The impact of organic pollution on the macrobenthic fauna of Dubai Creek (UAE)

Dubai Creek is a tidal marine intrusion bisecting Dubai within the United Arab Emirates (UAE). The creek extends 14km inland from its opening into the Arabian Gulf, with a narrow lower creek channel leading to a lagoon section in the upper creek. The creek contains numerous sources of organic pollution including sewage outlet flows and boat waste. A survey of the creek was performed, assessing organic pollution, water properties, and the benthic macrofaunal community. The upper creek was heavily polluted with macrofauna communities commonly associated with organic pollution and eutrophication, while the lower creek contained low pollution and relatively healthy macrofauna communities. There is little net tidal flow of water within the creek and residence time in the lagoon is high, which may account for the high organic pollution levels. However, some evidence of the pollution effect moving into the lower creek was found. The results are considered in light of current and historic organic loading within the creek and future developments in the area.     

High‐frequency streamflow acquisition and bed level/flow angle estimates in a mountainous river using shallow‐water acoustic tomography

The acquisition of reliable discharge estimates is crucial in hydrological studies. This study demonstrates a promising acoustic method for measuring streamflow at high sampling rate for a long period using the fluvial acoustic tomography system (FATS). The FATS recently emerged as an innovative technique for continuous measurements of streamflow. In contrast to the traditional point/transect measurements of discharge, the FATS enables the depth‐averaged and range‐averaged flow velocity along the ray path to be measured in a fraction of a second. The field test was conducted in a shallow gravel‐bed river (0.9 m deep under low‐flow conditions, 115 m wide) for 1 month. The parameters (stream direction and bottom elevation) required for calculating the streamflow were deduced by a nonlinear regression to the discharge data from the well‐established rating curve. The cross‐sectional average velocities were automatically calculated from the acoustic data, which were collected on both riverbanks every 30 s. The FATS was connected to the internet so that the real‐time flow data could be obtained. The FATS captured discharge variations at a cut‐off frequency of approximately 70 day^?1. The stream exhibited temporal discharge changes at multiple time scales ranging from a few tens of minutes to days. Copyright © 2016 John Wiley & Sons, Ltd.     

Estimating groundwater recharge for an arid karst system using a combined approach of time‐lapse camera monitoring and water balance modelling

Groundwater is the principal water resource in semi‐arid and arid environments. Therefore, quantitative estimates of its replenishment rate are important for managing groundwater systems. In dry regions, karst outcrops often show enhanced recharge rates compared with other surface and sub‐surface conditions. Areas with exposed karst features like sinkholes or open shafts allow point recharge, even from single rainfall events. Using the example of the As Sulb plateau in Saudi Arabia, this study introduces a cost‐effective and robust method for recharge monitoring and modelling in karst outcrops. The measurement of discharge of a representative small catchment (4.0 · 10⁴ m²) into a sinkhole, and hence the direct recharge into the aquifer, was carried out with a time‐lapse camera. During the monitoring period of two rainy seasons (autumn 2012 to spring 2014), four recharge events were recorded. Afterwards, recharge data as well as proxy data about the drying of the sediment cover are used to set up a conceptual water balance model. The model was run for 17 years (1971 to 1986 and 2012 to 2014). Simulation results show highly variable seasonal recharge–precipitation ratios between 0 and 0.27. In addition to the amount of seasonal precipitation, this ratio is influenced by the interannual distribution of rainfall events. Overall, an average annual groundwater recharge for the doline (sinkhole) catchment on As Sulb plateau of 5.1 mm has estimated for the simulation period. Copyright © 2015 John Wiley & Sons, Ltd.     

Seismic anisotropy in a hydrocarbon field estimated from microseismic data

The study of seismic anisotropy in exploration seismology is gaining interest as it provides valuable information about reservoir properties and stress directions. In this study we estimate anisotropy in a petroleum field in Oman using observations of shear‐wave splitting from microseismic data. The data set was recorded by arrays of borehole geophones deployed in five wells. We analyse nearly 3400 microearthquakes, yielding around 8500 shear‐wave splitting measurements. Stringent quality control reduces the number of reliable measurements to 325. Shear‐wave splitting modelling in a range of rock models is then used to guide the interpretation. The difference between the fast and slow shear‐wave velocities along the raypath in the field ranges between 0–10% and it is controlled both by lithology and proximity to the NE‐SW trending graben fault system that cuts the field formations. The anisotropy is interpreted in terms of aligned fractures or cracks superimposed on an intrinsic vertical transversely isotropic (VTI) rock fabric. The highest magnitudes of anisotropy are within the highly fractured uppermost unit of the Natih carbonate reservoir. Anisotropy decreases with depth, with the lowest magnitudes found in the deep part of the Natih carbonate formation. Moderate amounts of anisotropy are found in the shale cap rock. Anisotropy also varies laterally with the highest anisotropy occurring either side of the south‐eastern graben fault. The predominant fracture strikes, inferred from the fast shear‐wave polarizations, are consistent with the trends of the main faults (NE‐SW and NW‐SE). The majority of observations indicate subvertical fracture dip (>70° ). Cumulatively, these observations show how studies of shear‐wave splitting using microseismic data can be used to characterize fractures, important information for the exploitation of many reservoirs.     

Mineral Content of Bottled and Desalinated Household Drinking Water in Kuwait

Three hundred and twenty‐two samples of desalinated household water were collected from 99 sampling locations that covered 95% of Kuwaiti's residential areas. Seventy‐one brands of bottled water were collected from Kuwaiti markets. The water quality parameters that were studied included pH, electrical conductivity (EC), total dissolved solids (TDS), F^?, Cl^?, Br^?, , , , , , , , and the major macronutrients Na⁺, K⁺, Ca²⁺, and Mg²⁺. The analysis yielded a large range of results for most of these parameters, with differences in some cases exceeding 10‐fold. With a few exceptions, the results were found to comply with US‐EPA and WHO standards. Only the water in two brands of bottled water was acidic (pH < 6.5). The TDS was found to be higher than the US‐EPA regulated value in 4 and 3% of the household samples and bottled water brands, respectively. The fluoride levels were generally higher in bottled water than in household water. However, the household water that was produced by the Doha desalination plant and some of the European brands of bottled water were the best samples studied in terms of their quantity of Ca²⁺, Mg²⁺, and Na⁺ compared with the DRI values for those substances. EC and TDS were positively correlated with , , Na⁺, K⁺, Ca²⁺, and Mg²⁺ for household water but only with Ca²⁺ and Mg²⁺ for bottled water.     

Metal Retention Experiments for the Design of Soil‐Mix Technology Permeable Reactive Barriers

Soil‐mix technology is effective for the construction of permeable reactive barriers (PRBs) for in situ groundwater treatment. The objective of this study was to perform initial experiments for the design of soil‐mix technology PRBs according to (i) sorption isotherm, (ii) reaction kinetics and (iii) mass balance of the contaminants. The four tested reactive systems were: (i) a granular zeolite (clinoptilolite–GZ), (ii) a granular organoclay (GO), (iii) a 1:1‐mixture GZ and model sandy clayey soil and (iv) a 1:1:1‐mixture of GZ, GO and model soil. The laboratory experiments consisted of batch tests (volume 900 mL and sorbent mass 18 g) with a multimetal solution of Pb, Cu, Zn, Cd and Ni. For the adsorption experiment, the initial concentrations ranged from 0.01 to 0.5 mM (2.5 to 30 mg/L). The maximum metal retention was measured in a batch test (300 mg/L for each metal, volume 900 mL, sorbent mass 90–4.5 g). The reactive material efficiency order was found to be GZ > GZ‐soil mix > GZ‐soil‐GO mix > GO. Langmuir isotherms modelled the adsorption, even in presence of a mixed cations solution. Adsorption was energetically favourable and spontaneous in all cases. Metals were removed according to the second order reaction kinetics; GZ and the 1:1‐mix were very similar. The maximum retention capacity was 0.1–0.2 mmol/g for Pb in the presence of clinoptilolite; for Cu, Zn, Cd and Ni, it was below 0.05 mmol/g for the four reactive systems. Mixing granular zeolite, organoclay and model soil increased the chemisorption. Providing that GZ is reactive enough for the specific conditions, GZ can be mixed to obtain the required sorption. Granular clinoptilolite addition to soil is recommended for PRBs for metal contaminated groundwater.     

Spatial Variation of Haloacetic Acids in Indoor and Outdoor Desalinated Household Drinking Water in Kuwait

The present study reveals spatial variability of haloacetic acids and the basic physiochemical properties of drinking water samples through visualization based on the Kriging algorithm and hierarchical cluster analysis. Both projection and statistical method contributed to the logical classification of the indoor and outdoor water samples collected from various governorates covering more than 95% of the residential areas in Kuwait. Clustering of the variables led to the formation of several significant clusters corresponding to the effect of chlorine concentration and its residence time on the formation potential of chlorinated acetic acid derivatives in desalinated drinking water as well as to the total ionic composition of water samples and to the effect of the formation of brominated acetic acid derivatives. Clustering of samples, both indoor and outdoor, indicated that all of governorates located in the northern part of Kuwait are supplied with water containing high concentrations of chlorinated acetic acid derivatives, whereas significantly lower amounts of chlorinated or monobrominated acetic acids were found in water samples in the central and southern parts of the country.     

Variations of the Earth’s magnetic field in the Phanerozoic

The global VDM database, which was later supplemented by new determinations published in the world literature (a total of 3194 determinations), is used as the basis for addressing the VDM behavior in the Phanerozoic (0–542 Ma) and up to 580 Ma. The results revealed a positive linear trend to higher VDM values from 3.5 × l0²² Am² to 5.7 × l0²² Am². Against this background, fluctuations of the mean VDMs occur with a periodicity of about 40 Myr. In the Phanerozoic, prominent minima of the intensity are found in the time intervals of 510–520, 420–460, 340–370, 290–300, 240–270, 190–210, 165–140 Ma (chrons M17–M43), 130–120 Ma (chrons M2–M10), 100–110 Ma (chron C34), 75–85 Ma (chrons C33 and the beginning of chron C34), 70–60 Ma (chrons C31–C27), and 40–15 Ma (chrons C18–C5AD). The distribution of the VDMs appears to reflect the paleomagnetic field behavior and may be taken into account in a magnetization model for the reversely magnetized oceanic crust.     

Peculiarities of the structure and evolution of the Riphean Ai volcanic complex,South Urals

The Ai volcanic complex is a part of the Ai Formation, which begins the stratotypical Riphean section in the South Urals and lies on the Archean Taratash metamorphic complex. New geochemical and isotope data were obtained for the volcanic rocks. The dominant porphyritic plagioclase and pyroxene trachibasalts associated with dacites are characterized by higher contents of alkalis and titanium, which is typical of rift volcanism. However, other geochemical data, e.g., decreased Ni contents, are beyond of this scheme. The U-Pb (SHRIMP) age of zircons from dacites is 1415 ± 11 Ma.     

The Wabar impact craters,Saudi Arabia,revisited

The very young Wabar craters formed by impact of an iron meteorite and are known to the scientific community since 1933. We describe field observations made during a visit to the Wabar impact site, provide analytical data on the material collected, and combine these data with poorly known information discovered during the recovery of the largest meteorites. During our visit in March 2008, only two craters (Philby‐B and 11 m) were visible; Philby‐A was completely covered by sand. Mapping of the ejecta field showed that the outcrops are strongly changing over time. Combining information from different visitors with our own and satellite images, we estimate that the large seif dunes over the impact site migrate by approximately 1.0–2.0 m yr^?1 southward. Shock lithification took place even at the smallest, 11 m crater, but planar fractures (PFs) and undecorated planar deformation features (PDFs), as well as coesite and stishovite, have only been found in shock‐lithified material from the two larger craters. Shock‐lithified dune sand material shows perfectly preserved sedimentary structures including cross‐bedding and animal burrows as well as postimpact structures such as open fractures perpendicular to the bedding, slickensides, and radiating striation resembling shatter cones. The composition of all impact melt glasses can be explained as mixtures of aeolian sand and iron meteorite. We observed a partial decoupling of Fe and Ni in the black impact glass, probably due to partitioning of Ni into unoxidized metal droplets. The absence of a Ca‐enriched component demonstrates that the craters did not penetrate the bedrock below the sand sheet, which has an estimated thickness of 20–30 m.