Characterization of a chalcopyrite from Brazil by Mössbauer spectroscopy and other physicochemical techniques

We studied a chalcopyrite from a Cu ore deposit in Rio Grande do Sul, Brazil, by Mössbauer spectroscopy at room temperature and 110 K. Supporting methods to check for sample purity and to characterize further sample properties were slow-scanning X-ray powder diffraction and optical and microprobe analyses of polished sections of selected grains. Chemical analyses obtained using a scanning electron microscope equipped with an energy-dispersive X-ray spectrometer showed the sample to consist of homogeneous and essentially stoichiometric chalcopyrite (CuFeS₂). Mössbauer spectra taken at both the above temperatures consist of asymmetric magnetically ordered patterns with unequal intensities of the line pairs 1–6 and 2–5, pointing to the existence of non-equivalent or multiple Fe sites. Least-squares fittings evidenced that the resonance intensity ratio of subspectrum with lower quadrupole shift (indicative of a more symmetric environment) to that with higher shift is 69:31, at room temperature, and 68:32, at 110 K. Rietveld refinement of the XRD data indicates the existence of tetragonal [a = 0.52855(1) and c = 1.0412(1) nm] and cubic [a ₀ = 0.5273(2) nm] modifications in a proportion of 74:26, in good agreement with the Mössbauer data. The saturation magnetization of the sample was 32.7 J/(T kg), confirming the oxidation state of Fe as trivalent and pointing to little to no spin canting.     

Inferred gas hydrate on the Barents Sea shelf — a model for its formation and a volume estimate

 On the southwestern Barents Sea shelf, sediments containing gas hydrates that overlie free gas have been inferred from multichannel seismic data. The volume of suspected gas hydrate is tentatively estimated to about 1.9×10⁸ m³. The gas hydrate zone probably formed from thermogenic gas leaking from a deeper source. The hydrate zone may have thickened during the Neogene by including gas originally trapped as free gas below the hydrate following a significant downward migration of the isotherms caused by erosion and/or subsidence. Within the present oceanographic conditions, gas hydrate is suspected to be stable or slowly decomposing. Received: 20 December 1996 / Revision received: 20 August 1997     

Comparison of the high-pressure schist belts of New Caledonia and Sanbagawa,Japan

The high-pressure schist terranes of New Caledonia and Sanbagawa were developed along the oceanic sides of sialic forelands by tectonic burial metamorphism. The parent rocks were chemically similar, as volcanic-sedimentary trough or trench sequences, and metamorphic temperatures in both belts were 250° to 600° C. From phase equilibria curves, total pressures were higher for New Caledonia (6–15 kb) than for Sanbagawa (5–11 kb) and the estimated thermal gradients were 7–10° C/km and 15° C/km respectively.PT paths identify the higher pressure in New Caledonia (P differences 2 kb at 300° C and 4 kb at 550° C) with consequent contrast in progressive regional metamorphic zonation for pelites in the two areas: lawsonite-epidote-omphacite (New Caledonia) and chlorite-garnet-biotite (Sanbagawa). In New Caledonia the Na-amphibole is dominantly glaucophane and Na-pyroxenes associated with quartz are Jadeite (Jd_95–100) and omphacite; in Sanbagawa the amphibole is crossite or riebeckite and the pyroxene is omphacite (Jd₅₀). For both areas, garnet rims show increase in pyrope content with advancing grade, but Sanbagawa garnets are richer in almandine. Progressive assemblages within the two belts can be equated by such reactions as:New Caledonia Sanbagawa glaucophane+paragonite+H₂Oalbite+chlorite+quartz glaucophane+epidote+H₂Oalbite+chlorite+actinolite and the lower pressure Japanese associations appear as retrogressive phases in the New Caledonia epidote and omphacite zones.The contrasts inPT gradient, regional zonation and mineralogy are believed due to differences in the tectonic control of metamorphic burial: for New Caledonia, rapid obduction of an upper sialic plate over an inert oceanic plate and sedimentary trough; and for Sanbagawa, slower subduction of trench sediments beneath a relatively immobile upper plate.     

Supporting farmer-managed irrigation systems in the Shigar valley,Karakorum: Role of the government and Aga Khan Rural Support Programme

Farmer-managed irrigation systems(FMIS) in the high altitude valleys of the Karakorum,Pakistan, continue to be managed effectively despite increased pressure on the social arrangements that sustain them. Colonial era records shows that over a century ago government agencies undertook irrigation support projects. In the past three decades,government agencies and the non-government agency Aga Khan Rural Support Programme(AKRSP), which channels foreign funds into the region, have actively engaged in the provision of irrigation support. This article seeks to explore whether such projects support or undermine farmer-managed irrigation systems and the complex institutional arrangements that underpin them. Field research using ethnographic and participatory methods was conducted in spring 2013 in the upper Shigar valley, Skardu district, GilgitBaltistan. The findings show that irrigation development is a political activity that involves village-based actors, religious leaders, local politicians,and government and non-government agencies.Government agencies operate in a largely top-down,engineering mode, their larger projects limited to villages suffering water scarcity. The local government provides small funds for renovation work of FMIS,though allocation of funds is highly politicized. Nongovernment agencies, for a variety of reasons including donor-funding cycles, apply a one-size-fitsall ‘participatory' model in an attempt to socially engineer rules and institutions. In communities divided by factionalism the use of such external models that stress formation of committees are unlikely to yield positive results, and could instead contribute to undermining the very systems they seek to support. This research argues that irrigation interventions should take care to build upon the rich and complex social arrangements that have sustained FMIS through the centuries.     

利用场地观测计算地表通量

高原地表的感热和潜热通量在亚洲季风系统中有很重要的作用。由于高原地域辽阔，且自然环境较严酷，不利于建立完善的地面观测系统。因此，卫星遥感观测就成为测算高原整体感热和潜热通量的有效工具。地面场地的观测结果作为地表通量的真实值，对于卫星遥感测算是非常重要的。它也为构建陆面—大气模型提供了科学依据，是卫星资料的资料同化系统中的重要组成部分。 计算场地热量通量有几种不同的处理方法。最简单的方法利用有效的观测和试验的参数，可以给出稳定连续的估计。愈精确的Bowen比或者廓线的观测能给出愈精确的信息。综合了湍流测量及辐射测量、土壤热通量的观测结果的估计对陆面—大气相互作用进行了详细的描述，以适应模式的发展。从1998年开始，这些方法联合应用到青藏高原；场地通量观测方面的成果以及目前对其理解将在本文中做一概述。     

Water in India with reference to agriculture and population: some issues and patterns —dynamic approaches needed for development

In this paper an attempt is made to present some facets of status of water for agriculture and population in India. The issues are basic in nature which have been focused by scholars all over time and again. The materials are gathered from various sources to highlight and to consider a plea in the context of population-hydrological regions of the country to develop water potentials. Some characteristic mapping has also been conducted showing the main parameters of water utilization, need and spatial issues regarding consumptive use of water during agricultural operations as per the seasons prevalent in India. A relation is also established with the drought areas leading to assess the need for water. The human problems specially in relation to the safe drinking water is also projected in relation to distributional qualities with reference to natural regions by districts. The study does not claim a full assessment of the water issue due to paucity of statistics on water use, generation and potentials but it does indicate in many ways the geographical problems as an important study for further research by all concerned.     

Changes in bulk properties and molecular compositions within New Zealand Coal Band solvent extracts from early diagenetic to catagenetic maturity levels

The bulk properties and bitumen molecular compositions of a rank-series of 38 humic coals from the New Zealand Coal Band (Cretaceous–Cenozoic) have been analysed to investigate early maturation processes affecting coaly organic matter through diagenesis to moderate catagenesis (Rank(S_r) 0.0–11.8, R_o 0.23–0.81%). The samples comprise a relatively restricted range of vitrinite rich coal types formed largely from higher land plant material under relatively oxic conditions, but with a significant contribution from microbial biomass. With increasing rank, total organic carbon contents show a general increase, whereas moisture and asphaltene contents decrease. Bitumen yields also decrease through the stages of diagenesis and early catagenesis (Rank(S_r) < 9, R_o < 0.55%), indicating partial loss of initial bitumen during early maturation. Thermal generation of hydrocarbons begins slowly at Rank(S_r)  5–6 (R_o  0.40%) as indicated by the constant occurrence and gradual increase of isoprenoids (e.g., pristane and phytane) and hopanoids in their more mature αβ configuration. This early phase of catagenesis, not previously recognised in New Zealand coals, is followed at Rank(S_r)  9 (R_o  0.55%) by the main catagenesis phase characterised by a more rapid increase in the generation of hydrocarbons, including total n-alkanes, isoprenoids and αβ-hopanes. Changes in the maturity of New Zealand coals can be traced by the Carbon Preference Index and several hopane maturity parameters, including 22S/(22S + 22R), αβ/(αβ + βα) and ββ/(αβ + βα + ββ).     

Holocene sediments and magnetic stratigraphy from Lakes Zug and Zurich, Switzerland

Piston cores 7 m and 6.5 m long were collected from Lakes Zug and Zurich respectively. Radiocarbon age determinations, pollen assemblage zones and varve counts indicate dates of 5000–6000 years B.P. (Zug), and 12,000–13,000 years B.P. (Zurich) for the base of the cores. Declination of the magnetic remanence varies through 70° and inclination varies through 30°. Although the correlation with the geomagnetic secular variation curve covering the last 15,000 years as determined from Lake Windermere, England (Creer et al., 1972) is not precise, the results suggest that Lake Zug and Lake Zurich sediments have been recording the broad outline of past secular variations of the earth's magnetic field. Since intensity of magnetization and susceptibility correlate markedly with lithology, a detailed sediment stratigraphy is presented. The amount and texture of the detrital input appears to be a controlling factor for the natural magnetic remanence. Intensity varies from 90 μG in zones of organic, sulphide pigmentation and those with ultra-fine laminations to 0.8 μG in impure lacustrine chalk. Susceptibility ranges from 9 μG/Oe in laminated, fine-grained glacially derived muds to 0.5 μG/Oe in impure lacustrine chalk. Intensity of magnetization also varies systematically within individual turbidites with lowest values in the coarse-grained, basal fractions. Slumped beds were identified on the basis of erratic anomalies in magnetic declination and inclination measurements.     

Comparison of Canadian daily ice charts with surface observations off Newfoundland,winter 1992

Abstract

Forecast ice drift rates and thicknesses displayed on daily ice charts and forecast winds for the Canadian east coast are compared to on‐ice observations made during the second Canadian Atlantic Storm Program (CASP II) of March 1992. Observed and 24‐hour forecasts of daily ice drift rates were weakly correlated even though long‐term means closely matched observations. Daily drift rates have an RMS error of 13 cm s^‐1 relative to a 15 cm s^‐1 mean in addition to an RMS direction error of 50 degrees. Contributions towards daily drift uncertainties were: the estimation of winds, unmodelled physics of ocean and ice cover processes; and the inconsistency in the methods used by the ice forecaster. Correlation coefficients between forecast winds and on‐ice observed winds decreased from 0.8 at 0‐hour to 0.7 for the 30‐hour forecast. Similar results were found between ice drift rates from forecast winds. Histograms of ice thicknesses observed along narrow swaths using a helicopter‐towed electromagnetic sensor compared well with undeformed ice thicknesses representing large areas on ice charts, with differences mainly caused by difference in ice type representation and by co‐registering the two data sets.