Invisible gold in ore and mineral concentrates from the Hillgrove gold-antimony deposits, NSW, Australia

Vein-hosted mesothermal stibnite-gold mineralisation at the Hillgrove Au-Sb mine in northeastern New South Wales has a halo of veinlet and disseminated auriferous arsenopyrite and arsenian pyrite in metasedimentary and granitic host rocks. About 50–55% of the gold produced at Hillgrove occurs invisibly in arsenopyrite and pyrite. Gold losses of ∼20% into tailings are due to this mineral chemical factor. From PIXE probe analyses, it has been found that arsenopyrite contains 255–1500 ppm Au and pyrite 24–223 ppm Au, with Au contents of each mineral correlating moderately with As content. Arsenopyrite and pyrite also contain anomalous values of Cu, Ag and Sb, whereas paragenetically later stibnite contains little invisible gold, but minor Fe, As, Ag, Cu and Pb. The precipitation of invisible gold in arsenopyrite and pyrite by a possible (Fe, Au)³⁺= (As-S)³⁻ substitution mechanism may have been facilitated by rapid, non-equilibrium conditions involving pressure decreases and wall rock reaction (sulphidation, carbonatisation), as a prelude to the main stage of stibnite and gold deposition. Received: 15 January 1999 / Accepted: 12 October 1999     

Global warming and hurricanes: the potential impact of hurricane intensification and sea level rise on coastal flooding

Tens of millions of people around the world are already exposed to coastal flooding from tropical cyclones. Global warming has the potential to increase hurricane flooding, both by hurricane intensification and by sea level rise. In this paper, the impact of hurricane intensification and sea level rise are evaluated using hydrodynamic surge models and by considering the future climate projections of the Intergovernmental Panel on Climate Change. For the Corpus Christi, Texas, United States study region, mean projections indicate hurricane flood elevation (meteorologically generated storm surge plus sea level rise) will, on average, rise by 0.3 m by the 2030s and by 0.8 m by the 2080s. For catastrophic-type hurricane surge events, flood elevations are projected to rise by as much as 0.5 m and 1.8 m by the 2030s and 2080s, respectively.     

The rendition of the Atlantic Warm Pool in the reanalyses

The Atlantic Warm Pool (AWP) region, which is comprised of the Gulf of Mexico, Caribbean Sea and parts of the northwestern tropical Atlantic Ocean, is one of the most poorly observed parts of the global oceans. This study compares three ocean reanalyses, namely the Global Ocean Data Assimilation System of National Centers for Environmental Prediction (NCEP), the Climate Forecast System Reanalysis (CFSR) of NCEP, and the Simple Ocean Data Assimilation (SODA) for its AWP variation. The surface temperature in these ocean reanalyses is also compared with that from the Extended Range SST version 3 and Optimally Interpolated SST version 2 SST analyses. In addition we also compare three atmospheric reanalyses: NCEP-NCAR (R1), NCEP-DOE (R2), and CFSR for the associated atmospheric variability with the AWP. The comparison shows that there are important differences in the climatology of the AWP and its interannual variations. There are considerable differences in the subsurface ocean manifestation of the AWP with SODA (CFSR) showing the least (largest) modulation of the subsurface ocean temperatures. The remote teleconnections with the tropical Indian Ocean are also different across the reanalyses. However, all three oceanic reanalyses consistently show the absence of any teleconnection with the eastern equatorial Pacific Ocean. The influence of the AWP on the tropospheric temperature anomalies last for up to a one season lead and it is found to be relatively weak in R1 reanalyses. A simplified SST anomaly equation initially derived for diagnosing El Niño Southern Oscillation variability is adapted for the AWP variations in this study. The analysis of this equation reveals that the main contribution of the SST variation in the AWP region is from the variability of the net heat flux. All three reanalyses consistently show that the role of the ocean advective terms, including that associated with upwelling in the AWP region, is comparatively much smaller. The covariance of the SST tendency in the AWP with the net heat flux is large, with significant contributions from the variations of the surface shortwave and longwave fluxes.     

Application of the patient rule induction method to detect hydrologic model behavioural parameters and quantify uncertainty

Finding an operational parameter vector is always challenging in the application of hydrologic models, with over‐parameterization and limited information from observations leading to uncertainty about the best parameter vectors. Thus, it is beneficial to find every possible behavioural parameter vector. This paper presents a new methodology, called the patient rule induction method for parameter estimation (PRIM‐PE), to define where the behavioural parameter vectors are located in the parameter space. The PRIM‐PE was used to discover all regions of the parameter space containing an acceptable model behaviour. This algorithm consists of an initial sampling procedure to generate a parameter sample that sufficiently represents the response surface with a uniform distribution within the “good‐enough” region (i.e., performance better than a predefined threshold) and a rule induction component (PRIM), which is then used to define regions in the parameter space in which the acceptable parameter vectors are located. To investigate its ability in different situations, the methodology is evaluated using four test problems. The PRIM‐PE sampling procedure was also compared against a Markov chain Monte Carlo sampler known as the differential evolution adaptive Metropolis (DREAM_ZS) algorithm. Finally, a spatially distributed hydrological model calibration problem with two settings (a three‐parameter calibration problem and a 23‐parameter calibration problem) was solved using the PRIM‐PE algorithm. The results show that the PRIM‐PE method captured the good‐enough region in the parameter space successfully using 8 and 107 boxes for the three‐parameter and 23‐parameter problems, respectively. This good‐enough region can be used in a global sensitivity analysis to provide a broad range of parameter vectors that produce acceptable model performance. Moreover, for a specific objective function and model structure, the size of the boxes can be used as a measure of equifinality.     

Ti diffusion in quartz inclusions: implications for metamorphic time scales

Quartz inclusions in garnet from samples collected from the staurolite zone in central New England are zoned in cathodoluminescence (CL). The CL intensity is interpreted to be a proxy for Ti concentration and the zoning attributed to Ti diffusion into the quartz grains driven by Ti exchange between quartz and enclosing garnet as a function of changing temperature. The CL zoning has been interpreted using a numerical diffusion model to constrain the time scales over which the diffusion has occurred. Temperature–time histories are sensitive to the presumed peak temperature but not to other model parameters. The total time of the metamorphic heating and cooling cycle from around 450?°C to the peak temperature (550–600?°C) back to 450?°C is surprisingly short and encompasses only 0.2–2 million years for peak temperatures of 600–550?°C. The metamorphism was accompanied by large-scale nappe and dome formation, and it is suggested that this occurred as a consequence of in-sequence thrusting resulting in a mid-crustal ductile duplex structure.     

Field and geochemical characteristics of the Coolac Ophiolite suite and its possible origin in a marginal sea

Geological and geochemical data from the Coolac Serpentinite Belt, North Mooney Complex and Honeysuckle Beds in southern New South Wales indicate that the association represents a partially dismembered ophiolite suite. All the ideal ophiolite units are present, although the sheeted dyke unit is apparently of limited extent. Major and trace element (including rare‐earth) results, relationships of mafic volcanics and dolerite to massive and layered gabbroic and ultramafic intrusives, the occurrence of tectonised harzburgite with podiform chromitite, and the nature of pyritic sulphide occurrences, are consistent with a marginal sea or back‐arc environment for the generation of the ophiolite suite.     

Drivers of social media use among African Americans in the event of a crisis

Research has examined the role of social media during the time of a crisis in various fields; however, there is a paucity of research in this area as it relates to tourism. Moreover, few studies have examined at-risk populations, such as tourists, in times of crisis. To assess the drivers of turning to social media during a crisis, a national survey of 1,018 African American travelers was conducted. Respondents were asked to indicate on a 5-point scale the likelihood of turning to social media for information “if they were currently in the middle of their trip and heard that a crisis has just occurred within the immediate vicinity of their current location.” Hierarchical regression analysis was conducted to determine drivers on African American travelers’ decisions to use social media during a crisis. These drivers were age, perceptions of risk during their trip, and frequency and type of social media use engaged in on a regular basis. Overall, findings suggested that when controlling for age only, crime, financial, and physical perceptions of risk drove social media use during a crisis, while controlling for age and perception of risk, use of social media in one's daily life showed no influence.     

Paleoenvironmental context of archaeological sites,implications for subsistence strategies under Holocene climate change,northern Kenya

The Holocene was time of dramatic climate change in East Africa, shifting from wetter climate in the Early–Mid Holocene (∼10–5ka) to drier climates in the Late Holocene, followed by a slight reversal at <1ka. The Holocene was a time of cultural change from hunter‐gatherer and fishing to pastoralism. Recent excavations along the eastern shores of Lake Turkana, Kenya (4°N) provide new archaeological materials, a high‐resolution stratigraphic and paleoenvironmental data set, OSL dates, and cultural records in the context of documented environmental change (falling lake levels). Archaeological site FwJj25 (4.20 ± 0.28ka), on the northeastern margin of Lake Turkana, provides one of the earliest records of pastoralism in the region. The palimpsest record of FwJj5 (0.90 ± 0.06ka) was in a small valley containing a groundwater seep located 5km from the lake. FwJj5 reflects occupation by people who may have covered great distances in accessing resources, but were likely drawn to an environmental refugia of freshwater springs during times of regional aridity. © 2011 Wiley Periodicals, Inc.     

Avalanche fatalities in the western United States: a comparison of three databases

Reported avalanche fatalities in the United States increased markedly through the latter half of the twentieth century, a result of the increasing popularity of winter sports. Despite this increase, the literature concerning US avalanche fatalities is sparse. This paper presents a comparison of three US databases containing avalanche fatality information: Storm Data, the West Wide Avalanche Network (WWAN) dataset, and the National Avalanche Database (NAD). The frequency of avalanche fatalities, their temporal trends, spatial distributions, and the demographic characteristics of the victims were analyzed in each database for the years 1998–2009 for the US mountainous west. The data were then pooled to arrive at an estimate of avalanche fatality frequency in the United States for the study period. While the results indicate a considerable amount of overlap between the datasets, Storm Data reports fewer avalanche fatalities than both the WWAN and NAD datasets. All three datasets report a maximum of fatalities in January and display three spatial maxima: the Rocky Mountains of west-central Colorado, the intermountain region from central Utah through Idaho to west-central Montana, and the northern Cascade Ranges of Washington; however, a large void appears in the Storm Data records in the vicinity of the Montana maximum. These maxima result from a juxtaposition of avalanche hazard in these mountainous environments with a high concentration of winter sports activities.