaten its socio-economic sustainability. So the appropriate strategies for the management of groundwater resource on a sustainable basis should be the priority for maintaining agricultural productivity.     

Groundwater arsenic contamination and its health effects in India

During a 28-year field survey in India (1988–2016), groundwater arsenic contamination and its health effects were registered in the states of West Bengal, Jharkhand, Bihar and Uttar Pradesh in the Ganga River flood plain, and the states of Assam and Manipur in the flood plain of Brahamaputra and Imphal rivers. Groundwater of Rajnandgaon village in Chhattisgarh state, which is not in a flood plain, is also arsenic contaminated. More than 170,000 tubewell water samples from the affected states were analyzed and half of the samples had arsenic >10 μg/L (maximum concentration 3,700 μg/L). Chronic exposure to arsenic through drinking water causes various health problems, like dermal, neurological, reproductive and pregnancy effects, cardiovascular effects, diabetes mellitus, diseases of the respiratory and gastrointestinal systems, and cancers, typically involving the skin, lungs, liver, bladder, etc. About 4.5% of the 8,000 children from arsenic-affected villages of affected states were registered with mild to moderate arsenical skin lesions. In the preliminary survey, more than 10,000 patients were registered with different types of arsenic-related signs and symptoms, out of more than 100,000 people screened from affected states. Elevated levels of arsenic were also found in biological samples (urine, hair, nails) of the people living in affected states. The study reveals that the population who had severe arsenical skin lesions may suffer from multiple Bowens/cancers in the long term. Some unusual symptoms, such as burning sensation, skin itching and watering of eyes in the presence of sun light, were also noticed in arsenicosis patients.     

The effect of drained pre-shearing on the undrained behaviour of loose sand with a small amount of fines

Stress history is recognised to play a major role in determining stress–strain behaviour of soil in undrained shearing. Most experimental studies on the effects of stress history on undrained behaviour are mainly limited to clean sand. In this paper, an experimental study carried out to investigate the effect of stress history on the undrained behaviour of loose sand with a small amount of fines is presented. Four series of triaxial compression tests, with different types of drained stress histories to near-failure prior to commencement of undrained shearing, were conducted. The experimental results indicate that drained pre-shearing to near-failure affects significantly the undrained behaviour of loose sand. In general, the drained pre-shearing improves the subsequent undrained behaviour of loose sand to the extent that liquefaction may not occur. It is shown that the effect of drained pre-shearing cannot be explained by the reduction in void ratio induced by drained pre-shearing. However, for specimens subjected to drained pre-shearing, $ p_{{{\text{d}}0}}^{\prime } $ / $ p_{{{\text{u}}0}}^{\prime } $ can be used as a parameter for analysing the effects of preloading history. It is also shown that for different preloading histories that brought the same change in void ratio or state parameter, drained pre-shearing to near-failure is the most effective, whereas pre-compression alone is the least effective in improving subsequent undrained behaviour of loose sand.     

The Response of Macrobenthic Communities to Environmental Variability in Tropical Coastal Waters

The relative contributions of spatial and temporal fluctuations are different in shaping natural communities in a tropical coastal/estuarine system. Understanding how coastal communities respond to these fluctuations is still equivocal, and thus, available data are rare. Here, multiple analytical approaches were used to identify key spatial and temporal factors, and to quantify their relative roles in shaping a macrobenthic community through space (contamination degree, physical parameters, and sediment characteristics) and time (climatic factors, season, and year). A dataset of eight sampling times was analyzed over a period of 2 years, in which macrobenthic species abundances were sampled. A total of 33 species were identified, including 18 bivalves, 5 gastropods, and 4 crustaceans. The other taxa were less diverse. The results show that there were no significant temporal changes of macrobenthic community structure, but spatial changes were significant and synchronized with environmental factors (i.e., sediment characteristics, water depth, and the distance from anthropogenic sources). This study demonstrates that spatial factors played a primary role in structuring of macrobenthic assemblages, whereas the influence of temporal factors appeared less across geographically distinct sites. Thus, temporal variation of a coastal macrobenthic community appears to be controlled by partly different processes at different scales.