Magnetic characteristics of sediment grains concurrently contaminated with TBT and metals near a shipyard in Busan,Korea

Bottom sediments near shipyards are often susceptible to receiving accidental spills of TBT and metals or their degradation products from hull scraping of antifouling system paints applied prior to 2008, when the AFS Convention 2001 was not in force. We investigated TBT and metal contamination of sediments near the shipyards of a small marina located in Busan, Korea and found that they were highly contaminated with TBT, Cu, and Zn. To better understand the environmental impacts and to make an optimal remediation plan, we characterized individual antifouling fragments in terms of metal and TBT contents, magnetic properties, and grain-size. Coarse-sized individual antifouling fragments exhibited simultaneously high levels of TBT, metals and high magnetic susceptibility, and appeared to be a major source of pollution in the sediment. Therefore, magnetic separation in combination with size-separation appears to be a cost-effective remediation method to remove the TBT and metals from contaminated shipyard sediments.     

Diversity of the 2014 Iquique’s foreshocks and aftershocks: clues about the complex rupture process of a Mw 8.1 earthquake

We study the foreshocks and aftershocks of the 1 April 2014 Iquique earthquake of Mw 8.1. Most of these events were recorded by a large digital seismic network that included the Northern Chile permanent network and up to 26 temporary broadband digital stations. We relocated and computed moment tensors for 151 events of magnitude Mw?≥?4.5. Most of the foreshocks and aftershocks of the Iquique earthquake are distributed to the southwest of the rupture zone. These events are located in a band of about 50 km from the trench, an area where few earthquakes occur elsewhere in Chile. Another important group of aftershocks is located above the plate interface, similar to those observed during the foreshock sequence. The depths of these events were constrained by regional moment tensor (RMT) solutions obtained using the records of the dense broad band network. The majority of the foreshocks and aftershocks were associated to the interplate contact, with dip and strike angles in good agreement with the characteristics of horst and graben structures (>2000 m offset) typical of the oceanic Nazca Plate at the trench and in the outer rise region. We propose that the spatial distribution of foreshocks and aftershocks, and its seismological characteristics were strongly controlled by the rheological and tectonics conditions of the extreme erosive margin of Northern Chile.     

Body-wave Attenuation in the Region of Garda, Italy

We analyzed the spectral amplitude decay with hypocentral distance of P and S waves generated by 76 small magnitude earthquakes (M_L 0.9–3.8) located in the Garda region, Central-Eastern Alps, Italy. These events were recorded by 18 stations with velocity sensors, in a distance range between 8 and 120 km. We calculated nonparametric attenuation functions (NAF) and estimated the quality factor Q of both body waves at 17 different frequencies between 2 and 25 Hz. Assuming a homogeneous model we found that the Q frequency dependence of P and S can be approximated with the functions Q _P = 65 f ^0.9 and Q _S = 160 f ^0.6 , respectively. At 2 Hz the Q _S /Q _P ratio reaches the highest value of 2.8. At higher frequencies Q _S /Q _P varies between 0.7 and 1.7, suggesting that for this frequency band scattering may be an important attenuation mechanism in the region of Garda. To explore the variation of Q in depth, we estimated Q at short (r ≤ 30 km) and intermediate (35–90 km) distance paths. We found that in the shallow crust P waves attenuate more than S (1.3 < Q _S /Q _P < 2.5). Moreover, P waves traveling along paths in the lower crust (depths approximately greater than 30 km) attenuate more than S waves. To quantify the observed variability of Q in depth we considered a three-layer model and inverted the NAF to estimate Q in each layer. We found that in the crust Q increases with depth. However, in the upper mantle (~40–50 km depth) Q decreases and in particular the high frequency Q _S (f > 9 Hz) has values similar to those estimated for the shallow layer of the crust.     

Long-period seismicity during magma movement at Volcán de Colima

During the period from February to September 2005, Volcán de Colima produced 30 Vulcanian explosions of sufficient magnitude to produce pyroclastic flows of variable size, with a total volume of at least 2.5 × 10⁶ m³. Swarms of long-period events were associated with each event, their duration ranging from about 6 h to 3 days and each swarm containing up to 886 events. The characteristics of the swarms have been studied to understand the source mechanism and their relationship with the Vulcanian explosions. In total, 12,548 long-period events were analysed using various comparative and statistical methods. Patterns were not apparent in the data with no correlation between different properties of the swarms (duration, magnitude or frequency of occurrence of LP events) and the magnitude of the associated Vulcanian explosion, whether recorded by seismicity, volume of pyroclastics or altitude of the eruption column. This, along with other characteristics of the swarms, such as the continuation of the swarm after the explosion, with an increase in long-period event amplitude in some cases, suggests that the mechanism is not merely associated with the pressurization under an impermeable cap and resulting pressure differentials between adjacent volumes within the system. It is more likely that the production of long-period events is dominated by brittle fracturing on the margins of an ascending magma body. A model is proposed whereby the unloading above the ascending magma column produced by a Vulcanian explosion resulted in an increase in ascent rate, reflected in the increasing amplitude of long-period events. The results reflect the complexity of non-linear processes involved during magma ascent, degassing, crystallization and rupture of the impermeable plug during the Vulcanian process. At Volcán de Colima, as at many volcanoes, long-period events represent a useful precursor for eruptive activity. For monitoring, this paper highlights some useful analyses that can be carried out, which could illustrate certain characteristics of an eruptive episode. A preliminary model is presented of the conduit processes at work during the cyclic extrusive and explosive activity during 2005.     

Spatio‐temporal variation in biomass of the deep‐sea red crab Chaceon affinis in Gran Canaria Island (Canary Islands,Eastern‐Central Atlantic)

The spatial and temporal biomass distribution of Chaceon affinis and its vulnerability to fishing activity in Gran Canaria (Canary Islands) were investigated. The first goal was to assess the influence of the slope steepness and substrate on the size of crab patches, size of the crabs, and crab biomass. The second goal was to evaluate spatial and temporal variation in the biomass over a 15‐month period. The last goal was to assess the influence of fishing activity upon the reduction in the biomass over the same 15‐month period. Only two or three locations in the sampling area generated high‐biomass contour patches. When these patches were superimposed on the isobath lines, they were coincident with the main depth range described for the species in the area. The map of the biomass values clearly showed three structures with cores of the highest biomass in both muddy and rocky‐muddy areas. The biomass was higher on muddy than on rocky‐muddy bottoms. Biomass was twice as high when steepness was reduced to one third between isobaths of 500 and 900 m. The size of crab patches increases linearly with the decrease in slope steepness. The spatial structure of crabs remained fairly stable over time, showing that biomass changes with depth over time. Maps of the estimated biomass values over the 15‐month period showed the same two main patches over time with the cores of highest biomass separated by a distance of between 4.2 and 4.5 km. Although the bathymetric distribution by sexes showed temporal changes, with a displacement to deeper areas made by both sexes over the studied period, only a partial temporal segregation between males and females was observed. During the study period, crabs underwent a significant decline in biomass and this was consistent with the combined catches of both commercial and experimental fishing in the area. Due to its low mobility, C. affinis is highly vulnerable to local depletion by intensive fishing efforts.     

Towards a better understanding of the evolution of the flood risk in Mediterranean urban areas: the case of Barcelona

This contribution explores the evolution of the flood risk in the Metropolitan Area of Barcelona (MAB; Northeast Spain) from 1981 to 2015, and how it has been affected by changes in land use, population and precipitation. To complete this study, we analysed PRESSGAMA and INUNGAMA databases to look for all the information related to the floods and flash floods that have affected the chosen region. The “Consorcio de Compensación de Seguros”, a state insurance company for extraordinary risks, provided data on economic damage. The extreme precipitation trend was analysed by the Fabra Observatory and El Prat-Airport Observatory, and daily precipitation data were provided by the State Meteorological Agency of Spain (AEMET) and the Meteorological Service of Catalonia (SMC). Population data were obtained from the Statistical Institute of Catalonia (IDESCAT). Changes in land use were estimated from the land use maps for Catalonia corresponding to 1956, 1993, 2000, 2005 and 2009. Prevention measures like rainwater tanks and improvements to the drainage system were also been considered. The specific case of Barcelona is presented, a city recognised by United Nations International Strategy for Disaster Reduction as a model city for urban resilience to floods. The evolution of flood events in the MAB does not show any significant trend for this period. We argue that the evolution in floods can be explained, at least in part, by the lack of trend in extreme precipitation indices, and also by the improvements in flood prevention measures.     

Dissolved Pb Concentrations and Stable Pb Isotope Ratios in the Ulleung Basin,East/Japan Sea

Ocean Science Journal - The spatial distributions of dissolved lead (Pb) concentrations and stable Pb isotope ratios in the Ulleung Basin, East/Japan Sea, were investigated to identify the Pb...     

Assessing drought threats to agricultural water supplies under climate change by combining the SWAT and MODSIM models for the Geum River basin,South Korea

ABSTRACT

The impacts of future climate change on the agricultural water supply capacities of irrigation facilities in the Geum River basin (9645.5 km²) of South Korea were investigated using an integrated modeling framework that included a water balance network model (MODSIM) and a watershed-scale hydrologic model (Soil and Water Assessment Tool, SWAT). The discharges and baseflows from upland drainage areas were estimated using SWAT, and the predicted flow was used to feed agricultural reservoirs and multipurpose dams in subwatersheds. Using a split sampling method, we calibrated the daily streamflows and dam inflows at three locations using data from 6 years, including 3 years of calibration data (2005–2007) followed by 3 years of validation data (2008–2010). In the MODSIM model, the entire basin was divided into 14 subwatersheds in which various agricultural irrigation facilities such as agricultural reservoirs, pumping stations, diversions, culverts and groundwater wells were defined as a network of hydraulic structures within each subwatershed. These hydraulic networks between subwatersheds were inter-connected to allow watershed-scale analysis and were further connected to municipal and industrial water supplies under various hydrologic conditions. Projected climate data from the HadGEM3-RA RCP 4.5 and 8.5 scenarios for the period of 2006–2099 were imported to SWAT to calculate the water yield, and the output was transferred to MODSIM in the form of time-series boundary conditions. The maximum shortage rate of agricultural water was estimated as 38.2% for the 2040s and 2080s under the RCP 4.5 scenario but was lower under the RCP 8.5 scenario (21.3% in the 2040s and 22.1% in the 2080s). Under the RCP 4.5 scenario, the projected shortage rate was higher than that during the measured baseline period (1982–2011) of 25.6% and the RCP historical period (1982–2005) of 30.1%. The future elevated drought levels are primarily attributed to the increasingly concentrated rainfall distribution throughout the year under a monsoonal climate, as projected by the IPCC climate scenarios.

EDITOR Z.W. Kundzewicz; ASSOCIATE EDITOR not assigned     

Distribution and enrichment of trace metals and arsenic at the upper layer of sediments from Lerma River in La Piedad,Mexico: case history

Lerma River is one of the largest rivers in Mexico. Over the past 20 years, unplanned population growth occurred along its course and the river has been used as the only outlet for industrial and domestic wastewater disposal. The aim of the present study was to determine trace metals such as Cr, Ni, Cu, Zn, Fe, Pb, and arsenic concentrations at the upper layer of sediments of the Lerma River meander in La Piedad, Michoacan, Mexico. Sediment samples were collected from eight different sites during the rainy and dry seasons. All samples were physically characterized, and concentration values of trace metals and As were determined. On the basis of protection criteria for freshwater sediments, concentrations of Fe, Zn, Cu, Ni, and Pb were found to exceed the lowest effect level; moreover, the concentrations were found to exceed the severe effect level at some sites, particularly for Cu. Statistical analyses showed significant differences between sampling seasons for Fe and As, and among sites for Ni, Cu, Zn, and Pb. In addition, the enrichment factor indicates the following order Zn > Cr > Cu > Ni > Pb > As, and the geoaccumulation index (I _geo) indicates contamination in the following order Zn > Cr > Cu > Ni > As > Pb. The Lerma River meander in La Piedad shows a reduction in pollution by trace metals and arsenic near the drain area and downstream of the meander. However, there are significantly higher concentrations of these elements in sediments of sites located in the middle part of the city.     

Lu–Hf garnet systematics of a polymetamorphic basement unit: new evidence for coherent exhumation of the Adula Nappe (Central Alps) from eclogite-facies conditions

The Adula Nappe in the Central Alps is a mixture of various pre-Mesozoic continental basement rocks, metabasics, ultrabasics, and Mesozoic cover rocks, which were pervasively deformed during Alpine orogeny. Metabasics, ultrabasics, and locally garnet–mica schists preserve eclogite-facies assemblages while the bulk of the nappe lacks such evidence. We provide garnet major-element data, Lu profiles, and Lu–Hf garnet geochronology from eclogites sampled along a north–south traverse. A southward increasing Alpine overprint over pre-Alpine garnets is observed throughout the nappe. Garnets in a sample from the northern Adula Nappe display a single growth cycle and yield a Variscan age of 323.8 ± 6.9 Ma. In contrast, a sample from Alpe Arami in the southernmost part contains unzoned garnets that fully equilibrated to Alpine high-pressure (HP) metamorphic conditions with temperatures exceeding 800 °C. We suggest that the respective Eocene Lu–Hf age of 34.1 ± 2.8 Ma is affected by partial re-equilibration after the Alpine pressure peak. A third sample from the central part of the nappe contains separable Alpine and Variscan garnet populations. The Alpine population yields a maximum age of 38.8 ± 4.3 Ma in line with a previously published garnet maximum age from the central nappe of 37.1 ± 0.9 Ma. The Adula Nappe represents a coherent basement unit, which preserves a continuous Alpine high-pressure metamorphic gradient. It was subducted as a whole in a single, short-lived event in the upper Eocene. Controversial HP ages and conditions in the Adula Nappe may result from partly preserved Variscan assemblages in Alpine metamorphic rocks.