Climatic and environmental characteristics of Moscow megalopolis according to the data of the Moscow State University Meteorological Observatory over 60 years

Analyzed are the results of meteorological and environmental measurements performed over the 60-year period (1954–2013) at the Meteorological Observatory of Lomonosov Moscow State University. The significant positive temperature trend (0.04°C/year for 1954–2013) was obtained; it increased up to 0.07°C/year in 1976–2012. Considered are the features of seasonal variations of different atmospheric characteristics. Discussed are the type and causes of low-frequency changes in meteorological parameters, radiation balance components, radiation in different spectral ranges, and chemical composition of precipitation. Demonstrated are possible mechanisms of the more significant increase observed in air temperature in Moscow as compared with that in Central Federal District and their connection with the greenhouse effect in the urban atmosphere.     

Changes in the Period of Negative Superhumps of Type SU UMa Dwarf Novae. II. NY Her (2017 and 2020)

Astrophysics - Photometric studies of the type SU UMa dwarf nova NY Her were made during 2017 and 2020 at the Crimean Astrophysical Observatory and at the Sanglokh Observatory over a total of 77...     

The impact of vertebrate herbivores on wetland vegetation in Atchafalaya Bay, Louisiana

Delta islands in the Atchafalaya and Wax Lake deltas in Atchafalaya Bay, Louisiana, are in an extremely dynamic successional phase. These islands initially supported large marshes dominated by the pioneering plant species Sagittaria latifolia and Sagittaria platyphylla. A general decrease in vegetated areas has occurred in the delta island marshes in the Atchafalaya Delta since about 1980, while in the Wax Lake Delta portion of the complex the vegetation still flourished. The Atchafalaya Delta provides an interesting setting for the study of herbivory because of the complex interaction of biotic and physical factors operating in this delta. We hypothesized that grazing by herbivores has a marked effect on vegetation in these developing marshes. To test this hypothesis, exclosures were erected on islands in both deltas in September 1985 and January 1986. Each set of exclosure treatments included an openly-grazed control area, an ungrazed area, an area allowing nutria grazing, and one allowing waterfowl grazing in each site. Results of the experiment, based on field sampling of vegetation, indicated decreases in plant biomass and changes in plant species composition in grazed treatments. Waterfowl and nutria reduced biomass aboul equally, but there was a more marked effect in the openly grazed areas. These findings may be extrapolated to sediment diversion areas along the Mississippi River.     

Analysis of decade-long time series of GPS-based polar motion estimates at 15-min temporal resolution

We present results from the generation of 10-year-long continuous time series of the Earth’s polar motion at 15-min temporal resolution using Global Positioning System ground data. From our results, we infer an overall noise level in our high-rate polar motion time series of 60 \(\upmu \hbox {as}\) (RMS). However, a spectral decomposition of our estimates indicates a noise floor of 4 \(\upmu \hbox {as}\) at periods shorter than 2 days, which enables recovery of diurnal and semidiurnal tidally induced polar motion. We deliberately place no constraints on retrograde diurnal polar motion despite its inherent ambiguity with long-period nutation. With this approach, we are able to resolve damped manifestations of the effects of the diurnal ocean tides on retrograde polar motion. As such, our approach is at least capable of discriminating between a historical background nutation model that excludes the effects of the diurnal ocean tides and modern models that include those effects. To assess the quality of our polar motion solution outside of the retrograde diurnal frequency band, we focus on its capability to recover tidally driven and non-tidal variations manifesting at the ultra-rapid (intra-daily) and rapid (characterized by periods ranging from 2 to 20 days) periods. We find that our best estimates of diurnal and semidiurnal tidally induced polar motion result from an approach that adopts, at the observation level, a reasonable background model of these effects. We also demonstrate that our high-rate polar motion estimates yield similar results to daily-resolved polar motion estimates, and therefore do not compromise the ability to resolve polar motion at periods of 2–20 days.     

The development and the projective methods of geodesy and their effect on large triangulation and trilateration networks

The projective methods of Helmert and Pizzetti enable the measured elements of a geodetic network to be reduced rigorously to the surface of a reference ellipsoid. However, in most existing triangulation networks, the routine development method has been used for this purpose. Some of the differences between the development and projective methods are investigated by interpreting the results of two numerical examples. It is concluded that use of the development method may cause appreciable discrepancies to occur within geodetic networks, depending primarily upon the extent of the networks, the orientation of the ellipsoid used, and the magnitude of the geoid undulations. Geophysical Studies Section Aeronautical Chart and Information Center     

Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.