Laboratory studies on cometary molecules

We show results for some new bands of C₂, CN, N₂ ⁺, CO⁺, NH, OH, and CH hitherto unidentified, but expected to be present in the spectrum of comets by the analysis of Franck-Condon factors. Vibrational transition probabilities, Franck-Condon factors have been evaluated by an approxximate analytical method for the A-X system of C₂, A-X, and B-X systems of CN, B-X system of N₂ ⁺, A-X, and B-A systems of CO ⁺ , A-X system of NH and A–X system of OH.     

A new occurrence of sapphirine-spinel-corundum-bearing granulite from NE of Jagtiyal, Eastern Dharwar Craton, Andhra Pradesh

We report a new occurrence of sapphirine-spinel-corundum bearing granulites enclosed in granitic gneisses near Jagtiyal in the Eastern Dharwar Craton (EDC). These granulites are very important in deciphering the prehistory of the thermal peak of metamorphism due to the presence of refractory phases. The appearance of sapphirine is related to the following reactions: (a) Spl₁ + Crd₁ = Spr_{1 (2:2:1)} (b) Phl (in Bt₁) + Crn₁ = East (in Bt₂) + Spr_{2 (7:9:3)} + Crd₂ (c) Bt₂ + Crd₁ + Crn₁ = Spr_{2 (7:9:3)} + Kfs + H₂O (d) Crd₁ + Spl₁ + Crn₁ = Spr_{2 (7:9:3)}. The P-T evolution of these sapphirine granulites has been constrained through the use of THERMOCALC program. Temperature of formation of sapphirine-spinel assemblages is high, around 800 °C, and pressure ranges from 5–7 kbars, suggesting that sapphirine formation took place during decompression stage.     

Geomorphic control on the formation of mixed layer clays by progressive degradation of biotite: A case study from Jutulsessen Gjelsvikfjella,East Antarctica

Eleven glacial sediment samples collected from different elevation of Jutulsessen Nunatak, Gjelsvikfjella of East Antarctica were studied for the clay mineralogical analysis using X-ray diffraction technique. The result shows prominent peak at 10, and 3.34 Å suggesting the presence of biotite possibly derived from the catchment where biotite rich granite gneisses are exposed. The detailed investigation on the shape of biotite peak of certain samples shows the signs of alteration of biotite in to a mixed layer containing tri-octahedral smectite (low charge vermiculite). The presence of mixed layer along with the biotite is found to be associated with the samples of lower geomorphic level. The progressive alteration of clay sized biotite to form a mixed layer in the lower horizons of Jutulsessen Nunatak is probably due to the periodic accumulation of melt-water during the austral summer.     

One hundred and fifty-three diatomic molecules,molecular ions,and radicals of astrophysical interest

A critical analysis of the 583 available references in literature has been made to select 153 diatomic molecules, molecular ions, and radicals of astrophysical significance. The results have been arranged in a text-cum-tabular form. The compilation contains various information for each molecule, such as the dissociation energy, spectral region, transition levels, astrophysical objects where the respective molecules have been detected (say, comet, meteorite, Sun, planet, star, interstellar matter, Galaxy, etc.); computed theoretical parameters (i.e., FCFs, transition probabilities, r-centroids, PE curves), and available laboratory data with respective references.In many problems involving the estimation of the physical condition (viz., temperature, pressure, density, and abundance) of the emitter, in various cosmic sources, it is desirous to have a knowledge of the theoretical parameters as well as the experimental details for the molecular spectra of interest.A few important areas of active research in laboratory astrophysics have also been identified in this article: laboratory astrophysics, molecular cloud chemistry, isotopic abundance, planetary and cometary atmospheres through satellites.Besides, some interesting plots of the dissociation energy vs molecular weight, dissociation energy vs total atomic number, dissociation energy vs atomic number differences, ionization potential vs total atomic number, ionization potential vs atomic number differences, and ionization potential vs molecular weight for respective molecules have also been enumerated. Thirty-one new diatomic molecules/molecular ions/radicals of astrophysical significance have also been listed.Astrophysics and Space Science Review Paper.     

Petrology of the Basic Granulites from Kodaikanal, South India

Basic granulites occurring as small enclaves and pods within charnockites contain predominantly orthopyroxene, clinopyroxene, hornblende, plagioclase feldspar and quartz. Chemical composition of coexisting orthopyroxene, clinopyroxene, plagioclase and hornblende has been represented in ACF and AFM diagrams. The mineral assemblages and the textural relationships of the basic granulites have been described. Garnet is notably absent in the basic granulites and this is explained as due to lower (< 8 kbar) pressure and relatively magnesian bulk composition.     

Validation of TRMM-3B42 precipitation product over the tropical Indian Ocean using rain gauge data from the RAMA buoy array

In the present study, an attempt has been made to validate the Tropical Rainfall Measuring Mission (TRMM) Multisatellite Precipitation Analysis (TMPA)-3B42 recently released version 7 product over the tropical Indian Ocean using surface rain gauges from the National Oceanic and Atmospheric Administration/Pacific Marine Environmental Laboratory Research Moored Array for African–Asian–Australian Monsoon Analysis and Prediction buoy array available since late 2004. The validation exercise is carried out at daily scale for an 8-year period of 2004–2011. Results show statistically significant linear correlation between these two precipitation estimates ranging from 0.40 to 0.89 and the root-mean-square error varies from about 1 to 22 mm day^?1. Although systematic overestimation of precipitation by the TMPA product is evident over most of the buoy locations, the TMPA noticeably underestimates higher (more than 100 mm day^?1) and light (less than 0.5 mm day^?1) precipitation events. The highest correlation is observed during the southwest monsoon season (June–September) even though bias is the maximum possibly due to relatively lower fraction of stratiform precipitation during the monsoon season than other seasons. Furthermore, the TMPA estimates slightly underestimate or misses intermittent warm precipitation events as compared to the precipitation radar derived precipitation rates.     

Suspended sediment dynamics on a seasonal scale in the Mandovi and Zuari estuaries,central west coast of India

Suspended particulate matter (SPM) collected at regular stations from the Mandovi and Zuari estuaries indicates that the peaks of high SPM coincide with peaks of high rainfall and low salinity and also with peaks of moderate/low rainfall coupled with high salinity during the monsoon. The estuarine turbidity maximum (ETM) is a characteristic feature, it occurs in the channel accompanying spring tide during the monsoon and pre-monsoon, and shifts to the bay on neap tide during post-monsoon. ETM remains at the same position in the Mandovi River, both during the monsoon and pre-monsoon, whereas in Zuari it stretched upstream during monsoon and migrates seaward of the channel during pre-monsoon. The ETM coincides with the freshwater–seawater interface during the monsoon and is formed by the interaction between tidal currents and river flows. The ETM during pre-monsoon is associated with high salinities and is generated by tidal and wind-induced currents. The turbidity maximum on neap tide during post-monsoon may be due to the erosion and resuspension of sediments from the emergent tidal flats and transport of these turbid waters into the bay. Funneling effect of the narrowing bay in the Zuari estuary and associated physical processes effectively enhance the magnitude of the currents and transports sediments to the channel. SPM retention percentage indicates that the estuarine channel is prone to siltation.     

Petrography and provenance of Upper Cretaceous – Palaeogene sandstones in the foreland basin system of Central Nepal

Sedimentary deposits of the Cretaceous to Miocene Tansen Group of Lesser Himalayan association in central Nepal record passive-margin sedimentation of the Indian Continent with direct deposition onto eroded Precambrian rocks (Sisne Formation onto Kaligandaki Supergroup rocks), succeeded by the appearance of orogenic detritus as the Indian continent collided with Asia on a N-dipping subduction zone. Rock samples from two field traverses were examined petrographically and through detrital zircon U–Pb dating, one traverse being across the Tansen Group and another across the Higher and Tethyan Himalaya (TH). The Tansen Group depositional ages are well known through fossil assemblages. We examined samples from three units of the Tansen Group (Amile, Bhainskati, and Dumri Formations). The Sedimentary petrographic data and Qt F L and Qm F Lt plots indicate their ‘Quartzose recycled’ nature and classify Tansen sedimentary rocks as ‘recycled orogenic’, suggesting Indian cratonic and Lower Lesser Himalayan (LLH) sediments as the likely source of sediments for the Amile Formation (Am), the TH and the Upper Lesser Himalaya (ULH) as the source for the Bhainskati Formation (Bk), and both the Tethyan and Higher Himalaya (HH) as the major sources for the Dumri Formation (Dm). The Cretaceous–Palaeocene pre-collisional Am is dominated by a broad detrital zircon U–Pb ~1830 Ma age peak with neither Palaeozoic nor Neoproterozoic zircons grains, but hosts a significant proportion (23%) of syndepositional Cretaceous zircons (121–105 Ma) would be contributions from the LLH volcanosedimentary arc, Gangdese batholith (including the Xigaze forearc). The other formations of the Tansen Group are more similar to Tethyan units than to Higher Himalaya Crystalline (HHC). From the analysed samples, there is a lack of distinctive evidence or HH detritus in the Tansen basin. Furthermore, the presence of ~23±1 Ma zircons from the HH unit suggests that they could not have been exposed until the earliest Miocene time.     

Hydrochemical and isotopic characterization of groundwater in the southeastern part of the Plateaux Region,Togo

Hydrochemical, inverse geochemical modelling and isotopic approaches are used to assess the hydrogeochemical evolution of groundwater from the basement aquifers in the southeastern part of the Plateaux Region, Togo. Groundwater originates from present-day rainwater infiltration and is mostly fresh and slightly acidic to neutral. Hydrochemical facies are predominantly mixed cations-HCO₃ associated with Ca/Mg-Cl, Na-HCO₃ and Na-Cl water types in equilibrium with kaolinite and Ca/Mg-smectites. They are related to silicates hydrolysis, anthropogenic contamination, nitrification/denitrification, mixing along flowpaths and dissolution/precipitation of secondary minerals. The pattern of flow paths is in accordance with an increasing trend in total dissolved solids (TDS) toward the potentiometric depression located in the central and southern parts of the aquifer system. Inverse geochemical modelling using the NETPATH-WIN model showed the relative importance of biotite, plagioclase and amphibole weathering and dissolution of secondary carbonate minerals along the flowpath, suggesting that an abundance of minerals is not necessarily the main factor controlling the groundwater chemistry evolution.     

A novel insight into vertical ground motion modelling in earthquake engineering

Recent observations of failure and damage of buildings and structures under seismic action has led to an increasing interest for an in-depth analysis of the vertical component of site ground motion. In particular, when dealing with saturated soils, the current engineering practice does not usually go beyond the simplified $u$–$p$ formulation of the Biot's equations describing the coupled hydro-mechanical behaviour, thus neglecting some terms of fluid inertial forces, despite the presence of more refined formulations, for example, the $u$–$U$ formulation. Therefore, a theoretical and numerical validation of the $u$–$p$ formulation as compared with the $u$–$U$ formulation is proposed in this work, where the numerical simulations are compared with the analytical solution for the $u$–$p$ formulation, which is also derived and illustrated in this text. The comparison between the two formulations and the analytical solution is provided for different levels of permeability and dynamic actions, which are representative of a wide scenario of site ground properties and seismic hazard in the vertical direction. In particular, the soil response is analysed in terms of acceleration and pore pressure time history, frequency content, acceleration response spectrum, and amplification ratio of acceleration. This study extends the discussion of the limits of applicability of the $u$–$p$ formulation with respect to the rigorous solution of Biot's equations (obtained here with $u$–$U$ formulation) to the context of a complex dynamic regime provided by the vertical components of real earthquake records, and paves the way for further investigations.