Petrogenesis of ultramafic rocks and olivine-rich troctolites from the East Taiwan Ophiolite in the Lichi mélange

Mineralogy and Petrology - We examine ultramafic and olivine-rich troctolite blocks of the East Taiwan Ophiolite (ETO) in the Lichi Mélange. Although ultramafic rocks are extensively...     

Development of limiting soil slope profile under seismic condition using slip line theory

This study embraces the formation of the limiting geometry of finite slopes under the static and seismic conditions within the slip line theory framework coupled with the modified pseudo-dynamic approach. The proposed methodology is expected to achieve a global factor of safety of 1.0 for the obtained slope profile. While analysing the stability of slopes using the limit analysis or the limit equilibrium method, the cognition of the slope geometry and the nature of the slip surface need to be known in advance. Such limitations are ruled out in the present analysis with the aid of the slip line method. Further, by employing the modified pseudo-dynamic approach, the dynamic properties of soil, such as damping ratio and frequency effect, are effectively considered in this stability analysis. The consideration of the slip line theory permits to achieve an adaptive failure mechanism in the analysis. The impact of a set of parameters characterizing the input motion and the dynamic soil properties on the behaviour of a slope explains the relevance of the present modified pseudo-dynamic approach compared to the conventional pseudo-static and the original pseudo-dynamic approaches. The proposed solution serves as a measure of the seismic slope stability in accordance with the geomorphological process generally encountered in nature. Compared with the available literature, the present results propose safe, economical, and efficient design guidelines for finite slopes and intimate the need for preventive measures to enhance the stability of existing slopes.

     

Electron delocalization and magnetic behavior in a single crystal of ilvaite,a mixed valence iron silicate

Ilvaite, Ca(Fe²⁺, Fe³⁺)Fe²⁺Si₂O₈(OH), a black mixed valence iron silicate shows considerable Fe²⁺?Fe³⁺ electron delocalization above 400 K, reminiscent of magnetite. A crystallographic phase transition from orthorhombic (Pnam) to monoclinic (P2 ₁/a) symmetry takes place on cooling at 343 K induced by electron ordering. In both phases, Fe²⁺ and Fe³⁺ occur in double octahedral chains parallel to the c axis. The thermal characteristics of the magnetic susceptibilities and their anisotropies in different crystallographic planes have been measured in the temperature range 400?21 K. Below 343±1K, a continuous rotation of the molar susceptibility K _∥ in the ab plane down to 90±2 K is observed, where the symmetry of the magnetic ellipsoid remains unchanged. X _a, X _b and X _c increase abruptly below 123±0.5 K, although antiferromagnetic ordering of Fe²⁺ and Fe³⁺ spins on A sites was suggested in previous Mössbauer and neutron powder diffraction studies. In addition, 1/X _a shows an antiferromagnetic maximum at 50±3 K, whereas 1/X _b and 1/X _c at first increase sharply below 123 K, followed by antiferromagnetic curvatures in the lowest temperature region. This behavior is consistent with the antiferromagnetic ordering of Fe²⁺ spins in the B sites. The observed magnetic phenomena suggest charge delocatization effects between adjacent Fe²⁺(A)-Fe³⁺(A) pairs not only along c, but also along a and b directions. The negative sign of the molar anisotropy (K _∥-K_⊥) suggests a singlet ground State ⁵A₁ for the Fe²⁺ ions, in agreement with previous Mössbauer studies.     

Lateritisation of gabbro-granophyre rock units of the Ezhimala Complex of north Kerala, India

Laterites are ubiquitous in Kerala and are developed over different rock types. The laterite profiles developed over gabbro, granophyre of the Ezhimala Complex are discussed here.

The principal mineral assemblages of the laterites are kaolinite, gibbsite, goethite, hematite and quartz with minor amounts of zircon. Amorphous ferric hydroxide, Al-hydroxide and Al-silicate are also present. Samples from various units of the weathering profile have been analysed for major and trace elements. Major-element data show a steady depletion of Si and enrichment of sesquioxides and TiO₂ during weathering. It is also observed that the more the content of the mobile elements (Si, Mg, Ca, K, Na) in the parent rock, the greater is its depletion during lateritisation. The trace elements Co, Cr, V, Cu and Ni show an enrichment while Zn and Ba show depletion over both the rock types. Pb shows almost a consistent behaviour.     

A new method for estimating rate constants for trace gas reactions within stratospheric sulphuric acid aerosol droplets

Uptake of trace gases by (stratospheric aerosol can be significant particularly after large injections of volcanic sulphur. A theoretical scheme is presented to quantify the rate at which trace gases diffuse into these aerosol droplets. Rate constants for 19 trace gases are calculated and it is found that the rates vary from a value of 2.85 × 10^-7s^-1 for CC14 to 8.08 × 10^-7s^-1 for NO. The calculations are characterised by their ease of application and can be incorporated into stratospheric chemical models.     

Delineation of groundwater potential zone in Chhatna Block, Bankura District, West Bengal, India using remote sensing and GIS techniques

Groundwater is one of the most valuable natural resources, which is an immensely important and dependable source of water supply in all climatic regions over the world. Groundwater is in demand in areas where surface water supply is inadequate and nonsexist in the Chhatna Block, Bankura district and is located on the eastern slope of Chotonagpur Plateau, which is mapped on 73 I/15, 73 I/16 and 73 M/3, and falls between latitude 23°10′–23°30′N and longitude 86°47′–87°02′E. It represents plain land and gentle slope, which is responsible for infiltration and groundwater recharge. The groundwater in this region is confined within the fracture zones and weathered residuum. The present investigation is, therefore, undertaken to delineate potential zones for groundwater development with the help of a remote-sensing study. IRS–LISS-III data along with other data sets, e.g., existing toposheets and field observation data, have been utilized to extract information on the hydrogeomorphic features which include valley fills, buried pediment moderate, buried pediment shallow and structural hills, lineament density contour and slope map of this hard rock terrain. The target of this study is to delineate the groundwater potential zones in Chhatna block, Bankura District, West Bengal. Satellite imagery, along with other data sets, has been utilized to extract information on the groundwater controlling features of this study area. Three features (hydrogeomorphology, slope, and lineaments) that influence groundwater occurrences were analyzed and integrated. All the information layers have been integrated through GIS analysis and the groundwater potential zones have been delineated. The weighted index overlay method has been followed to delineate groundwater potential zones. The results indicate that good to excellent groundwater potential zones are available in almost the entire block. The results show that there is good agreement between the predicted groundwater potential map and the existing groundwater borehole databases. The area is characterized by hard rock terrain—still due to the presence of planation surface along valley fills; it became the prospective zone. The area has been categorized into four distinct zones: excellent, good, fair and poor. Excellent groundwater potential zones constitute 30–35 % of the total block area; good groundwater potential zones occupy a majority of the block, covering approximately 55–60 % and the fair potential zones occupy about 10–15 % of the total block. Poor potential zones occupy a very insignificant portion (less than 1 %).     

Prioritization of soil conservation measures using erodibility indices as criteria in Sikkim (India)

Erodibility indices are important parameter that can be used to describe the intensity of the soil erosion problems causing environmental concerns. These indices are convenient to estimate the susceptibility to erosion where physical measurement is very difficult. Sikkim is one such state in India where measuring erosion is a tedious process due to its difficult and inaccessible terrain conditions. In the present study, spatial variation of susceptibility of erosion in East district of Sikkim was estimated by using indices such as clay ratio, dispersion ratio, mod clay ratio and critical level of soil organic matter. The result indicates soils in East district are mostly dominated by sand particles (40.5–81.06%) in majority of soil samples. The dispersion ratio values in most of the soils were >15% indicating very high vulnerability to erosion. The values of clay ratio (3.44–9), modified clay ratio (mean value of 6.9) and critical level of soil organic matter content (<5%) indicated high susceptibility to erosion. The trends of indices were generated by IDW interpolation method to understand the spatial variation of the susceptibility to erosion. The interpolated maps were overlaid on subwatershed maps to prioritize the subwatershed for planning treatment measures.     

Seismic stability of two interconnected steel structures freely standing on the floor

Nuclear fuel fabrication and reprocessing facilities have glove boxes that are extensively used as a primary containment for radiological material. These equipment are maintained under negative pressure using ventilation system and possess high degree of leak tightness. Sometimes, they are used as a standalone structure and many a times, interconnected to each other. Normally, they are not anchored to the floor, which raises serious concerns about their seismic performance. To check seismic stability of the glove boxes and evaluate safety margins in design, tri directional fullscale shake table experiments of two interconnected glove boxes had been carried out. Two configurations were compared; in first, both the boxes were connected through flexible linkage (material transfer tunnel) and in second both were rigidly connected via structural members. Objective of experiments was to observe effects of seismic excitation on leak tightness, structural integrity and overall stability of two interconnected glove boxes. Subsequently, nonlinear finite element analysis was carried out to establish and develop analysis methodology. Experimental results were utilized for model benchmarking. Furthermore, a numerical method was developed to determine safe upper bounds on sliding displacements. This paper highlighted critical findings emanated from experimental results and examined their effect on seismic stability. Enhanced seismic stability in case of rigidly connected boxes was observed. Rigid body motions (mainly sliding and low magnitude rocking) dominated the response with very limited effect of elastic motions. Methodology used for modelling and analyzing glove boxes under seismic loading using finite element methods was also presented.