U-series evidence for crustal involvement and magma residence times in the petrogenesis of Parinacota volcano, Chile

In this study, we present Th–U disequilibria as well as radiogenic and trace element data for recent volcanic rocks from the Nevados de Payachata volcano which erupted through ∼70 km of continental crust in the Central Volcanic Zone of the Andes (18°S, 69°W). Both lavas and mineral separates were analyzed by mass spectrometry for ²³⁸U–²³⁰Th disequilibria. The lavas are characterized either by ²³⁰Th enrichment or depletion relative to its parent nuclide ²³⁸U. Mineral separates are used to derive U–Th isochron ages and these ages compare favorably with inferred stratigraphic ages or K–Ar ages, although in one case the U–Th age is significantly older than the stratigraphic age. Despite relatively constant Sr, Nd, and Pb isotope ratios, the lavas display inverse trends in ²³⁰Th/²³⁸U versus Ce/Yb or Ba/Hf diagrams. These trends cannot be interpreted by simple two-component mixing. Rather, there must be three (and perhaps four components) involved in the genesis of the Parinacota lavas. A mantle wedge, a slab fluid, and a lower crustal component can be identified. A sediment component is more difficult to detect as it is difficult to decipher its signature because of the strong crustal influence. The existence of binary arrays can be explained by variable amounts of crustal material. The process of crust–mantle interaction must have been short enough to preserve U–Th disequilibrium (<300 ka). Received: 21 April 1999 / Accepted: 11 March 2000     

Lippmann Diagrams: Theory and Application to Carbonate Systems

Since 1980 when F. Lippmann's seminal paper appeared, ourunderstanding of solubility equilibria involving ionic solidsolutions has been advanced by theoretical considerations as wellas careful experimental studies designed to determine excess Gibbsfunctions. A unified theory of solid-solution aqueous-solutionequilibria as well as the thermodynamic background of thephenomenon of ``stoichiometric saturation' are reviewed.It is shown that Lippmann diagrams effectively summarize thethermodynamic basis of solid-solute aqueous-solution equilibria ofsparingly soluble metal carbonate systems. Clearly, the predictivepower of these diagrams may be limited due to kineticrestrictions. Only when dissolution and precipitation areessentially reversible, favourable conditions to synthesizehomogeneous solid phases can be derived from studies of equilibria.     

Some modifications of Stokes' formula that account for truncation and potential coefficient errors

 Stokes' formula from 1849 is still the basis for the gravimetric determination of the geoid. The modification of the formula, originating with Molodensky, aims at reducing the truncation error outside a spherical cap of integration. This goal is still prevalent among various modifications. In contrast to these approaches, some least-squares types of modification that aim at reducing the truncation error, as well as the error stemming from the potential coefficients, are demonstrated. The least-squares estimators are provided in the two cases that (1) Stokes' kernel is a priori modified (e.g. according to Molodensky's approach) and (2) Stokes' kernel is optimally modified to minimize the global mean square error. Meissl-type modifications are also studied. In addition, the use of a higher than second-degree reference field versus the original (Pizzetti-type) reference field is discussed, and it is concluded that the former choice of reference field implies increased computer labour to achieve the same result as with the original reference field. Received: 14 December 1998 / Accepted: 4 October 1999     

Analysis of the positive ionospheric response to a moderate geomagnetic storm using a global numerical model

Current theories of F-layer storms are discussed using numerical simulations with the Upper Atmosphere Model, a global self-consistent, time dependent numerical model of the thermosphere-ionosphere-plasmasphere-magnetosphere system including electrodynamical coupling effects. A case study of a moderate geomagnetic storm at low solar activity during the northern winter solstice exemplifies the complex storm phenomena. The study focuses on positive ionospheric storm effects in relation to thermospheric disturbances in general and thermospheric composition changes in particular. It investigates the dynamical effects of both neutral meridional winds and electric fields caused by the disturbance dynamo effect. The penetration of short-time electric fields of magnetospheric origin during storm intensification phases is shown for the first time in this model study. Comparisons of the calculated thermospheric composition changes with satellite observations of AE-C and ESRO-4 during storm time show a good agreement. The empirical MSISE90 model, however, is less consistent with the simulations. It does not show the equatorward propagation of the disturbances and predicts that they have a gentler latitudinal gradient. Both theoretical and experimental data reveal that although the ratio of [O]/[N₂] at high latitudes decreases significantly during the magnetic storm compared with the quiet time level, at mid to low latitudes it does not increase (at fixed altitudes) above the quiet reference level. Meanwhile, the ionospheric storm is positive there. We conclude that the positive phase of the ionospheric storm is mainly due to uplifting of ionospheric F2-region plasma at mid latitudes and its equatorward movement at low latitudes along geomagnetic field lines caused by large-scale neutral wind circulation and the passage of travelling atmospheric disturbances (TADs). The calculated zonal electric field disturbances also help to create the positive ionospheric disturbances both at middle and low latitudes. Minor contributions arise from the general density enhancement of all constituents during geomagnetic storms, which favours ion production processes above ion losses at fixed height under day-light conditions.     

Morphology of NmF2 nighttime increases in the Eurasian sector

A statistical analysis of two peaks (pre-midnight and post-midnight) occurrence in NmF2 daily variations was made on a latitudinal chain of four ionosonde stations in the Eurasian longitudinal sector. Overall 6182 cases of the first and 5600 cases of the second peak occurrence were analyzed using all available foF2 observations for the years of solar maximum and minimum. Well-pronounced and systematic variations with season and solar activity were revealed in the occurrence probability of the peaks, their amplitude and timing. The pattern of both peaks occurrence is similar during winter and equinoxes for midlatitude stations implying one and the same mechanism of their formation. The pre-midnight summer peak shows specific variations in particular during solar maximum pointing to a different mechanism controlling its appearance. Possible mechanisms of both peaks formation are discussed.     

On the way to a better state? The role of NGOs in the planning and implementation of protected areas in Brazil

Protected areas are considered some of the most versatile as well as important instruments of nature conservation and environmental policies. The `classic' model of nature conservation aims at the isolation of large areas in order to preserve their `pristine' nature from human interference. However, the transfer of this model to developing countries led to serious conflicts with local people. From a socio-geographical viewpoint, protected areas can be understood as regulative tools for the shaping and controlling of space. This approach helps to recognise the influence of distinct modes of appropriation of space and nature on the emergence and course of conflicts. In the present article it is used to analyse the leading role played by Brazilian NGOs in the transformation of the classic model of protected area management at the beginning of the nineties. Two case studies – dealing with the implementation of the Amazonian Mamirauá Reserve and with the reform of the Brazilian protected area legislation – are used to illustrate not only the success of the new approaches, but also the expectations and contradictions which surround the future development of protected areas in Brazil.     

The equatorial Atlantic oscillation and its response to ENSO

An internal equatorial Atlantic oscillation has been identified by analyzing sea surface temperature (SST) observations. The equatorial Atlantic oscillation can be viewed as the Atlantic analogue of the El Niño/Southern Oscillation (ENSO) phenomenon in the equatorial Pacific, but it is much less vigorous. The equatorial Atlantic oscillation is strongly influenced by the Pacific ENSO with the equatorial Atlantic sea surface temperature lagging by about six months. This lag can be explained by the dynamical adjustment time of the equatorial Atlantic to low-frequency wind stress variations and the seasonally varying background state, which favours strongest growth of perturbations in summer. Results of an extended-range simulation with a coupled ocean-atmosphere GCM support this picture.     

Style and evolution of salt pillows and related structures in the northern part of the Northeast German Basin

The northern part of the Northeast German Basin contains a large number of Late Permian (Zechstein) salt pillows, whereas diapiric structures are almost completely absent. This lack of diapirs facilitated the study of early stages of salt movement in the basin. Salt pillows and related structures were investigated in terms of distribution, geometry and time of initiation of salt flow within the regional geological context. The primary Zechstein thickness in the study area was reconstructed to gain more insight into the relationship between the geometry of the salt layer and the style of the salt-related structures. In this study, no clear spatial relationship between the salt structures and basement faults has been found and the location of the salt structures in this area appears to be highly independent of the underlying structural grain. The overburden is affected by minor faulting. We propose that buckling of the overburden due to regional compression significantly contributed to the initiation of the Late Jurassic to Early Cretaceous salt structures in the basin. Reverse faulting of the Gardelegen and Haldensleben Faults is related to inversion tectonics and exerted a compression on the basin fill. During the deformation, the Late Permian salt layer acted as an efficient detachment and led to a marked decoupling of the Mesozoic overburden from the underlying pre-Zechstein rocks.     

Radiation Induced Dynamics of the Galactic Halo

We show results of numerical simulations of a three component plasma consisting of electrons, ions and dust with external gravitation and radiation fields. We perform simulation runs, starting from an analytic halo equilibrium, balancing pressure, gravitational, and radiative forces. Within these the equilibrium is perturbed by the radiation of a typical OB-star association. The perturbation has a total energy input of 10⁷ L _⊙ and a duration of 30 Myrs. After switching off the perturbation, the simulations are continued to further investigate the dynamics induced. We start with a self consistent one-fluid MHD model without background magnetic field and show for an asymmetric case that the system approaches a new equilibrium after switching on the perturbation. Later it relaxes into the starting configuration again, when the additional radiation is turned off. We then show, first by including a disk-parallel magnetic field and then by redoing the simulations with a full three-fluid code, the influence of magnetic fields and species separation on the plasma dynamics. With our computations we demonstrate that these features can be important for the explanation of the structures of galactic halos and large scale mass flows. This revised version was published online in July 2006 with corrections to the Cover Date.     

Shaping of Planetary Nebulae by Dust Driven AGB Winds

We have investigated the interacting winds model (IWM) in which the shapes of elliptical Planetary Nebulae (PNe) can be explained by the asymmetric mass loss produced by a rotating AGB star. The mass loss mechanism is based on a dust driven wind calculated for stationary situations. Already for small rotation rates of the AGB star we get a significantly angle-dependent mass loss which is concentrated towards the equatorial plane. This pole to equator density variation in the space surrounding the star influences the shape of the later developed PN. We compare these theoretical shapes with observed PNe and for some objects with well known quantities our model can fit the observations quite well. This revised version was published online in July 2006 with corrections to the Cover Date.