Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

A numerically calibrated reference level (MP28) for the terrestrial mammal-based biozonation of the European Upper Oligocene

The fauna of the Enspel (Westerwald) and the neighbouring Kärlich (Neuwied basin) fossil deposits correspond to the Upper Oligocene Mammal Paleogene (MP) reference level 28 and 28–30, respectively. Basaltic flows and a trachyte tuff terminating and predating the fossil deposit sedimentation allow to numerically calibrate the MP reference levels by radioisotope dating. Laser fusion ⁴⁰Ar/³⁹Ar step heating on volcanic feldspars yield a time interval of 24.9–24.5 Ma for reference level MP28 at Enspel and a maximum age of 25.5 Ma for the time interval MP28–MP30 at Kärlich. Interpolation between the time intervals determined for the Enspel reference level MP28 and the age of the global Oligocene/Miocene boundary of 24.0 ± 0.1 Ma taken from literature results in time intervals of 24.5–24.2 Ma and 24.2–23.9 Ma for the younger reference levels MP29 and MP30, respectively. These intervals of ≤ 0.4 m.y. for MP reference levels of the latest Oligocene are short relative to older Oligocene MP reference levels 21–27 between 34 and 25 Ma. Since subdivision into MP reference levels essentially is based on assemblages of mammal taxa and on evolutionary changes in tooth morphology of mammals short MP time intervals during the latest Oligocene indicate a rapid evolutionary change relative to the early Oligocene.     

Small and large scale fluctuations in atmospheric wind speeds

Atmospheric wind speeds and their fluctuations at different locations (onshore and offshore) are examined. One of the most striking features is the marked intermittency of probability density functions (PDF) of velocity differences, no matter what location is considered. The shape of these PDFs is found to be robust over a wide range of scales which seems to contradict the mathematical concept of stability where a Gaussian distribution should be the limiting one. Motivated by the non-stationarity of atmospheric winds it is shown that the intermittent distributions can be understood as a superposition of different subsets of isotropic turbulence. Thus we suggest a simple stochastic model to reproduce the measured statistics of wind speed fluctuations.     

Zoobenthos of Lake Uluabat,a Ramsar Site in Turkey,and Their Relationship with Environmental Variables

The numerical and proportional distributions of zoobenthos in lake Uluabat, which is located in the Northwestern part of Turkey and having international importance according to the Ramsar Convention, were determined from August 2004 to July 2005 at monthly intervals (except for December 2004, January and February 2005) at 12 different stations. Thirty‐three taxonomic groups were recorded. It was found that the zoobenthos consisted of 35.6 % Oligochaeta, 27.7 % Nematoda, 12.3 % Chironomidae larvae, 10.7 % Gastropoda, 3.6 % Ostracoda, and 10.1 % Varia by numbers (Bivalvia, Ceratopogonidae, Hirudinea, Odonata, Ephemeroptera, Asilidae, Hydraacarina, Hemiptera, Argulidae, and Gammaridae). The average number of invertebrates was 160 individuals for 33 taxa at the 12 different stations. Also some environmental parameters of the lakewater were analyzed (temperature, pH, dissolved oxygen, biochemical oxygen demand, chemical oxygen demand, NO₂–N, NO₃–N, NH₃–N, PO₄^–3, fecal coliform, and total coliform). The relationships between the dynamics of the Oligochaeta and the physicochemical variables were supported by the Pearson correlation index and the canonical correspondence analysis (CANOCO). It was found that the relation between the average number of P. hammoniensis and P. albicola (p < 0.05, r = 0.590 and 0.593, respectively) and L. hoffmeisteri (p < 0.01, r = 0.777) was directly proportional while the relation between the average number of some taxa Trichodrillus sp., Rhyacodrilus coccineus, Nais communis, N. variabilis, and N. barbata and NO₃–N (p < 0.05, r = –0.685) was inversely proportional.     

Atmospheric, oceanic and hydrological contributions to seasonal variations in length of day

 The annual and semiannual residuals derived in the axial angular momentum budget of the solid Earth–atmosphere system reflect significant signals. They must be caused by further excitation sources. Since, in particular, the contribution for the wind term from the atmospheric layer between the 10 and 0.3 hPa levels to the seasonal variations in length of day (LOD) is still missing, it is necessary to extend the top level into the upper stratosphere up to 0.3 hPa. Under the conservation of the total angular momentum of the entire Earth, variations in the oceanic angular momentum (OAM) and the hydrological angular momentum (HAM) are further significant excitation sources at seasonal time scales. Focusing on other contributions to the Earth's axial angular momentum budget, the following data are used in this study: axial atmospheric angular momentum (AAM) data derived for the 10–0.3 hPa layer from 1991 to 1997 for computing the missing wind effects; axial OAM functions as generated by oceanic general circulation models (GCMs), namely for the ECHAM3 and the MICOM models, available from 1975 to 1994 and from 1992 to 1994, respectively, for computing the oceanic contributions to LOD changes, and, concerning the HAM variations, the seasonal estimates of the hydrological contribution as derived by Chao and O'Connor [(1988) Geophys J 94: 263–270]. Using vector representation, it is shown that the vectors achieve a close balance in the global axial angular momentum budget within the estimated uncertainties of the momentum quantities on seasonal time scales. Received: 6 April 2000 / Accepted: 13 December 2000     

Topographic and atmospheric corrections of gravimetric geoid determination with special emphasis on the effects of harmonics of degrees zero and one

 The topographic and atmospheric effects of gravimetric geoid determination by the modified Stokes formula, which combines terrestrial gravity and a global geopotential model, are presented. Special emphasis is given to the zero- and first-degree effects. The normal potential is defined in the traditional way, such that the disturbing potential in the exterior of the masses contains no zero- and first-degree harmonics. In contrast, it is shown that, as a result of the topographic masses, the gravimetric geoid includes such harmonics of the order of several centimetres. In addition, the atmosphere contributes with a zero-degree harmonic of magnitude within 1 cm. Received: 5 November 1999 / Accepted: 22 January 2001     

Hydrogeologic studies for nuclear-waste disposal in Sweden

Safety Report 1997 (SR 97) of the Swedish Nuclear Fuel and Waste Management Company is a comprehensive performance assessment of three hypothetical radioactive waste repositories in Sweden. It includes hydrogeologic studies (data compilation, parameter synthesis, and groundwater flow modeling) to determine groundwater flow and the associated uncertainties for the three sites. This report reviews and compares the hydrogeologic characterization programs, the site characteristics, and the groundwater flow models used in the SR 97 performance assessment. Although differences in site-characterization programs tend to mask differences in site characteristics, the sites do have notable differences that affect the results of the performance assessment. The effects of model uncertainties evaluated by the variant cases appear to be smaller than the variability of results for the base case (best estimate of site conditions) of each site. Electronic Publication