Trace-element composition of Fe-rich residual liquids formed by fractional crystallization: Implications for the Hadean magma ocean

New isotopic studies of ¹⁴²Nd, the daughter product of the short-lived and now extinct isotope ¹⁴⁶Sm, have revealed that the accessible part of the silicate Earth (e.g., upper mantle and crust) is more radiogenic in ¹⁴²Nd/¹⁴⁴Nd than that of chondritic meteorites. The positive ¹⁴²Nd anomaly of the Earth’s mantle implies that the Sm/Nd ratio of the mantle was fractionated early in Earth’s history and that the complementary low ¹⁴²Nd reservoir has remained isolated from the mantle since its formation. This has led to the suggestion that an early enriched reservoir, formed within Earth’s first hundred million years (the Hadean), resides permanently in the deep interior of the Earth. One hypothesis for a permanently isolated reservoir is that there may be an Fe-rich, and hence intrinsically dense, chemical boundary layer at the core-mantle boundary. The protoliths of this chemical boundary layer could have originated at upper mantle pressures during extreme fractional crystallization of a global magma ocean during the Hadean but testing this hypothesis is difficult because samples of this early enriched reservoir do not exist. This hypothesis, however, is potentially refutable. Here, we investigate a post-Archean magnetite-sulfide magma formed by extreme magmatic differentiation to test whether residual Fe-rich liquids of any kind have the necessary trace-element signatures to satisfy certain global geochemical imbalances. The magnetite-sulfide magma is found to have high Pb contents (and low U/Pb ratios), high Re/Os ratios, and anti-correlated Sm/Nd and Lu/Hf fractionations. Permanent segregation of such a magma would (1) provide a means of early Pb sequestration, resulting in the high U/Pb ratio of the bulk silicate Earth, (2) be a source of radiogenic ¹⁸⁷Os in the source regions of plumes, and (3) provide an explanation for decoupled Hf and Nd isotopic evolution in the early Archean, which is not easily produced by silicate fractionation. However, the magnetite-sulfide magma is not highly enriched in K, and thus, at face value, this magma analog would not serve as a repository for all of the heat producing elements. Nevertheless, other Fe-O-S liquids reported elsewhere are enriched in apatite, which carries high concentrations of K, U and Th. Given some promising geochemical fractionations of the Fe-rich liquids investigated here, the notion of a Hadean Fe-rich residual liquid deserves continued consideration from additional experimental or analog studies.     

Early Cretaceous (late Berriasian to early Aptian) palaeoceanographic change along the northwestern Tethyan margin (Vocontian Trough,southeastern France): δ13C, δ18O and Sr-isotope belemnite and whole-rock records

Stable carbon, oxygen, and strontium isotope records were obtained from uppermost Hauterivian to lowermost Aptian belemnite rostra, which were collected in well-dated sections from the Vocontian Trough (southeastern France). This data set complements previously published belemnite-isotope records from the uppermost Berriasian-Hauterivian interval from the same basin. The belemnite carbon and oxygen isotope record is compared to the carbonate bulk-rock isotope record from the same sections, and from additional Italian sections. With regards to their long-term trends, both belemnite and whole-rock δ¹⁸O records are well correlated, except for the uppermost Hauterivian-lower Barremian interval, within which they deviate. This discrepancy is interpreted to be linked to the latest Hauterivian Faraoni oceanic anoxic event and its early Barremian aftermath. The Faraoni level is characterized by enhanced sea-water stratification, probably induced by the onset of a warmer and more humid climate along the northern Tethyan margin. The early Barremian was characterized by stronger vertical sea-water mixing reflected by a decrease in density contrast between sea-surface and deeper waters. The belemnite oxygen isotope record shows a more stable evolution with smaller fluctuations than its bulk-rock counterpart, which indicates that deeper water masses were not as much subjected to density fluctuations as sea-surface water. The comparison of belemnite and bulk-rock carbon isotope records allows observing the impact of regional influence exerted by platform carbonate ooze shedding on the carbon cycle. Discrepancies in the two records are observed during time of photozoan carbonate platform growth. The strontium isotopic record shows a gradual increase from the uppermost Berriasian to the uppermost lower Barremian followed by a rapid decrease until the uppermost Barremian and a renewed small increase within the lowermost Aptian. The major inflection point in the uppermost lower Barremian appears to predate the onset in the formation of the Ontong-Java volcanic plateau.     

Smithian and Spathian (Early Triassic) ammonoid assemblages from terranes: Paleoceanographic and paleogeographic implications

Early Triassic paleobiogeography is characterised by the stable supercontinental assembly of Pangea. However, at that time, several terranes such as the South Kitakami Massif (SK), South Primorye (SP) and Chulitna (respectively, and presently located in Japan, eastern Russia and Alaska) straddled the vast oceans surrounding Pangea. By means of quantitative biogeographical methods including Cluster Analysis, Non-metric Multidimensional Scaling and Bootstrapped Spanning Network applied to Smithian and Spathian (Early Triassic) ammonoid assemblages; we analyze similarity relationships between faunas and suggest paleopositions for the above-cited terranes.Taxonomic similarities between faunas indicate that primary drivers of the ammonoid distribution were Sea Surface Temperature and currents. Possible connections due to current-controlled faunal exchanges between both sides of the Panthalassa are shown and terranes such as SK, SP and Chulitna played an important role as stepping stones in the dispersal of ammonoids. SK and SP terranes show strong sub-equatorial affinities during the Smithian, thus suggesting a location close to South China. At the same time, the Chulitna terrane shows strong affinities with equatorial faunas of the eastern Panthalassa. This paleoceanographic pattern was markedly altered during the Spathian, possibly indicating significant modifications of oceanic circulation at that time, as illustrated by the development of a marked intertropical faunal belt across Tethys and Panthalassa.     

Effect of anorthite on granite phase relations: Experimental data and models

New experimental data on the effect of anorthite (An) on liquidus phase equilibria in the system Qz–Ab–Or are presented. The data were obtained for 5 wt% An added to variable Qz/Ab/Or compositions at 300 MPa and under H₂O-saturated conditions. Crystal–liquid equilibria were determined for 13 synthetic glass compositions made from gels in experiments performed between 660 and 750 °C in cold-seal pressure vessels. Forward and reversal experiments were systematically conducted on each composition to demonstrate equilibrium. A total of 51 charges was examined. Three crystalline phases, quartz, alkali feldspar and plagioclase appear on the H₂O-saturated liquidus surface. The determined minimum liquidus 5 wt% An “piercing” point (39% Qz, 33% Ab, 28% Or) is shifted away from the Ab apex toward the Qz–Or sideline when compared with the An-free 300 MPa H₂O-saturated minimum. This shift is of the same type as that observed at 100 MPa in the same system and at 200 MPa in a rhyolitic system. The new experimental results are used to test both empirical and thermodynamic models for silicic magmas. Empirical models reproduce reasonably well the new experimental data, although more sophisticated calculations schemes appear to be required to improve their accuracy. The new experimental results in the haplogranodiorite system are not well reproduced with the model of Holland and Powell (2001), mainly because plagioclase stability appears greatly enhanced in the model. Rhyolite-MELTS satisfactorily reproduces the Qz-, Pl- and Af-liquid phase equilibria, but model H₂O solubilities are significantly lower and crystallization temperatures higher than in experiments.     

Recognition of disturbances with specified morphology in time series: Part 2. Spikes on 1-s magnetograms

Preliminary magnetograms contain different types of temporal anthropogenic disturbances: spikes, baseline jumps, drifts, etc. These disturbances should be identified and filtered out during the preprocessing of the preliminary records for the definitive data. As of now, at the geomagnetic observatories, such filtering is carried out manually. Most of the disturbances in the records sampled every second are spikes, which are much more abundant than those on the magnetograms sampled every minute. Another important feature of the 1-s magnetograms is the presence of a plenty of specific disturbances caused by short-period geomagnetic pulsations, which must be retained in the definitive records. Thus, creating an instrument for formalized and unified recognition of spikes on the preliminary 1-s magnetograms would largely solve the problem of labor-consuming manual preprocessing of the magnetic records. In the context of this idea, in the present paper, we focus on recognition of the spikes on the 1-s magnetograms as a key point of the problem. We describe here the new algorithm of pattern recognition, SPs, which is capable of automatically identifying the spikes on the 1-s magnetograms with a low probability of missed events and false alarms. The algorithm was verified on the real magnetic data recorded at the French observatory located on Easter Island in the Pacific.     

The physical conditions in the BHR71 outflows

Highly-collimated outflows are believed to be the earliest stage in outflow evolution, so their study is essential for understanding the processes driving outflows. The BHR71 Bok globule is known to harbour such a highly-collimated outflow, which is powered by a protostar belonging to a protobinary system. Using the APEX telescope on Chajnantor, we mapped the BHR71 highly-collimated outflow in CO(3-2), and observed several bright points of the outflow in the molecular transitions CO(4-3), CO(7-6), ¹³CO(3-2), C¹⁸O(3-2), CH₃OH(7-6) and H₂CO(4-3). We use an LVG code to characterise the temperature enhancements in these regions. These observations are particularly interesting for investigating the interaction of collimated outflows with the ambient molecular cloud. In our CO(3-2) map, the second outflow driven by IRS2, which is the second source of the binary system, is completely revealed and shown to be bipolar. We also measure temperature enhancements in the lobes. The CO and methanol LVG modelling points to temperatures between 30 and 50 K in the two lobes. The methanol emission in the southern lobe bright knot is barely resolved with the APEX single-dish. ALMA will thus be a central tool to study the shock chemistry in these regions.     

Pro‐glacial soil variability and geomorphic activity – the case of three Swiss valleys

Soils in pro‐glacial areas are often approached from a chronosequence viewpoint. In the chronosequence approach, the objective is to derive rates of soil formation from differences in properties between soils of different age. For this reason, in chronosequence studies, soils are sampled in locations that are assumed geomorphically stable and that have different age. As a result, these studies do not necessarily yield a complete view of soil variability in pro‐glacial areas, and may miss important relations between geomorphology and soil development. In this contribution, we present new soil observations from three closely related pro‐glacial areas in Switzerland. These observations were intended to get closer to a complete view of soil variability, and to assess impacts from factors other than time on soil development. About 40 soils were visited in each pro‐glacial valley in a combined design‐convenience sampling scheme and described in the field. Linear modelling was used to assess effects of time and topographic factors on soil properties. The time since glacial retreat turned out to rarely explain more than half of the variation in soil properties, and a linear model combining effects of time and topographic variables explained typically about half of the variation in each pro‐glacial valley. Models differed and were not transferable between valleys. Apparently, time and the present‐day shape of the landscape combined are insufficient information to accurately predict soil properties. Field evidence points to the importance of the geomorphic history and regime of the valleys as a reason for this. Copyright © 2014 John Wiley & Sons, Ltd.     

Modelling centennial sediment waves in an eroding landscape – catchment complexity

Sediment flux dynamics in fluvial systems have often been related to changes in external drivers of topography, climate or land cover. It is well known that these dynamics are non‐linear. Recently, model simulations of fluvial activity and landscape evolution have suggested that self‐organization in landscapes can also cause internal complexity in the sedimentary record. In this contribution one particular case of self‐organization is explored in the Sabinal field study area, Spain, where several dynamic zones of sedimentation and incision are observed along the current river bed. Whether these zones can be caused by internal complexity was tested with landscape evolution model (LEM) LAPSUS (Landscape Process Modelling at Multi‐dimensions and Scales). During various 500 year simulations, zones of sedimentation appear to move upstream and downstream in eroding river channels (‘waves’). These waves are visualized and characterized for a range of model settings under constant external forcing, and the self‐organizing process behind their occurrence is analysed. Results indicate that this process is not necessarily related to simplifications in the model and is more generic than the process of bed‐armouring that has recently been recognized as a cause for complexity in LEM simulations. We conclude that autogenic sediment waves are the result of the spatial propagation in time of feedbacks in local transport limited (deposition) and detachment limited (erosion) conditions. Copyright © 2014 John Wiley & Sons, Ltd.     

Protostellar Collapse Induced by Compression

We present numerical simulations of the evolution of low-mass, isothermal, molecular cores which are subjected to an increase in external pressure. If the external pressure increases very slowly, the core approaches instability quite quasi-statically. However, for faster compressions, a compression wave is driven into the core (Hennebelle, P., Whitworth, A., Gladwin, P. and André, P.: 2003a MNRAS 340, 870). Quantitative comparisons with observational velocity and density profiles are presented. The consequences of this compression for the fragmentation of the cloud is investigated and discussed.     

On the errors on Ω0: Monte Carlo simulations of the EMSS cluster sample

We perform Monte Carlo simulations of synthetic EMSS cluster samples, to quantify the systematic errors and the statistical uncertainties on the estimate of Ω₀ derived from fits to the cluster number density evolution and to the X-ray temperature distribution up to z =0.83 . We identify the scatter around the relation between cluster X-ray luminosity and temperature to be a source of systematic error, of the order of Δ_systΩ₀=0.09 , if not properly taken into account in the modelling. After correcting for this bias, our best Ω₀ is 0.66. The uncertainties on the shape and normalization of the power spectrum of matter fluctuations imply relatively large uncertainties on this estimate of Ω₀, of the order of Δ_statΩ₀=0.1 at the 1 σ level. On the other hand, the statistical uncertainties due to the finite size of the high-redshift sample are twice as small. Therefore, what is needed in order to improve the accuracy of Ω₀ estimates based on cluster number density evolution is a more reliable measure of the local temperature function and a better understanding of the cluster observed properties both in the local Universe and at high redshift, that is the relation between cluster mass, temperature and luminosity. This requires detailed observations of X-ray selected cluster samples, in comparison with hydrodynamic simulations including refined physics.