REDOX POTENTIAL MEASUREMENTS AS AN INDICATION OF BIOCHEMICAL WELL PLUGGING

Abstract. Hydrogeologic and geochemical investigations have recently been made at an existing municipal supply well in the Town of Pembroke, Massachusetts, to determine the feasibility of using the Vyredox Method (Hallberg and Martinell, 1976) to remove iron and manganese from the ground water. The unique Vyredox testing procedures confirmed the existence of an active iron and manganese precipitating bacteria colony in the productive zone of the aquifer, which was causing rapid plugging of the well.     

Advance of the late Wisconsin Cordilleran Ice Sheet in southern British Columbia since 22,000 Yr B.P.

Radiocarbon dates from critical stratigraphic localities in southern British Columbia indicate that the growth history of the late Wisconsin Cordilleran Ice Sheet was different from that of most of the Laurentide Ice Sheet to the east. Much of southern British Columbia remained free of ice until after about 19,000 to 20,000 yr ago; only adjacent to the Coast Mountains is there a record of lowland glacier tongues in the interval 22,000 to 20,000 yr B.P. A major advance to the climax of late Wisconsin Cordilleran glacier ice in the northern States was not begun until after about 18,000 yr B.P. in the southwest of British Columbia and after about 17,500 yr B.P. in the southeast. The rate of glacier growth must have been very rapid in the two to three millennia prior to the climax, which has been dated in western Washington at shortly after 15,000 yr B.P.     

Geochronology of Precambrian rocks in the Laramie Range and implications for the tectonic framework of Precambrian southern Wyoming

From Casper Mountain; at its northern end, to the northwestern margin of the Laramie anorthosite—syenite complex, in its central parts, the Laramie Range is underlain by granite and granitic gneiss that has a minimum age of 2.54 ± 0.04 Ga (Rb/Sr whole-rock isochron) and by metasedimentary rocks, including marble and quartzite, that appear to overlie the granitic gneiss nonconformably (minimum age: 1.7 Ga based on several horn-blende K/Ar dates). Southward from the anorthosite—syenite complex into Colorado, the Range is underlain chiefly by the Sherman Granite (1.41 Ga; Peterman and Hedge, 1968) and scattered patches of gneiss that are not dated, but are tentatively correlated wit similar gneiss in the southern Medicine Bow Mountains and in the Colorado Front Range, where they are dated as ? 1.7 Ga (Peterman and Hedge, 1968).The Laramie anorthosite—syenite complex (minimum age: ? 1.42 Ga or ? 1.51 Ga if a hornblende K/Ar date is accepted) apparently intruded the suture separating the old (? 2.5 Ga) continental edge from younger (? 1.7 Ga) geosynclinal rocks. The suture, which manifests itself as the Mullen Creek—Nash Fork shear zone in the Medicine Bow Mountains, also is the boundary between ensialic and ensimatic geosynclinal deposition that occurred during the interval 1.7–2.5 Ga ago.K/Ar dates on biotite and muscovite from rocks north of the anorthosite—syenite complex grade from 2.5 Ga on Casper Mountain down to 1.38 Ga near the complex. Near its northern tip, the Laramie Range is crossed by a geochronologic front, separating 2.5 Ga old gneiss whose K/Ar dates were not lowered by subsequent metamorphism from 2.5 Ga old gneiss whose mica dates were reset between 1.4 and 1.6 Ga ago.     

Age,provenance and tectonic setting of the Canastra and Ibiá Groups (Brasília Belt,Brazil): Implications for the age of a Neoproterozoic glacial event in central Brazil

The Brasília Belt is one of the best preserved Neoproterozoic orogens in Brazil. It comprises a thick Meso–Neoproterozoic sedimentary/metasedimentary pile including the Canastra and Ibiá Groups, which are the object of this study. The Canastra Group constitutes a regressive sedimentary sequence made mainly of greenschist-facies metapelitic and metapsammitic rocks, including phyllite, sandy metarhythmite and quartzite, with minor intercalations of limestone, as well as carbonaceous and carbonatic phyllite. The Ibiá Group is formed of a basal diamictite followed upwards by phyllites and calc-schists. It rests on an erosional unconformity on top of the Canastra Group.A provenance study based on U–Pb zircon geochronology on a selection of seven samples helped to establish the various source areas and maximum depositional ages of the original sediments. In addition, seven new Sm–Nd analyses are presented and discussed together with previously published data.LAM-ICP-MS U–Pb dating of detrital zircon grains indicates a maximum depositional age of the Canastra and Ibiá Groups of ca. 1030 and 640 Ma, respectively. The provenance signature of the Canastra Group comprises a wide range of detrital zircon ages with a significant Paleoproterozoic component (～1.8 and ～2.1 Ga) and an important Mesoproterozoic source (1.1–1.2 Ga), especially for the Paracatu Formation, indicating the São Francisco–Congo Craton as main source. These provenance data, in particular the absence of Neoproterozoic zircon grains, typical of the active margin of the Brasília Belt, allied with the homogeneous Paleoproterozoic T_DM values are consistent with the previous interpretation that the Canastra Group represents a sedimentary sequence deposited on a passive margin setting.Zircon grains from the diamictite of the Ibiá Group yielded ages ranging from 936 to 2500 Ma. In contrast, the overlying calc-phyllite of the Rio Verde Formation reveals a dominant Neoproterozoic provenance pattern with important peaks at 665, 740 and 850 Ma. The São Francisco-Congo Craton and Goiás Magmatic Arc are, most probably, the two main source regions for the Ibiá Group which may represent, therefore, a former fore- or back-arc sedimentary sequence. Tectonically, therefore, the Ibiá Group is equivalent to the Araxá Group exposed in central Goiás and both represent syn-orogenic sedimentary sequences formed with important detrital contributions derived from the Neoproterozoic Goiás Arc.The provenance data presented here indicate that the Cubatão Formation is most possibly representative of a Marinoan or younger glacial event.     

Distribution of Impact Locations and Velocities of Earth Meteorites on the Moon

Following the analytical work of Armstrong et al. (Icarus 160:183–196, 2002), we detail an expanded N-body calculation of the direct transfer of terrestrial material to the Moon during a giant impact. By simulating 1.4 million particles over a range of launch velocities and ejecta angles, we have derived a map of the impact velocities, impact angles, and probable impact sites on the moon over the last 4 billion years. The maps indicate that the impacts with the highest vertical impact speeds are concentrated on the leading edge, with lower velocity/higher-angle impacts more numerous on the Moon’s trailing edge. While this enhanced simulation indicates the estimated globally averaged direct transfer fraction reported in Armstrong et al. (Icarus 160:183–196, 2002) is overestimated by a factor of 3–6, local concentrations can reach or exceed the previously published estimate. The most favorable location for large quantities of low velocity terrestrial material is 50 W, 85 S, with 8.4 times more impacts per square kilometer than the lunar surface average. This translates to 300–500 kg km⁻², compared to 200 kg km⁻² from the previous estimate. The maps also indicate a significant amount of material impacting elsewhere in the polar regions, especially near the South Pole-Aiken basin, a likely target for sample return in the near future. The magnitudes of the impact speeds cluster near 3 km/s, but there is a bimodal distribution in impact angles, leading to 43% of impacts with very low (<1 km/s) vertical impact speeds. This, combined with the enhanced surface density of meteorites in specific regions, increases the likelihood of weakly shocked terrestrial material being identified and recovered on the Moon.     

Comparison between different kriging estimators

Six different geostatistical estimators (linear kriging, lognormal kriging, and disjunctive kriging, each with and without a nonbias, i.e., universality condition) were compared using data from a polymetallic deposit in Algeria. The differences between estimators with and without the nonbias condition were far more pronounced than between the different kriging methods. This highlights the importance of choosing an appropriate stationarity model for the data. The criterion concerning kriging weight of the mean in simple kriging, proposed by Remacre (1984, 1987) and Rivoirard (1984) was found to be helpful for determining blocks where the choice of the stationarity hypothesis was critical.     

Modelling rainfall/watertable relations using linear response functions

Linear system theory can be used to model and predict watertable responses to precipitation inputs in an artificially drained field. The response function is mathematically equivalent to the Unit Hydrograph concept familiar to hydrologists. This paper shows that it is possible to derive such response functions, and comments on the problems encountered in their derivation. Response functions for two contrasted sites are presented, and the possibilities for their use discussed.