Biomarker distributions in asphaltenes and kerogens analysed by flash pyrolysis-gas chromatography-mass spectrometry

Biomarker distributions in a suite of asphaltenes and kerogens have been analysed by flash pyrolysis directly coupled to a GCMS system. Attention has been focussed on biomarkers of the sterane and triterpane types. The sample suite under investigation consists of sediments with different kerogen types and some crude oils. Biomarker distributions in the pyrolysates have been compared with the “free” biomarkers in the corresponding saturated hydrocarbon fractions.The analyses show significant differences between the distributions of the free biomarkers and those in the pyrolysates. The latter have lower amounts of steranes while diasteranes are absent or present at low concentrations only. In the triterpane traces a shift of maximum intensity from C₃₀ (free compounds) to C₂₇/C₂₉ is observed. Furthermore, the pyrolysates contain a set of triterpenes (not present among the free compounds), and there is a selective loss of “non-regular” triterpanes that are present in the saturated hydrocarbon fractions. The observed differences between pyrolysates and free hydrocarbons can be explained partly by the processes occurring during pyrolysis such as bond rupture and subsequent stabilisation of primary pyrolysis products. To a certain extent these differences also show that maturation processes occurring in sediments have effects on free biomarker molecules different from those on molecules that are enclosed in a macromolecular matrix (kerogen or asphaltenes).Differences between biomarker distributions of asphaltene and kerogen pyrolysates are relatively small. A comparison with the pyrolysates from extracted whole sediments suggests that these differences are mainly caused by interactions between the organic material and the mineral matrix during pyrolysis.Oil asphaltenes behave differently from sediment asphaltenes as their pyrolysates are more similar to the corresponding saturated hydrocarbon fractions, i.e. the differences described above are observed to a much smaller extent. This different behaviour appears to be the result of coprecipitation of a part of the maltene fraction with the oil asphaltenes.     

High latitude river runoff in a doubled CO2 climate

A global atmospheric model is used to calculate the monthly river flow for nine of the world's major high latitude rivers for the present climate and for a doubled CO₂ climate. The model has a horizontal resolution of 4° × 5°, but the model's runoff from each grid box is quartered and added to the appropriate river drainage basin on a 2° × 2.5° resolution. A routing scheme is used to move runoff from a grid box to its neighboring downstream grid box and ultimately to the mouth of the river. In a model simulation in which atmospheric carbon dioxide is doubled, mean annual precipitation and river flow increase for all of these rivers, increased outflow at the river mouths begins earlier in the spring, and the maximum outflow occurs approximately one month sooner due to an earlier snow melt season. In the doubled CO₂ climate, snow mass decreases for the Yukon and Mackenzie rivers in North America and for rivers in northwestern Asia, but snow mass increases for rivers in northeastern Asia.     

Seismically active fracture zones and distribution of thermal springs in Ecuador

Summary The analysis of the geometry of distribution of earthquake foci occurring in the continental South American plate above the subducted Nazca plate reveals that in the region of Ecuador these earthquakes accumulate in 8 well-separated fracture zones. These zones are interpreted as a system of deep seismically active fractures induced in the continental plate by the process of subduction. It is shown that the position of known thermal springs and of observed hydrothermal alterations in Ecuador correlates with the outcrops of the fracture zones.

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¶rt;aumuu an¶rt;u a mu muma num uu a¶rt; ¶rt;uu a¶rt; naa m mu mu anm 8 m¶rt; a a, m umnmua au uu amu a a muma um n ¶rt;uu. aam, m nmu um ma umuu uu¶rt;ma uu a¶rt; a¶rt;am ¶rt;a mu a .

     

Ice sheets and the CO2 problem

In this review, the carbon dioxide problem is discussed, with special reference to the possible effects of a global warming on the ice sheets of Greenland and Antarctica. Instead of detailed projections of future climate and the consequences, the basic mechanisms are explained and illustrated with results described in the literature.It is concluded that a doubling of the atmospheric CO₂ content (most likely to occur somewhere in the second half of the next century) will result in a globally-averaged warming of 2–4°C, and an intensification of the hydrological cycle. In the polar regions, this warming will be a few degrees larger and as a consequence the Greenland Ice Sheet will decrease in size. Antarctica, on the other hand, is expected to grow because of the increased snowfall. The instability of the West Antarctic Ice Sheet is also discussed and, although no conclusive prediction to its long-term response can be made, it is argued that on a short time scale (less than about 100 y) nothing dramatically wil happen to this part of Antarctica.     

Deep seismically active fracture zones in ecuador and northern peru

Summary A system of 8 seismically active fracture zones was delineated on the basis of the distribution of earthquake foci in the continental lithosphere of Ecuador. The position and width of the outcrop, thickness, dip and maximum depth of the individual fracture zones were estimated and correlated with surface geological and tectonic phenomena, volcanism and hydrothermal manifestations. The existence and strike of the fracture zones was independently confirmed by the occurrence of historical disastrous earthquakes.

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uma 8 uu amu a a aa a auu an¶rt;u a mu muma um a¶rt;a. u n¶rt; nu u uua a nmu, mua, u auaaua m¶rt; a . mau mu auu n¶rt;m¶rt;am a¶rt;u umuu aum mu u nmau nmu, mmu, au uu¶rt;mau nuu.

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Visiting professors at Instituto Geofísico and Facultad de Geología, Minas y Petróleos, Escuela Politécnica Nacional, Quito (Ecuador).     

Geochemical studies in the drainage basin of the Rio Vouga,Portugal. IV. Impact of land use on the hydrogeochemistry of natural waters in the Vouzela region

A hydrogeochemical study of the impact of land use on the composition of natural waters in the Vouzela region in northern Portugal was carried out during the summer of 1983. Water samples were collected from spring and major streams in the area and analyzed for major constituents and some trace elements. Analysis of variance and subsequent pairwise contrast tests demonstrated that waters from agricultural areas are significantly enriched in constiluents such as Na, K, Ca, Mg, Sr, Cl, SO₄, and NO₃. High concentrations of these ions in agricultural areas are the result of both the application of fertilizers and enhanced evaporation by the intensive irrigation of agricultural lands. Constitutents such as H₄SiO₄, HCO₃, F, and probably Li, which are typically related to mineral weathering, were not affected by land use. In waters from forested areas the concentration of most constituents was about 20% higher than in waters from uncultivated areas with mainly a grass cover. This reflects the difference in the evapotranspiration of these two vegetation types. The chemistry of the Rio Zela clearly reflects differences in land use in the Rio Zela valley.     

Calculation of space-time correlations

When treating relative diffusion as a statistical problem, mixed space-time correlations are encountered. In order to make practical calculations possible, two methods are proposed to express a space-time correlation as a function of a space correlation and a time correlation.     

Field observations of stratified atmospheric flow above an obstacle

In a study using the plume from the Four Corners power plant, near Farmington, N.M., lee waves were observed during times when the plume flowed across the Hogback. Wavelengths were typically about 1.2 km; wave amplitudes were more variable, ranging from 20 to 100 m. The observed amplitudes imply an obstacle that is broader and shallower than is actually the case. This is in agreement with laboratory studies that show the existence of regions of complex flow both upstream and downstream from an obstacle, which have the effect of broadening the region over which laminar flow occurs. Visual observation, measurement of the plume cross-sectional area both upstream and downstream from the Hogback, and measurement of plume aerosol concentrations show that turbulent and eddy flow over and downwind from the Hogback increase the rate of mixing of the plume with the surrounding atmosphere. This in turn increases the rate at which plume components come into contact with the ground.     

The southern cape conductive belt (South Africa): Its composition, origin and tectonic significance

Magnetometer array studies have led to the discovery and mapping of the Southern Cape Conductive Belt (SCCB) crossing the southern tip of Africa from west to southeast coasts. The SCCB lies just south of the Namaqua-Natal Belt of cratonic rocks remobilized about 1000 m.y. B.P. It is shown that it coincides with a zone of weakness which has been exploited by three major geosynclinal accumulations over some 600 m.y. Relationships between the SCCB and the basement geochronology, geology and tectonics are considered in detail. These relationships support the view that the conductive belt was formed by an accumulation of marine sediments and oceanic lithosphere at the top of a Proterozoic subduction which stopped about 1000 to 800 m.y. B.P. Associated with this subduction we propose a Proterozoic range of Andean mountains, whose roots are now exposed in the Namaqua-Natal Belt. Later subduction further south, near the present south coast, is proposed to account for the intrusion, between the south coast and the SCCB, of the Cape Granites in the time interval 600-500 m.y. B.P. There is some evidence for a third, yet more distant, subduction episode off Permian Gondwanaland. After outlining this tectonic history, the paper turns to a closer examination of the hypothesis that the Southern Cape Conductive Belt consists of partly serpentinized basalt accumulated at the top of a Proterozoic subduction. A large static magnetic anomaly, which correlates with the SCCB over most of its length, is well fitted by a model which strongly supports this hypothesis. Bouguer gravity anomalies along western and central profiles likewise support the hypothesis. A discussion follows of the process of formation of the proposed block of serpentinized marine rocks, beginning with serpentinization of the crust near oceanic ridges by reaction of warm, porous, newly-extruded basalt with seawater convecting through it. The serpentinized basalt is stable at crustal temperatures and pressures and so is transported in the seafloor until it reaches a subduction, where it accumulates because of its low density. Examples of such accumulations are cited. Finally, it is shown that any iron in the olivine and pyroxene in the original basalt precipitates, when these silicates are hydrated to serpentine, as magnetite which is the dominant mineral conferring high electrical conductivity and high magnetic susceptibility on serpentinites. In particular the Beattie static magnetic anomaly requires, in our model calculation, a very high susceptibility readily attainable in basalt at 15–20% serpentinization. The authors know of no other rock able to provide this high susceptibility. A similar percentage of serpentinization provides the density required to model the gravity anomalies.     

Nitrogen isotopes in the solar system

Measurements of the isotopic composition of nitrogen in the solar system are summarized. We show that the 30% change, during the last 3 to 4 billion years, of ${}^{15}\text{N}{}^{14}\text{N}$ in solar-wind-bearing lunar soils and breccias probably does not reflect changes in this ratio at the solar surface. Such changes, whether by spallation or thermonuclear reactions are ruled out by comparing the yields of ¹⁵N with those of other rare isotopes such as ⁹Be, ¹¹B, ³He or ¹³C, even if an arbitrary degree of solar mixing is introduced. Moreover, we calculate that the solar activity required for producing significant amounts of ¹⁵N by spallation at the solar surface should have resulted in a particle bombardment of the Moon of an intensity that would have produced amounts of spallation isotopes (e.g.¹⁵N, ²¹Ne, ³⁸Ar, ¹³¹Xe) several orders of magnitude in excess of what is actually found in the whole regolith.We argue that accretion of interstellar matter also does not work as a cause for a significant change of the photospheric ${}^{15}\text{N}{}^{14}\text{N}$ ratio. Evidence is presented that the mixing depth at the solar surface on a time scale of ?10⁹ years is (10^?2 ?10^?1) M_⊙ Mixing to this depth renders accretion of interstellar matter as a source of compositional changes at the solar surface inefficient, even if allowance is made for the expected large difference in the accretion rates of condensed and gaseous matter. A quantitative treatment of several alternatives of solar accretion leads to serious contradictions (e.g. with the low Ne abundances in planetary atmospheres or with the amounts of nitrogen that should have been directly accreted by the Moon), and we conclude that accretion during the main sequence life of the Sun is an unlikely source of changes in ${}^{15}\text{N}{}^{14}\text{N}$ at the solar surface.A ratio of ${}^{15}\text{N}{}^{14}\text{N}\text{= (4.0 ± 0.3) × 10}{}^{\mathrm{?3}}$ is our best estimate for average solar system material and for the Sun. We propose that a rare, very light nitrogen component (called LPN) is admixed in varying amounts to planetary matter. Undiluted LPN has not been found in meteorites or planetary atmospheres, but we show that the combined effects of LPN admixture and isotope fractionation can in principle account for the variability of ${}^{15}\text{N}{}^{14}\text{N}$ observed in the planetary system. Determination of the Jovian ${}^{15}\text{N}{}^{14}\text{N}$ ratio with an accuracy of ~10% would crucially test our interpretation of the nitrogen isotope observations.