Chemical behavior of the Salí River, Province of Tucumán, Argentina

Major ionic composition and other chemical parameters were determined at five sampling stations on the Salí River (Province of Tucumán, Argentina). The heavy human usage of the river causes increased levels of dissolved ions, from the dissolution of halite and gypsum, and from the weathering of basic sediments. Correlations demonstrate that sodium chloride and sulphate, and calcium carbonate are the main contributors to dissolved ions in the river. In the polluted region, south of the Celestino Gelsi dam, the main source of calcium and sulphate is the dissolution of gypsum. Large amounts of halite are also dissolved. Weathering of biotite, K-feldspar and albite are suggested by the data. Conductivity, dissolved oxygen and organic matter all indicate severe contamination by organic matter (mainly from sugar-cane processing) in the lower course. The data also demonstrate a substantial improvement in water quality before the discharge of the river at the Río Hondo dam. Data from the Colorado (a tributary of the Salí River) and Medina rivers are also analyzed and compared.     

Geochemistry of groundwater in the alluvial plain of Tucumán province, Argentina

The Salí River hydrogeological basin is one of the most productive artesian basins in Argentina. It is located in the southeastern part of the province of Tucumán, northwestern Argentina, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow pattern and time of residence. Three hydrochemical zones are defined in the study area and the processes that control the chemical composition of the water are manifestly different in each zone. The dissolution of halite, sodium sulphate, and gypsum explains part of the contained Na⁺, K⁺, Cl^–, SO₄ ^2–, and Ca²⁺, but other processes, such as cation exchange, calcite precipitation, weathering of aluminosilicates, and gas exchange with the atmosphere, also contribute to the water composition. The assessment of contamination indicators, such as pH, dissolved organic matter, dissolved oxygen, phosphate, and nitrate, indicates that the groundwater is suitable for human consumption. However, biological contamination has been detected in samples from some wells, especially those near the Salí River. Electronic Publication     

Effect of neutrino magnetic moment on solar neutrino observations

Neutrino spin precession effects in the magnetic field of the Sun are considered as an explanation of the outcome of Davis' solar neutrino experiments. Theoretically, it is possible to account for a neutrino magnetic moment only as the result of the interaction of the electromagnetic field with charged particles into which the neutrino can transform virtually. The currently accepted theory of weak interactions (the two component neutrino andV-A interactions) forbids a resulting magnetic moment interaction with the electromagnetic field for all such virtual processes. Modifications of this theory are considered to find out whether an appreciable precession effect is permitted within the experimentally established limits. It is found that the value for the neutrino magnetic moment evaluated under these theoretically anomalous circumstances is still so small that only the largest possible estimate for the magnetic field strength in the Sun's interior would cause the required effect.The author has received scholarship support from the Latin American Scholarship Program of American Universities during the preparation of this work.     

Predation on the rocky shores of Patagonia,Argentina

Rocky intertidal communities of Argentinean Patagonia are exposed to harsh physical conditions caused by dry, strong southern trade winds (mean speed 45 km h^-1, gusts up to 140 km h^-1) that result in intense desiccation of intertidal organisms. Predator distributions in these communities were evaluated from April 2003 to December 2004 at two exposed headlands and six protected bays in Cabo dos Bahias (44°50′S, 65°40′W). Crabs and sea stars dominated the predator assemblage, with occasional scavenger snails and fish also present. During low tide, predators were never found in the open but were always associated with shelter (primarily within mussel beds and coralline algae), suggesting a strong predator dependency on foundation species to buffer them from physical stress. Few predators (mostly crabs) emerged from shelter at high tide. Unlike the larger predators found on Chilean rocky shores, invertebrate predators in this system are diminutive, generally < 2 cm. The lone exception was the newly discovered invasive green crab,Carcinus mamas. Feeding trials, gut content analyses, and visual surveys indicated that native predators feed primarily on small, soft-bodied prey.C. mamas fed on slow-moving and sessile animals, including the super abundant musselPerumytilus purpuratus, with much greater voracity than native predators. Because native intertidal organisms are dependent on mussel beds and coralline algae for shelter from desiccation, successful invasion ofC. mamas may lead to a significant decrease in native diversity by consuming foundation species. This study represents a preliminary survey of predator distributions and feeding habits on the rocky shores of Argentinean Patagonia and provides important baseline data to evaluate trophic linkages and predatory effects on Patagonian rocky shores.     

Geochemical Evidence for Slab Melting in the Trans-Mexican Volcanic Belt

Geochemical studies of Plio-Quaternary volcanic rocks from theValle de Bravo–Zitácuaro volcanic field (VBZ) incentral Mexico indicate that slab melting plays a key role inthe petrogenesis of the Trans-Mexican Volcanic Belt. Rocks fromthe VBZ are typical arc-related high-Mg andesites, but two differentrock suites with distinct trace element patterns and isotopiccompositions erupted concurrently in the area, with a traceelement character that is also distinct from that of other Mexicanvolcanoes. The geochemical differences between the VBZ suitescannot be explained by simple crystal fractionation and/or crustalassimilation of a common primitive magma, but can be reconciledby the participation of different proportions of melts derivedfrom the subducted basalt and sediments interacting with themantle wedge. Sr/Y and Sr/Pb ratios of the VBZ rocks correlateinversely with Pb and Sr isotopic compositions, indicating thatthe Sr and Pb budgets are strongly controlled by melt additionsfrom the subducted slab. In contrast, an inverse correlationbetween Pb(Th)/Nd and ¹⁴³Nd/¹⁴⁴Nd ratios, which extend to lowerisotopic values than those for Pacific mid-ocean ridge basalts,indicates the participation of an enriched mantle wedge thatis similar to the source of Mexican intraplate basalts. In addition,a systematic decrease in middle and heavy rare earth concentrationsand Nb/Ta ratios with increasing SiO₂ contents in the VBZ rocksis best explained if these elements are mobilized to some extentin the subduction flux, and suggests that slab partial fusionoccurred under garnet amphibolite-facies conditions. KEY WORDS: arcs; mantle; Mexico; sediment melting; slab melting     

Fire‐induced changes in soil water repellency increased fingered flow and runoff rates following the 2004 Huelva wildfire

Water repellency (WR) from fire‐affected soils can affect infiltration processes and increase runoff rates. We investigated the effects of fire‐induced changes in soil WR and the related soil hydrological response after one of the largest wildfires in Spain in recent years. The vertical distribution of WR in soil profiles was studied under oak and pine forests and the wetting pattern was analysed after rainfall simulations (85 mm h^?1 during 60 min). After burning, the persistence of WR in soils under oaks increased in the upper 0–5 cm of soil in comparison with pre‐fire WR, but no significant changes were observed under pines. After a fire, WR was stronger and the thickness of the water‐repellent layer increased in soils under pines in the upper 0–16 cm of soil. The hydrophobic layer was thinner under oaks, where no strong to extremely water‐repellent samples were observed below 12 (in burnt soils) and 8 cm (in unburnt soils). Uniform wetting was observed through soil depth in burnt and unburnt soils under oaks, as a consequence of the prevailing matrix flux infiltration. Water was mostly stored in the upper few centimetres and soil became rapidly saturated, favouring a continuous rise in the runoff rate during the experiments. Moisture profiles under pines showed a heterogeneous wetting pattern, with highly irregular wetting fronts, as a result of wettable and water‐repellent three‐dimensional soil patches. In this case, runoff rates on burnt plots increased in relation to unburnt plots, but runoff generation reached a steady state after 25–30 min of simulated rainfall at an intensity of 85 mm h^?1. Rainfall water infiltrated over a small part of the ponded area, where the vertical pressure of the water column overcame the WR. Copyright © 2010 John Wiley & Sons, Ltd.     

Inference of Solar Magnetic Field Parameters from Data with Limited Wavelength Sampling

We investigate the diagnostic potential of polarimetric measurements with filtergraph instruments. Numerical simulations are used to explore the possibility of inferring the magnetic field vector, its filling factor, and the thermodynamics of model atmospheres when only a few wavelength measurements are available. These simulations assume the magnetic Sun to be represented by Milne–Eddington atmospheres. The results indicate that two wavelength measurements are insufficient to reliably determine the magnetic parameters, regardless of whether magnetograph techniques or least-squares fitting inversions are used. However, as few as four measurements analyzed with the inversion technique provide enough information to retrieve the intrinsic magnetic field with an accuracy better than 10% in most cases.     

Inverse problem in hydrogeology

The state of the groundwater inverse problem is synthesized. Emphasis is placed on aquifer characterization, where modelers have to deal with conceptual model uncertainty (notably spatial and temporal variability), scale dependence, many types of unknown parameters (transmissivity, recharge, boundary conditions, etc.), nonlinearity, and often low sensitivity of state variables (typically heads and concentrations) to aquifer properties. Because of these difficulties, calibration cannot be separated from the modeling process, as it is sometimes done in other fields. Instead, it should be viewed as one step in the process of understanding aquifer behavior. In fact, it is shown that actual parameter estimation methods do not differ from each other in the essence, though they may differ in the computational details. It is argued that there is ample room for improvement in groundwater inversion: development of user-friendly codes, accommodation of variability through geostatistics, incorporation of geological information and different types of data (temperature, occurrence and concentration of isotopes, age, etc.), proper accounting of uncertainty, etc. Despite this, even with existing codes, automatic calibration facilitates enormously the task of modeling. Therefore, it is contended that its use should become standard practice.

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Resumen Se sintetiza el estado del problema inverso en aguas subterráneas. El énfasis se ubica en la caracterización de acuíferos, donde los modeladores tienen que enfrentar la incertidumbre del modelo conceptual (principalmente variabilidad temporal y espacial), dependencia de escala, muchos tipos de parámetros desconocidos (transmisividad, recarga, condiciones limitantes, etc), no linealidad, y frecuentemente baja sensibilidad de variables de estado (típicamente presiones y concentraciones) a las propiedades del acuífero. Debido a estas dificultades, no puede separarse la calibración de los procesos de modelado, como frecuentemente se hace en otros campos. En su lugar, debe de visualizarse como un paso en el proceso de entendimiento del comportamiento del acuífero. En realidad, se muestra que los métodos reales de estimación de parámetros no difieren uno del otro en lo esencial, aunque sí pueden diferir en los detalles computacionales. Se discute que existe amplio espacio para la mejora del problema inverso en aguas subterráneas: desarrollo de códigos amigables al usuario, acomodamiento de variabilidad a través de geoestadística, incorporación de información geológica y diferentes tipos de datos (temperatura, presencia y concentración de isótopos, edad, etc), explicación apropiada de incertidumbre, etc. A pesar de esto, aún con los códigos existentes, la calibración automática facilita enormemente la tarea de modelado. Por lo tanto, se sostiene que su uso debería de convertirse en práctica standard.

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Résumé Létat du problème inverse des eaux souterraines est synthétisé. Laccent est placé sur la caractérisation de laquifère, où les modélisateurs doivent jouer avec lincertitude des modèles conceptuels (notamment la variabilité spatiale et temporelle), les facteurs déchelle, plusieurs inconnues sur différents paramètres (transmissivité, recharge, conditions aux limites, etc.), la non linéarité, et souvent la sensibilité de plusieurs variables détat (charges hydrauliques, concentrations) des propriétés de laquifère. A cause de ces difficultés, le calibrage ne peut être séparé du processus de modélisation, comme cest le cas dans dautres cas de figure. Par ailleurs, il peut être vu comme une des étapes dans le processus de détermination du comportement de laquifère. Il est montré que les méthodes dévaluation des paramètres actuels ne diffèrent pas si ce nest dans les détails des calculs informatiques. Il est montré quil existe une large panoplie de techniques d ‹inversion : codes de calcul utilisables par tout-un-chacun, accommodation de la variabilité via la géostatistique, incorporation dinformations géologiques et de différents types de données (température, occurrence, concentration en isotopes, âge, etc.), détermination de lincertitude. Vu ces développements, la calibration automatique facilite énormément la modélisation. Par ailleurs, il est souhaitable que son utilisation devienne une pratique standardisée.

     

利用遥感技术建立墨西哥热带地上生物量模型(英文)

Spatially-explicit estimation of aboveground biomass(AGB) plays an important role to generate action policies focused in climate change mitigation,since carbon(C) retained in the biomass is vital for regulating Earth’s temperature.This work estimates AGB using both chlorophyll(red,near infrared) and moisture(middle infrared) based normalized vegetation indices constructed with MCD43A4 MODerate-resolution Imaging Spectroradiometer(MODIS) and MOD44B vegetation continuous fields(VCF) data.The study area is located in San Luis Potosí,Mexico,a region that comprises a part of the upper limit of the intertropical zone.AGB estimations were made using both individual tree data from the National Forest Inventory of Mexico and allometric equations reported in scientific literature.Linear and nonlinear(expo-nential) models were fitted to find their predictive potential when using satellite spectral data as explanatory variables.Highly-significant correlations(p = 0.01) were found between all the explaining variables tested.NDVI62,linked to chlorophyll content and moisture stress,showed the highest correlation.The best model(nonlinear) showed an index of fit(Pseudo-r2) equal to 0.77 and a root mean square error equal to 26.00 Mg/ha using NDVI62 and VCF as explanatory variables.Validation correlation coefficients were similar for both models:lin-ear(r = 0.87**) and nonlinear(r = 0.86**).     

Relationship between climate change and vegetation distribution in the Mediterranean mountains: Manzanares Head valley, Sierra De Guadarrama (Central Spain)

This work analyzes the consequences of climate change in the distribution of the Mediterranean high-mountain vegetation. A study area was chosen at the Sierra de Guadarrama, in the center of the Iberian Peninsula (1,795 to 2,374 m asl). Climate change was analyzed from the record of 18 variables regarding temperature, rainfall and snowfall over the period 1951–2000. The permanence of snow cover (1996–2004), landforms stability and vegetation distribution in 5 years (1956, 1972, 1984, 1991 and 1998) were all analyzed. The Nival Correlation Level of the different vegetation classes was determined through their spatial and/or temporal relationship with several climatologic variables, snow cover duration and landforms. In order to quantify trends and major change processes, areas and percent changes were calculated, as well as Mean Annual Transformation Indices and Transition Matrices. The findings reveal that in the first part of the study period (up to the first half of the 1970s) the temperature rise in the mid-winter months caused the reduction of some classes of nival vegetation, while others expanded, favored by high rainfall, decrease in both maximum temperatures and summer aridity, and longer snow cover duration. The second part of the study period was characterized by the consolidation of the increase in all thermal variables, along with an important reduction in rainfall volume and snow cover duration. As a result, herbaceous plants, which are highly correlated with a long snow permanence and abundance of melting water, have been replaced by leguminous shrubs which grow away from the influence of snow, and which are steadily becoming denser.