Dissolved Boron in the Tapi,Narmada and the Mandovi Estuaries,the Western Coast of India: Evidence for Conservative Behavior

The concentrations of dissolved boron have been measured during different seasons in three estuaries, the Tapi, Narmada and the Mandovi situated on the western coast of India, to investigate its geochemical behavior and inputs from the localized anthropogenic pressures of industrial effluents and sewage discharge. The measured boron concentrations in these estuaries (except the Tapi during non-monsoon) at salinity ≤0.1 fall in a narrow range?～?2–4 μmol/kg (average B?～?2.4?±?0.8 μmol/kg) within the reported wide range?～?0.1–18.6 μmol/kg for global rivers. The much higher estimate of boron concentration in the Tapi River during non-monsoon is attributed to its possible additional supply from the sewage and/or industrial effluents discharged along the river course. During monsoon, the rains seem to be a significant source of dissolved boron to all the three rivers. The distribution of dissolved boron in each estuary exhibits a conservative behavior during the seasons sampled suggestive of no measurable addition or removal of boron in the estuarine region. The orders of magnitude differences in boron concentration between the river waters and seawater, and the conservative behavior of dissolved boron indicate that its major contributor to the estuaries sampled is seawater.     

Mechanism of arrested charnockite formation at Nemmara, Palghat region, southern India

The formation of arrested charnockite is an excellent example of structurally controlled channellised fluid flow along specific sites accompanied by selective elemental mobility and mineralogical changes. The present paper recognises and focuses study on three types of arrested charnockite formation from Palghat region, namely, shear-controlled, foliation parallel and boudin-neck types, and address their spatio-temporal relations to regional-scale charnoenderbite. The shear-controlled and foliation parallel types post-date deformation and migmatisation. The boudin-neck type, on the contrary, is coeval with partial melting and followed the path of cooling and decreasing water activity in the gneiss. K-feldspar veining around plagioclase and quartz, symplectitic intergrowth of biotite+quartz after orthopyroxene and K-feldspar, and fluid inclusion data suggests the presence of alkalic supercritical brine and low-density CO₂-rich fluid during charnockite formation. Charnockite domains developed following the breakdown of hornblende, biotite and quartz are characterised by a more or less pronounced depletion of Fe, Ca, Mg and Ti and trace elements Y and Zr, compared to their counterpart gneiss. REE spectra indicate a subtle depletion in the HREE near the centre of the charnockite domain. Although close-pair samples of gneiss–charnockite are isochemical, on a scale of a few millimetres, bi-directional element movement, related to the formation of new mineral was noted. It is postulated that arrested charnockite formation developed in situ on local scale within the granitic domains of the hornblende-biotite gneiss, in the presence of CO₂-rich fluids and alkalic supercritical saline brine. This process post-dated the time of regional granulite (charnoenderbite) and large regional scale retrogression and migmatisation.     

Computation of ground motion amplification in Kolkata megacity (India) using finite-difference method for seismic microzonation

This paper presents the ground motion amplification scenario along with fundamental frequency (F ₀) of sedimentary deposit for the seismic microzonation of Kolkata City, situated on the world’s largest delta island with very soft soil deposit. A 4th order accurate SH-wave viscoelastic finite-difference algorithm is used for computation of response of 1D model for each borehole location. Different maps, such as for F ₀, amplification at F ₀, average spectral amplification (ASA) in the different frequency bandwidth of earthquake engineering interest are developed for a variety of end-users communities. The obtained ASA of the order of 3–6 at most of the borehole locations in a frequency range of 0.25–10.0 Hz reveals that Kolkata City may suffer severe damage even during a moderate earthquake. Further, unexpected severe damage to collapse of multi-storey buildings may occur in localities near Hoogly River and Salt Lake area due to double resonance effects during distant large earthquakes.     

Charnockite genesis across the Archaean–Proterozoic terrane boundary in the South Indian Granulite Terrain: Constraints from major–trace element geochemistry and Sr–Nd isotopic systematics

Major, trace element compositions and Sr–Nd isotopic characteristics of charnockitic gneisses from the Southern Granulite Terrain (SGT), South India are presented. The study region encompasses the central segment of the Cauvery Shear Zone system (CSZ) and regions within the Madurai Block (MB) immediately south of it (designated here as the CSZ/MB and MB domains). Differences in the compositions and source characteristics between charnockitic rocks of the CSZ vis-à-vis those of the CSZ/MB and MB regions are highlighted. Foremost, the charnockites and enderbites of the CSZ show highly fractionated REE patterns with positive Eu-anomalies, depleted HREE, Y and near chondritic εNd₀ and initial-⁸⁷Sr/⁸⁶Sr at ca. 2.5 Ga, consistent with hydrous partial melting of amphibolitic crust with residual garnet and hornblende for the parental melts. By contrast, modeled at ca. 1.8 Ga and 0.8 Ga, the CSZ/MB and MB charnockitic rocks, which show a wider range of Ti and P, relatively lower degree of HREE depletion, commonly negative Eu-anomalies and undepleted Y, present clear evidence for involvement of Archaean crustal components in sources of their magmatic protoliths. There is also evidence for significant intracrustal melting processes within a thickened crust at elevated temperatures between 800 and 1000 °C. Implications to the controversial Archaean–Neoproterozoic terrane boundary problem of the SGT are discussed.     

Eddies and planetary waves in the Central Arabian Sea

Eddies and planetary waves are identified as one of the important factors that control the dynamics of the Arabian Sea. During 10–14 January 1990, Ignat, Paulyuchenkov (USSR ship) conducted an experiment in the central Arabian Sea and of late TOPEX/POSEIDON satellites collected data on sea surface height (SSH) anomalies of the Arabian Sea. These data sets give an opportunity to understand the characteristic of eddies and planetary waves in this region during winter. The geostrophic flow revealed three anticyclonic and two cyclonic eddies of diameters ranging from 75 to more than 150 km from surface to subsurface levels. Current speeds around different eddies were maximum at surface and varied from 9 cm/s to 25 cm/s (at the middle point between the center and periphery). The occurrence of eddies were further investigated with the TOPEX/POSEIDON altimetry for the years 1993–97. The analysis revealed multiple eddies of diameter 100 to 550 km occur every year with maximum number of eddies during 1997 and minimum during 1995. The calculated speed varied between 8–30 cm/s around various eddies. Longitude-Time plots showed annual Rossby waves generating at the eastern Arabian Sea and propagating westwards with a phase speed of ~ 10 cm/s along 16° N. Further, it was observed that these waves arrived in the study area by January. In addition, another positive anomaly of SSH was found generating at the western Arabian Sea simultaneously and extended up to the study region by April–June. Time series of SSH at selected locations along 16°N revealed many small-scale oscillations and their spatial variability. These oscillations were delineated using the FFT analysis. Other than the Rossby wave, the major components at the study region were 40–60 and 26–32 day oscillations. The implications of these long period waves associated with eddies are discussed.     

A multi-isotope approach (O,H, C,S, B and Sr) to understand the source of water and solutes in some the thermal springs from West Coast geothermal area,India

The West Coast belt, consisting of nearly 60 thermal springs, is one of the most diversified geothermal fields in India. The present work describes the multi-isotopic (O, H, C, S, B and Sr) characterization of thermal waters carried out in the Tural-Rajwadi geothermal field, situated in southern sector of the west coast geothermal area. The aim of this study is to delineate the origin of thermal water as well as to ascertain the sources of carbon, sulphur, boron and strontium dissolved in those thermal springs. The stable isotopes (δ²H and δ¹⁸O) and tritium data indicate that these thermal springs are not recently recharged rain water rather, it contains very old component of water. Oxygen-18 shift is observed due to rock-water interaction over a long period of time. Carbon isotopic composition of DIC points out to the silicate weathering with soil CO₂ coming from C₃ type of plants whereas δ³⁴S of dissolved sulphate confirms the marine origin of sulphate. This marine signature is basically derived from paleo-seawater possibly entrapped within the flows. Boron isotopic data reveals that both the seawater and rock dissolution are the sources of boron in the thermal waters whereas high ⁸⁷Sr/⁸⁶Sr ratios (0.7220–0.7512) of the thermal waters conclusively establishes that archean granitic basement is the predominant rock source of strontium, not the Deccan flood basalts. In addition, like strontium, concentrations of lithium, rubidium and caesium are also governed by the rock-water interaction. Thus, the combined use of this multi-isotope technique coupled with trace element concentrations proves to be an effective tool to establish the sources of solutes in the thermal water.     

Nature, origin and evolution of the granitoid-hosted early Proterozoic copper-molybdenum mineralization at Malanjkhand, Central India

At Malanjkhand, Central India, lode-type copper (-molybdenum) mineralization occurs within calcalkaline tonalite-granodiorite plutonic rocks of early Proterozoic age. The bulk of the mineralization occurs in sheeted quartz-sulfide veins, and K-silicate alteration assemblages, defined by alkali feldspar (K-feldspar ≫ albite) + dusty hematite in feldspar ± biotite ± muscovite, are prominent within the ore zone and the adjacent host rock. Weak propylitic alteration, defined by albite + biotite + epidote/zoisite, surrounds the K-silicate alteration zone. The mineralized zone is approximately 2 km in strike length, has a maximum thickness of 200 m and dips 65°–75°, along which low-grade mineralization has been traced up to a depth of about 1 km. The ore reserve has been conservatively estimated to be 92 million tonnes with an average Cu-content of 1.30%. Supergene oxidation, accompanied by limited copper enrichment, is observed down to a depth of 100m or more from the surface. Primary ores consist essentially of chalcopyrite and pyrite with minor magnetite and molybdenite. δ³⁴S (‰) values in pyrite and chalcopyrite (−0.38 to +2.90) fall within the range characteristic of granitoid-hosted copper deposits. δ¹⁸O (‰) values for vein quartz (+ 6.99 to +8.80) suggest exclusive involvement of juvenile water. Annealed fabrics are common in the ore. The sequence of events that led to the present state of hypogene mineralization is suggested to be as follows: fracturing of the host rock, emplacement of barren vein quartz, pronounced wall-rock alteration accompanied by disseminated mineralization and the ultimate stage of intense silicification accompanied by copper mineralization. Fragments of vein quartz and altered wall rocks and striae in the ore suggest post-mineralization deformation. The recrystallization fabric, particularly in chalcopyrite and sphalerite, is a product of dynamic recrystallization associated with the post-mineralization shearing. The petrology of the host rocks, hydrothermal alteration assemblages, ore mineral associations, fluid inclusions and the sulfur and oxygen isotopes of ores are comparable to those in Phanerozoic (and reported Precambrian) porphyry-copper systems, and the Malanjkhand deposit has important implications for both metallogenic models for, and mineral exploration in, Precambrian terrains.     

A Case Study on Forewarning of Yellow Rust Affected Areas on Wheat Crop Using Satellite Data

Objective of this study was to identify stripe rust affected areas of wheat crop as well as evaluation of remote sensing (RS) derived indices. Moderately low temperature and high humidity favour the growth of yellow rust. Most affected areas of Punjab are the foothill districts such as Gurdaspur, Hoshiarpur and Ropar. Occurrence of yellow rust is possible when maximum temperature for day is below 15 °C and Temperature difference of day’s maximum and minimum temperature is less than 5 °C during the early growth of wheat. Forecast of the infestation was done using 3 days forecast of weather data obtained from Weather Research and Forecasting (WRF) model at 5 km resolution. Weather forecast used was obtained from Meteorological and Oceanographic Satellite Data Archival System (MOSDAC) site and post infestation, identification of specific locations were done using multi-date IRS AWiFS data. It is an attempt for early detection through 3 days advance forewarning of weather which will be handy tool for planners to expedite relief measures in case of epidemic with a more focused zones of infestation as well as for crop insurers to know the location and extent of damage affected areas.