Spatial modelling of hazardous elements at waste dumps using geostatistical approach: a case study Sarcheshmeh copper mine,Iran

Mining activities and resulting wastes can be considered as one of the most important sources of hazardous elements in the environment. Knowledge of the spatial distribution of toxic elements in waste dump systems is necessary to assess environmental hazard and strategy. To achieve this goal, this paper investigates spatial distribution of toxic elements using statistical and geostatistical analysis. A total of 58 soil samples were collected, and the amount of As, Cd, Co, Cr, Cu, Mn, Mo, Ni, Pb and Zn was then determined at “Sarcheshmeh” copper mine waste dumps. In order to evaluate the presence of multivariate outliers, Mahalanobis distance technique (D ²) was applied and the multivariate outlier samples were removed. This resulted in an increase in correlation coefficient. To reduce dimension of data set, principal component analysis was applied and four principal components were determined which indicate 83.463% of the total variance of data set. Estimated PCs together with the toxic elements maps based on the ordinary kriging display aggregation of toxic elements in some parts, and validity of predictions was evaluated using the leave-one-out cross-validation method. The regression coefficients of estimated and observed values presented the reliability of the kriging estimates. Sequential Gaussian simulation method was applied for principal components due to similar results of estimated principal components and toxic elements. The results of simulation maps are almost identical to estimated outcomes.     

Geological and Geochemical Investigation of Three Ophiolite‐Hosted Manganese Prospects,Southeast of Birjand,South Khorasan,East of Iran

The studied ophiolite‐hosted manganese prospects are located in southeast of Birjand, South Khorasan, in the east of Iran. The manganese ores within the ophiolitic sequence in this region occur as small discrete patches, associated with radiolarian chert and shale. Manganese ores in the host rocks are recognizable as three distinct syngenetic, diagenetic, and epigenetic features. The syngenetic manganese ores occurred as bands associated with light‐red radiolarian chert. The diagenetic Mn ores occurred as lenses accompanied by dark‐red to brown radiolarian chert. The epigenetic Mn ores occurred as veins/veinlets within the green radiolarian shale. The major manganese ore minerals are pyrolusite, braunite, bixbyite, ramsdellite, and romanechite showing replacement, colloidal, and brecciated textures. The high mean values of Mn/Fe (15.32) and Si/Al (15.65), and the low mean concentration values of trace elements, such as Cu (85.9 ppm), Ni (249.9 ppm), and Zn (149 ppm), as well as the high concentration values of Si, Fe, Mn, Ba, Zn, Sr, and As in the studied manganese ores furnished sufficient evidence to postulate that the sea‐floor Mn‐rich hydrothermal exhalatives were chiefly responsible for the ore formation, and the hydrogenous processes had negligible role in generation of the ores. The further geological and geochemical evidence also revealed that the ores deposited on the upper parts of the ophiolitic sequence by submarine exhalatives. The intense hydrothermal activities caused leaching of elements such as Mn, Fe, Si, Ba, As and Sr from the basaltic lavas (spilites). After debouching of the sea‐floor exhalatives, these elements entered the sedimentary basin. The redox conditions were responsible for separation of Fe from Mn.     

Timing of metamorphism and deformation in the Swat valley,northern Pakistan:Insight into garnet-monazite HREE partitioning

New metamorphic petrology and geochronology from the Loe Sar dome in the Swat region of northern Pakistan place refined constraints on the pressure, temperature and timing of metamorphism and deformation in that part of the Himalayan orogen. Thermodynamic modelling and monazite petrochronology indicate that metamorphism in the area followed a prograde evolution from ～525 ± 25 ℃and 6 士 0.5 kbar to ～610 ± 25 ℃ and 9 士 0.5 kbar, between ca. 39 Ma and 28 Ma. Partitioning of heavy rare earth elements between garnet rims and 30-28 Ma monazite are interpreted to indicate coeval crystallization at peak conditions. Microtextural relationships indicate that garnet rim growth post-dated the development of the main foliation in the area. The regional foliation is folded about large-scale N-S trending fold axes and overprinting E-W trending folds to form km-scale domal culminations. The textural relationships observed indicate that final dome development must be younger than the 30-28 Ma monazite that grew with garnet rims post-regional foliation development, but pre-doming-related deformation. This new timing constraint helps resolve discrepancy between previous interpretations,which have alternately suggested that N-S trending regional folds must be either pre-or post-early Oligocene. Finally, when combined with existing hornblende and white mica cooling ages, these new data indicate that the study area was exhumed rapidly following peak metamorphism.     

Assessing agricultural drought management strategies in the Northern Murray–Darling Basin

Natural Hazards - The Northern Murray–Darling Basin (MDB) is a key Australian agricultural region requiring efficient Agricultural Drought Management (ADM), focused on resilience. Although a...     

Geochronological and geochemical studies of adakites from Tethyan Belt,Western Pakistan: A clue to geodynamics and Cu-Au mineralization

ABSTRACT

Large porphyry Cu-Au deposits are associated with Early Miocene intrusive rocks in Tethyan belt, discovered along Chagai magmatic arc in Western Pakistan, adjacent to Southeast Iran. Two types of rocks were discriminated as granodiorite and monzodiorite from Saindak area. The granodiorites are associated with regional large Cu-Au mineralization, while the monzodiorites are mostly ore-barren. LA-ICP-MS U-Pb dating yielded weighted mean ²⁰⁶Pb/²³⁸U ages of 22.16–24.2 Ma for granodiorites and ca. 22.6 Ma for a monzodiorite. These intrusive rocks in the Saindak area are all calc-alkaline rocks, with enriched LILEs and depleted HFSEs, and without Eu negative anomalies. The felsic granodiorites are characterized by high Sr contents and Sr/Y ratios, with intermediate to high (La/Yb)_N ratios that identify them as typical high-silica adakites. In contrast, the basaltic-andesitic monzodiorites are just normal arc-related rocks, showing less fractionated REE patterns than the granodiorites, with systematically lower LREE and higher MREE and HREE. Low K₂O/Na₂O ratios and decoupled Sr/Y-(La/Yb)_N ratios indicate the characteristics of slab-derived adakites for the granodiorites, most likely originated through partial melting of the subducted Neotethys oceanic crust beneath Eurasian continent followed by subsequent mantle interaction. The almost simultaneously melting of subcontinental lithospheric mantle induced by dehydration of Neotethys plate gave rise to the formation of the barren monzodiorites. These intrusive rocks in the Saindak area are characterized by similar Sr-Nd-Pb isotopes with high ⁸⁷Sr/⁸⁶Sr_i ratios, slightly negative εNd(t) values and radiogenic Pb isotopes, plotting in the field between the MORB and EM-II mantle endmembers or the Average Cadomian Lower Crust, suggesting subducting sediments or old continental crustal materials have contributed into the compositions of these rocks by source enrichment or crustal contamination. The slab-melting derived adakite is favourable for regional massive Cu-Au mineralization in the Saindak area.     

Changing Land Use a Threat to Surface Water Quality: a Vulnerability Assessment Approach in Zanjanroud Watershed,Central Iran

Maintaining the quality of surface water resources as one of the most vital water supplies has always been at the center of global concerns. A set of manifest and latent factors have yet been identified by researchers worldwide that are subject to affect the quality of surface water. Among which, the effect of land use change, due to a spatial and temporal complexity, is often not easily verifiable. The present study attempts to offer an index-based model to quantify vulnerability of surface water resources in a semi arid basin in central Iran against land use changes. For this, water quality data including Na, K, Mg, Ca, Sodium Adsorption Ratio (SAR), total anions (Sum. A), SO₄, Cl, HCO₃, EC, TDS, and pH were collected from hydrometric stations over a period of 26 years (1987?2013). In order to detect land use changes, the land use maps of the years 1987, 1998, 2002, 2009, and 2013 were prepared from TM satellite images using supervised classification method. At next step, changing patterns of different land uses were traced by Shanon’s Diversity Index (SHDI) as a metric of patch diversity indicating diversity and heterogeneity of a landscape over time. Relationship between the SHDI values and water quality indicators revealed the impact of land use changes on quality of surface water resources. Statistical analysis confirmed a significant relationship between nine water quality factors and water discharge in the basin during the study period. From 1998 to 2009, the greatest changes were visible in the total anions, Ca, SO₄, and HCO₃. These parameters along with salinity were increasing in almost all sub-basins. According to the results, conversion of poor rangelands to rain fed agriculture fields is the most apparent land use change occurred in the study area over the study period. In 1987, SHDI as an indicator of the diversity and changes in the basin, showed a significant relationship with good rangelands (R² =–0.835). This indicates that fragmentation of the entire watershed area was initiated in 1987, which reached its peak in 2013. Generally speaking, urbanization, poor rangeland, and irrigated agriculture were recognized as three influential land uses adversely affect the water quality in the study area.     

Rare Earth Elements Geochemistry of Sheikh-Marut Laterite Deposit,NW Mahabad,West-Azarbaidjan Province,Iran

Laterite deposit at Sheikh-Marut(NW Mahabad,West-Azarbaidjan province,Iran) occurred within middle-upper Permian carbonate rocks.It consists of seven stratiform and/or discontinuous lenticular layers extending over 4.2 km in length and having thicknesses ranging from 3 to 14 m.Mineralogical data show that the ores contain kaolinite and hematite as major and boehmite, diaspore,halloysite,amesite,anatase,and muscovite-illite as minor mineral phases.The computed Ce anomaly values in the ores range from 0.05 to 20.84.Conservative index(e.g.,Eu/Eu) suggests that this deposit is a product of alteration and weathering of basaltic rocks.Rhythmic increment ofΣREE values of the ores with approaching to the carbonate bedrocks shows an in-situ occurrence of lateritization processes.Mass change calculations of elements indicate that two competing processes namely leaching and fixation were the major regulating factors in concentration variation of REEs (La-Lu) in this deposit.The obtained results show that pH increase of weathering solutions by carbonate bedrocks,existence of organic matters,and the degree of comlexation with organic ligands played remarkable role in distribution of REEs during lateritization.Further geochemical considerations revealed that secondary phosphates,Mn-oxides and -hydroxides,diaspore,and anatase were the potential hosts for REEs in this deposit.     

Spatial heterogeneity and temporal stability of throughfall under individual Quercus brantii trees

Spatio‐temporal patterns of throughfall (TF) have often been studied under forest canopies. Few reports, however, have been made on small‐scale TF variability in deciduous forest stands. In the present research, the spatial heterogeneity and temporal stability of TF under five individual persian oak trees (Quercus brantii var. Persica) was quantified. The research site was in the Zagros forests in western Iran, where mean annual precipitation and temperature are equal to 587.2 mm and 16.9 °C, respectively. Data from 23 rainfall events were aggregated to assess the spatial correlation of TF. Variograms for TF beneath two of the five trees reached a stable sill at the range of 5–6 m. The redistribution of TF within the canopy was highly variable in time, attributable to seasonal variation in canopy foliation and meteorological factors. As the length of the sampling period increased, the spatial variability of TF decreased and the temporal stability of the TF pattern increased. Time stability plots of TF normalized with respect to mean and variance showed a moderate general persistence for all individual trees. We conclude that single trees modify the spatial distribution of TF reaching the forest floors. Copyright © 2012 John Wiley & Sons, Ltd.     

Middle and Late Permian palynoflora in Tianshan Township,southeast of Bogda Mountain,Xinjiang, China

The Permian is one of the most important periods during which the vegetative earth witnessed the transition from icehouse to greenhouse climate and the global environment changes. Organisms on the planet en-countered great challenge and the demise of swamp caused the extinction of arborescent lycopods and the rising of Mesophytic plants accomplished the floral transition from the Paleophytic to Mesophytic vegetation. In order to depict the climatic changes and floral succession in the middle and high latitudes of the North Hemisphere, palynological investigation was engaged, and 40 samples collected from the uppermost of Taerlang Formation, Hongyanchi Formation and Quanzijie Formation in the Tianshan Town, Turpan-Hami Basin, eastern Xinjiang, China. The result shows that the palynoflora in the studied area is composed of 50 species of 33 genera, domi-nated by disaccites and striatiti gymnosperm pollen, and characterized by diverse Protohaploxypinus, Hamia-pollenites, Alisporites and Klausipollenites. It is quite similar to those Middle and Late Permian palynological as-semblages reported in the Dalongkou section and other localities in southern margin of Junggar Basin, and aged at Middle and Late Permian. The diversity of typical Angara and sub-Angara pollen, such as Falcisporites, Alisporites, Protohaploxypinus, Vittatina, Lunatisporites, Hamiapollenites, etc. indicates that the studied palyno-flora belonged to the sub-Angara phytoprovince, while the presence of Lueckisporites virkkiae implied Euramerica pollen intruded northward sometimes. The paleoclimate of the studied area might be warm and humid with fluc-tuated dry seasons during the late Guadalupian and early Lopingian time.