Vertical Structure in the Marine Atmospheric Boundary Layer and its Implication for the Inertial Dissipation Method

The structure of the marine atmospheric boundarylayer and the validity ofMonin–Obukhov similarity theory over the seahave been investigated using longterm measurements. Three levels of turbulencemeasurements (at 10 m, 18 mand 26 m) at Östergarnsholm in themiddle of the Baltic Sea have beenanalysed. The results show that turbulentparameters have a strong dependenceon the actual height due to wave influence.The wind profile and thus thenormalised wind gradient are very sensitiveto wave state. The lower part of theboundary layer can be divided into three heightlayers, a wave influenced layerclose to the surface, a transition layer andan undisturbed ordinary surfacelayer; the depth of the layers is determinedby the wave state. This heightstructure can, however, not be found for thenormalised dissipation, which is onlya function of the stability, except duringpronounced swell where the actualheight also has to be accounted for. Theresults have implications for the heightvariation of the turbulent kinetic energy(TKE) budget. Thus, the imbalancebetween production and dissipation willalso vary with height according to thevariation of wave state. This, in turn,will of course have strong implicationsfor the inertial dissipation method, inwhich a parameterisation of the TKEbudget is used.     

Isotopic constraints on the origin of AMCG-suite rocks on the Lofoten Islands, N Norway

Summary ¶Sm–Nd, Rb–Sr and Pb–Pb isotopic compositions of 34 intrusive AMCG (anorthosite–mangerite–charnockite–granite) suite rocks and spatially related ferrodiorites and gabbros from the Lofoten Islands, northern Norway, suggest that almost all Lofoten intrusive rocks can be modelled as a mixture of mainly two components: Archean lower crustal material and an about 1.8Ga mantle-derived component. Isotopically, the gabbros and anorthosites overlap the mangeritic rocks in all three isotope systems. Hence, the isotopic data are in agreement with a model that relates the mangeritic rocks to the fractionation of crustally contaminated mantle-derived basaltic melts. Overlap in all three isotopic systems indicates that at least part of the assimilation process predates or accompanies fractionation. Whole rock geochemistry supports this model: based on major, minor, and trace element data, primitive 1.79–1.86Ga mangerites could have formed from anorthosite residual liquids – the ferrodiorites – by fractionation processes involving Fe–Ti oxides, Fe–Mg silicates and apatite combined with contamination of the ferrodiorites with about 50wt.% crustal anatectic melt.Received May 7, 2002; revised version accepted November 26, 2002 Published online: April 14, 2003     

Evidence for chemical evolution in spectra of high redshift galaxies

Using a sample of 57 VLT FORS spectra in the redshift range 1.37< z < 3.40 and a comparison sample with 36 IUE spectra of local ( ) starburst galaxies we derive CIV equivalent width values and estimate metallicities of starburst galaxies as a function of redshift. Assuming that a calibration of the CIV equivalent widths in terms of the metallicity based on the local sample of starburst galaxies is applicable to high-z objects, we find a significant increase of the average metallicities from about 0.16 Z _⊙ at the cosmic epoch corresponding to z ≈ 3.2 to about 0.42 Z _⊙ at z ≈ 2.3. A significant further increase in metallicity during later epochs cannot be detected in our data. Compared to the local starburst galaxies our high-redshift objects tend to be overluminous for a given metallicity. This revised version was published online in August 2006 with corrections to the Cover Date.     

Velocity Field of a Complex Sunspot with Light Bridges

For the leading part of sunspot group NOAA 8323, which rapidly changed its complex structure, a time series of the line-of-sight (LOS) component of the velocity field was obtained. With a two-dimensional Fabry–Pérot spectrometer, the magnetically insensitive line Fei 557.6 nm was scanned. The inclination of the LOS (heliographic angle) to the vertical was =28.5°. The umbra of the observed spot was divided by a system of light bridges into several parts. The spatial and temporal velocity field also exhibits a considerable complexity: in one extended umbral area there is a downward flow of 1 km s^–1 relative to other dark sub-umbrae. At the center-side penumbra, with a line-of-sight Evershed outflow of 1.5 km s^–1, a persistent patch, somewhat darker than the average penumbra, has a LOS velocity of 1.3 km s^–1 in opposite direction, probably a downflow. At the limb-side penumbra, a photosphere-like area is interspersed, interrupting the Evershed flow which resumes with typical strength beyond this feature towards the outer penumbral boundary. Most interesting is the behavior of the light bridges, which have a slight blue shift, interrupted by short events of strong blue or red shifts which – within the time resolution of 35 s – instantly affect a considerable part of a light bridge.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Fifteen days of continuous activity survey at Stromboli volcano, Italy, in late September 2000: Doppler radar, seismicity, infrared, soil humidity, and mapping of the crater region

The intention of our study was to gain new insight into the complex interplay between different types of eruption of the Stromboli volcano by combining detailed field observation with different geophysical methods. We recorded more than 600 eruptions by use of continuous Doppler radar measurements. We detected the onset of the seismic precursor and the beginning of the visible eruption by use of seismic and infrared data. Two soil samples per day were used to monitor the effect of humidity on the eruptive style. We mapped the crater region as a reference base for the long-term morphological changes of the active region and for the exact positions of our measurement systems. Two distinct types of eruption were distinguished from each other on the basis of seismic and radar data - short, wide-angle Strombolian explosions and pulsating, sharp angle fountain-like eruptions. Data and visual observations imply that weather conditions significantly effect volcanic activity. We also interpret the intensification of eruptive activity during our field study as replenishment of the reservoir with a new batch of magma in late September 2000.     

Critical Self-Organization of Astrophysical Shocks

There are two distinct regimes of the first-order Fermi acceleration of shocks. The first is a linear (test-particle) regime in which most of the shock energy goes into thermal and bulk motions of the plasma. The second is an efficient regime in which the shock energy goes into accelerated particles. Although the transition region between them is narrow, we identify the factors that drive the system toward a self-organized critical state between those two regimes. Using an analytic solution, we determine this critical state and calculate the spectra and maximum energy of accelerated particles.     

Size Fractionation (Dissolved, Colloidal and Particulate) of Trace Metals in the Thur River, Switzerland

The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L^-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions.     

Uncertainty in GPS Networks due to Remaining Systematic Errors: The Interval Approach

A realistic assessment of the total uncertainty budget of Global Positioning System (GPS) observations and its adequate mathematical treatment is a basic requirement for all analysis and interpretation of GPS-derived point positions, in particular GPS heights, and their respective changes. This implies not only the random variability but also the remaining systematic errors. At present in geodesy, the main focus is on stochastic approaches in which errors are modeled by means of random variables. Here, an alternative approach based on interval mathematics is presented. It allows us to model and to quantify the impact of remaining systematic errors in GPS carrier-phase observations on the final results using deterministic error bands. In this paper, emphasis is given to the derivation of the observation intervals based on influence parameters and to the study of the complex linear transfer of this type of uncertainty to estimated point positions yielding zonotopes. From the presented simulation studies of GPS baselines, it turns out that the uncertainty due to remaining systematic effects dominates the total uncertainty budget for baselines longer than 200 km.     

Brest sea level record: a time series construction back to the early eighteenth century

The completeness and the accuracy of the Brest sea level time series dating from 1807 make it suitable for long-term sea level trend studies. New data sets were recently discovered in the form of handwritten tabulations, including several decades of the eighteenth century. Sea level observations have been made in Brest since 1679. This paper presents the historical data sets which have been assembled so far. These data sets span approximately 300 years and together constitute the longest, near-continuous set of sea level information in France. However, an important question arises: Can we relate the past and the present-day records? We partially provide an answer to this question by analysing the documents of several historical libraries with the tidal data using a ‘data archaeology’ approach advocated by Woodworth (Geophys Res Lett 26:1589–1592, 1999b). A second question arises concerning the accuracy of such records. Careful editing was undertaken by examining the residuals between tidal predictions and observations. It proved useful to remove the worst effects of timing errors, in particular the sundial correction to be applied prior to August 1, 1714. A refined correction based on sundial literature [Savoie, La gnomique, Editions Les Belles Lettres, Paris, 2001] is proposed, which eliminates the systematic offsets seen in the discrepancies in timing of the sea level measurements. The tidal analysis has also shown that shallow-water tidal harmonics at Brest causes a systematic difference of 0.023 m between mean sea level (MSL) and mean tide level (MTL). Thus, MTL should not be mixed with the time series of MSL because of this systematic offset. The study of the trends in MTL and MSL however indicates that MTL can be used as a proxy for MSL. Three linear trend periods are distinguished in the Brest MTL time series over the period 1807–2004. Our results support the recent findings of Holgate and Woodworth (Geophys Res Lett) of an enhanced coastal sea level rise during the last decade compared to the global estimations of about 1.8 mm/year over longer periods (Douglas, J Geophys Res 96:6981–6992, 1991). The onset of the relatively large global sea level trends observed in the twentieth century is an important question in the science of climate change. Our findings point out to an ‘inflexion point’ at around 1890, which is remarkably close to that in 1880 found in the Liverpool record by Woodworth (Geophys Res Lett 26:1589–1592, 1999b).