Chemical and isotopic variations in the Wiśniówka Mała mine pit water,Holy Cross Mountains (south-central Poland)

In 2005 and 2006, hydrogeochemical study was carried out in the bipartite Wiśniówka Mała pit lake of the Holy Cross Mountains (south-central Poland). This is the largest acidic water body in Poland. This report presents the element concentrations in the water and sediment, stable sulfur and oxygen isotope ratios in the soluble sulfates, and stable oxygen isotope ratio in the water. The scope of the investigation also encompassed mineralogical examinations (scanning electron microscope, X-ray diffraction) of the sediment. The results of this study show that there is a spatial and temporal variability in concentrations of most elements and sulfur isotope ratios in the examined pit lake. The water of the western pond displayed a lower pH with a mean of 3.73 and higher conductivity (390 μS cm⁻¹) as well as higher concentrations of sulfates (156 mg L⁻¹) and most of the cations and anions. The concentrations of Fe²⁺ and Fe³⁺ averaged 0.8 and 0.4 mg·L⁻¹. In contrast, the eastern pond water revealed a higher pH (mean of 4.36), lower conductivity (293 μS cm⁻¹) and lower sulfate (90 mg L⁻¹) and trace metal levels. Similar variations were recorded in the stable sulfur isotope ratios. The δ³⁴S_V-CDT(SO₄ ²⁻) values in the water of the western pit pond were in the range of −6.7 to −4.6‰ (mean of −5.6‰), whereas that in the eastern pit pond ranged from −2.2 to −0.9‰ (−1.6‰). The alkalinity of the entire lake water was below 0.1 mg·L⁻¹ CaCO₃. No distinct difference in the δ¹⁸O_V-SMOW(SO₄ ²⁻) was noted between the western and eastern pit ponds. Compared to the Purple Pond in the Sudetes (Poland) and similar sites throughout the world, the examined pit lake is highlighted by distinctly low concentrations of sulfates, iron and other trace metals. Based on this and other studies performed in the Holy Cross Mountains, a conclusion can be drawn that the SO₄ ²⁻ in the Wiśniówka Mała pit lake water is a mixture of SO₄ ²⁻ derived from the following sources: (1) pyrite oxidation (especially in the western pond water), (2) leaching of soluble sulfates from soils and waste material, as well as (3) subordinate deposition of airborne sulfate precipitation.     

A new procedure to estimate the RUSLE EI30 index, based on monthly rainfall data and applied to the Algarve region, Portugal

One of the best indicators of the potential erosion risks is the rainfall–runoff erosivity factor (R) of the revised universal soil loss equation (RUSLE). Frequently, however, there is not enough data available to compute the R value, and other parameters, such as the modified Fournier index (F_mod), are used instead. But RUSLE is less effective if only the alternative procedures exist. One of the major discrepancies between R and the alternative parameters is time resolution: individual storms are used to calculate R while monthly averages over the year are used to calculate F_mod.

In this study, a multiple linear regression (r²=0.89) involving monthly EI₃₀, monthly rainfall for days with ≥10.0 mm and monthly number of days with rainfall ≥10.0 mm, for the Algarve region, is presented. Twenty-seven years of monthly rainfall erosivity values were computed for the 32 standard daily-read raingauge stations of the Algarve region.     

Base isolation for retrofitting historic buildings: Evaluation of seismic performance through experimental investigation

An experimental test program on a full‐scale model representing a sub‐assemblage of the cloister facade of the Sao Vicente de Fora monastery, retrofitted through base isolation, has been recently carried out at the European Laboratory for Structural Assessment of the Joint Research Centre of the European Commission. In this paper an overview of the laboratory model and the experimental results is provided. In particular, firstly the test model is described, including the geometry and mechanical properties of the masonry specimen and the design of the isolation devices; then the testing method and the sub‐structuring of the isolation system are described and the seismic inputs adopted for the pseudo‐dynamic tests are defined. Finally, the experimental results are discussed and compared to the analogous results obtained on the ‘as is’, fixed‐base sub‐assemblage model. The implications of the test outcomes are emphasized and developments of this research line are presented. Copyright © 2001 John Wiley & Sons, Ltd.     

Arsenic in the groundwater of Ouro Preto (Brazil): its temporal behavior as influenced by the hydric regime and hydrogeology

In the city of Ouro Preto (MG), water catchment for public supply originates from superficial drainage, springs, old abandoned mines and some driven wells. In the rocks of the region, As is originally found in gold-enriched sulphide-bearing mineral deposits. The weathering process introduces As into the hydrological system by dissolution of this element into the leachate. Measurement of the As content in the groundwater of some catchments was carried out during 1 year and these measurements demonstrated high As content—up to 224 μg L⁻¹ of As(V)—during the rainy season (the maximum concentration limit according to World Health Organization is 10 μg L⁻¹). Lower values were observed during the dry season and in some sampling stations, As was not even detected. The As concentration variability during 1 year shows a strict and direct relationship to seasonal and hydrological conditions. For city authorities, responsible for public water supply, it is necessary to perform a complete inventory of the water sources used and constantly monitor the As content in the water.     

Experimental verification of effective anisotropic crack theories in variable crack aspect ratio medium

Physical modelling of cracked/fractured media using downscaled laboratory experiments has been used with great success as a useful alternative for understanding the effect of anisotropy in the hydrocarbon reservoir characterization and in the crustal and mantle seismology. The main goal of this work was to experimentally verify the predictions of effective elastic parameters in anisotropic cracked media by Hudson and Eshelby–Cheng's effective medium models. For this purpose, we carried out ultrasonic measurements on synthetic anisotropic samples with low crack densities and different aspect ratios. Twelve samples were prepared with two different crack densities, 5% and 8%. Three samples for each crack density presented cracks with only one crack aspect ratio, whereas other three samples for each crack density presented cracks with three different aspect ratios in their composition. It results in samples with aspect ratio values varying from 0.13 to 0.26. All the cracked samples were simulated by penny‐shaped rubber inclusions in a homogeneous isotropic matrix made with epoxy resin. Moreover, an isotropic sample for reference was constructed with epoxy resin only. Regarding velocity predictions performed by the theoretical models, Eshelby–Cheng shows a better fit when compared with the experimental results for samples with single and mix crack aspect ratio (for both crack densities). From velocity values, our comparisons were also performed in terms of the ε, γ, and δ parameters (Thomsen parameters). The results show that Eshelby–Cheng effective medium model fits better with the measurements of ε and γ parameters for crack samples with only one type of crack aspect ratio.     

Hydrodynamic parameters in a flood impacted boulder block ramp: Krzczonówka mountain stream,Polish Carpathians

Boulder block ramps are river engineering structures used to stabilise river beds. Block ramps provide a semi-natural and aesthetically pleasing solution to certain river engineering problems in mountain streams. When constructing block ramps,one can use the dissipative behaviour of large macroroughness elements randomly placed on the river bed to enhance fish migration in an upstream direction thus, in this sense, meeting the requirements of the EU Water Framework Directive. Block ramps are often designed and constructed to replace damaged drop hydraulic structures in the channels of mountain streams. This paper investigates the resilience of a particular block ramp placed in the Krzczonówka stream(Polish Carpathians) in terms of the engineering design function and its durability against damaging. A hydrodynamic analysis of a block ramp is presented before and after a flood event that changed the configuration of the blocks. The seminatural unstructured hydraulic structure was built on the Krzczonowka stream to protect gas pipes which are located beneath it. As a result of several floods, the boulder block chute described in this paper was damaged, and some boulders were dislodged and transported downstream. Our post-flood investigations of bathymetry and velocity revealed that even damaged boulder blocks, removed from the chute and displaced downstream of the structure, still provide significant energy dissipation of the flowing water. The novel of our paper is for the first time showing very detailed analysis of unstructured block ramp hydrodynamics parameters done in the field.Also the novel finding of our investigations shows that before and after the flood event the unstructured block ramp structure, is still fish friendly in terms of hydrodynamics.     

Heat capacities of Tschermak substituted Fe-biotite

Six members of the annite–siderophyllite join were synthesized in a three step process – crystallization of biotite from gels, decomposition of the fine-grained biotite under oxidizing conditions and resynthesis of Fe-Al biotite with planned compositions from these products – producing biotite crystals with thicknesses of up to 10 μm. The biotite was characterized by microprobe, electron microscopy and X-ray diffraction. Heat capacities of these biotites were measured with a DSC (differential scanning calorimeter) over the temperature range 143 to 623 K. Using a least-squares technique, the data were fitted to a c_p-polynomial, c _p =k ₀+k ₁ T ^−0.5+ k ₂ T ⁻²+k ₃ T ⁻³. In the temperature range 143 to 250 K, heat capacities of the different annite–siderophyllite members decrease linearly with increasing Al content. At higher temperatures, however, the c_p-polynomial of biotites with intermediate composition (except Ann₇₉Sid₂₁) exhibit a steeper slope than those of other biotites. This produces positive excess heat capacities in the annite–siderophyllite join at higher temperatures. The activity-composition data of the same binary derived from phase equilibrium experiments (Benisek et al. 1996) and the data of this study suggest two compositional regions along this join, with different extent of deviation from ideality. One at X _Sid < 0.3, characterized by a small deviation, one at X _Sid > 0.3 showing a higher nonideality, resulting in a discontinuity visible at this composition. Powder IR-spectra of these solid solutions were measured with a FTIR-spectrometer and used to calculate heat capacities according to the vibrational model of Kieffer (1979). The comparison of the vibrational function with the c_p-polynomials shows that the vibrational function reproduces well the DSC-data of the siderophyllite-poor and -rich members, but deviates for intermediate compositions, where the excess heats of mixing occur. With increasing Tschermak vector, the tetrahedral rotation angle α increases from 0 to 13° for annite to siderophyllite, respectively. At the composition of the discontinuity, this rotation angle α reaches a value of ∼8^∘. The processing of ∼300 chemical data of natural biotites indicates that over 90% of them have a tetrahedral rotation angle that lies between 7 and 9°. It would appear that biotites with these structural characteristics are most stable. Received: 27 August 1998 / Accepted: 10 November 1998     

DAMÉE-NAB: the base experiments

The results of an intercomparison experiment performed with five numerical ocean models of different architecture are presented. While all models are able to simulate the large-scale characteristics of the North Atlantic circulation with a fair degree of realism, they also exhibit differences that can be attributed to the choices made in vertical coordinates, domain size, and boundary conditions.