Limestone Provenance in Roman Lime‐Volcanic Ash Mortars from the Villa dei Quintili,Rome

Roman mortars were collected from the Villa dei Quintili in Rome, an archaeological site consisting of numerous edifices from nine construction phases dating from the 2nd century A.D. to modern times. A multianalytical approach was used on 34 mortar samples to infer the evolution of production techniques over time and to identify the source area of calcareous raw materials used in the preparation of the lime. Optical microscopy, scanning electron microscopy coupled with an energy‐dispersive system, and laser ablation inductively coupled plasma mass spectrometry were used to study the samples. The major and trace element data were compared with the compositions of two types of limestone samples (Calcare Massiccio and Calcare Maiolica) collected from the Cornicolani Mountains. The results suggest that the technological practices and the calcareous raw materials used for lime production remained unchanged over the time period considered (2nd century A.D. to 3rd century A.D.). The compositions of lime‐related particles in the mortars match those of Calcare Maiolica, which suggests its use as raw material for lime production. On the whole, the results are in agreement with data from existing literature regarding both the use by Roman builders of specific raw materials for the mortars’ production and the relative supply area.     

Application of protective products to “Noto” calcarenite (south-eastern Sicily): a case study for the conservation of stone materials

Noto is an important Baroque urban center in south-eastern Sicily, which was completely reconstructed after the severe earthquake of 1693. Most of its monuments and historic buildings were built in Pietra di Noto stone, a pale cream calcarenite, quarried in outcrops located near the city. This stone, still currently used as building material, is undergoing many forms of alteration and degradation, which cause significant damage to monuments. In this study, three commercial protective products were tested on some Noto calcarenite samples from quarries, with the aim of assessing their protective effectiveness. In particular, petrographic analyses by optical microscopy were carried out for textural characterization of the stone materials. Capillary water absorption, porosimetric and colorimetric procedures, UV radiation and salt crystallization aging tests were performed to better evaluate interactions between protective products and substrate.     

Two refractory Wild 2 terminal particles from a carrot‐shaped track characterized combining MIR/FIR/Raman microspectroscopy and FE‐SEM/EDS analyses

We present the analyses results of two bulk Terminal Particles, C2112,7,171,0,0 and C2112,9,171,0,0, derived from the Jupiter‐family comet 81P/Wild 2 returned by the Stardust mission. Each particle embedded in a slab of silica aerogel was pressed in a diamond cell. This preparation, as expected, made it difficult to identify the minerals and organic materials present in these particles. This problem was overcome using a combination of three different analytical techniques, viz. FE‐SEM/EDS, IR, and Raman microspectroscopy that allowed identifying the minerals and small amounts of amorphous carbon present in both particles. TP2 and TP3 were dominated by Ca‐free and low‐Ca, Mg‐rich, Mg,Fe‐olivine. The presence of melilite in both particles is supported by IR microspectroscopy, but is not confirmed by Raman microspectroscopy, possibly because the amounts are too small to be detected. TP2 and TP3 show similar silicate mineral compositions, but Ni‐free and low‐Ni, subsulfur (Fe,Ni)S grains are present in TP2 only. TP2 contains indigenous amorphous carbon hot spots; no indigenous carbon was identified in TP3. These nonchondritic particles probably originated in a differentiated body. This work found an unanticipated carbon contamination following the FE‐SEM/EDS analyses. It is suggested that organic materials in the embedding silica aerogel are irradiated during FE‐SEM/EDS analyses creating a carbon gas that develops a strong fluorescence continuum. The combination of the selected analytical techniques can be used to characterize bulk Wild 2 particles without the need of extraction and removal of the encapsulating aerogel. This approach offers a relatively fast sample preparation procedure, but compressing the samples can cause spurious artifacts, viz. silica contamination. Because of the combination of techniques, we account for these artifacts.     

High Energy Astrophysics with INTEGRAL

INTEGRAL is an ESA mission scheduled to be launched in 2001. Its fourcoaligned instruments will allow observations of cosmic sources from afraction of a keV to several MeV plus source monitoring in the opticalband. INTEGRAL will be operated as a space observatory and an Announcementof Opportunity to the astronomical community at large will be issued byESA in the spring of the year 2000. Purpose of this paper is to illustrateINTEGRAL capabilities of the three X and Gamma Ray detectors plus opticalmonitor in order to help potential users to write observing proposals.     

On the time dependence of differential rotation in young late-type stars

A model for the angular momentum transfer within the convection zone of a rapidly rotating star is introduced and applied to the analysis of recent observations of temporal fluctuations of the differential rotation on the young late-type stars AB Doradus (AB Dor) and LQ Hydrae (LQ Hya). Under the hypothesis that the mean magnetic field produced by the stellar dynamo rules the angular momentum exchanges and that the angular velocity depends only on the distance s from the rotation axis and the time, the minimum azimuthal Maxwell stress  | B_sB _φ|  , averaged over the convection zone, is found to range from ∼0.04 to  ∼0.14 T²  . If the poloidal mean magnetic field   B _s   is of the order of 0.01 T, as indicated by the Zeeman–Doppler imaging maps of those stars, then the azimuthal mean field   B _φ  can reach an intensity of several teslas, which significantly exceeds equipartition with the turbulent kinetic energy. Such strong fields can account also for the orbital period modulation observed in cataclysmic variables and RS Canum Venaticorum systems with a main-sequence secondary component. Moreover, the model allows us to compute the kinetic energy dissipation rate during the maintenance of the differential rotation. Only in the case of the largest surface shear observed on LQ Hya may the dissipated power exceed the stellar luminosity, but the lack of a sufficient statistic on the occurrence of such episodes of large shear does not allow us to estimate their impact on the energy budget of the convection zone.     

Thermodynamic modeling assisted by multivariate statistical image analysis as a tool for unraveling metamorphic P-T-d evolution: an example from ilmenite-garnet-bearing metapelite of the Peloritani Mountains, Southern Italy

An ilmenite-garnet-bearing schist from the medium-grade metapelite complex of the Mandanici Unit in the Peloritani Mountains has been investigated to constrain the P-T conditions attained in this sector of the southern European Hercynian chain. Microprobe investigations assisted by statistical handling of X-ray maps via principal component analysis allowed us to better elucidate the porphyroblast-matrix relationships, the geometry of the elemental distribution in garnet porphyroblasts and the average volume percentage of the reactant garnet during retrograde metamorphic evolution. Selected microprobe data were then used to constrain, by means of P-T pseudosections, the main P-T stages of the metamorphic evolution, using the XRF bulk-rock chemistry as the equilibrium chemical composition for the prograde and peak stages and an effective bulk-rock composition for the retrograde one. Peak metamorphic P-T estimates (~530?°C; 0.9?GPa) are consistent with a Hercynian crustal thickening stage at middle-lower crustal conditions, while subsequent evolution, constrained at 420–460?°C; 0.30–0.60?GPa, depicts a retrograde clockwise P-T trajectory linked to exhumation under likely extensional shearing conditions. The results obtained in this paper lead to envisage a new scenario for the crustal evolution of the Peloritani Mountains and stimulate a revision of previous interpretations in the light of the new investigation techniques.     

Location Performance and Detection Magnitude Threshold of the Romanian National Seismic Network

Romania is an earthquake prone area with a few destructive earthquakes per century. The National Institute for Earth Physics carries out the seismic survey of Romania through the Romanian National Seismic Network (RNSN) consisting of 65 real-time seismic stations. Daily reports and monthly bulletins are delivered after routinely analyzing and processing the recorded data. In the present paper we applied the Seismic Network Evaluation through Simulation method for the RNSN configuration as it was in August 2011 to estimate the background noise level, assess the appropriateness of the velocity model adopted in routine location procedure, evaluate the hypocenter location uncertainty and determine the detection magnitude threshold. Areas of greater (southern Romania) and lower (Carpathians and Apuseni Mountains) background noise within the RNSN are identified by mapping the average power of noise in 1–12?Hz frequency range. The statistical study of the P and S phases residual times allow us to assess the appropriateness of the velocity model used in routine location. Both P- and S-wave velocity models can be optimized to improve the quality of the hypocenter location. As shown by our analysis, the RNSN is able to detect and locate earthquakes with M _L magnitude above 2.5 anywhere on the Romanian territory, except the border areas, such as the Crisana–Maramures seismic source zone. Merging data from both sides of the border significantly improves the quality of hypocenter location in these areas.     

Combined statistical and petrological analysis of provenance and diagenetic history of mudrocks: Application to Alpine Tethydes shales (Sicily,Italy)

Mineralogical (X-ray diffraction) and geochemical (X-ray fluorescence) compositional data of Alpine Tethyde mudrocks from Sicily were used to unravel the interplay of provenance and diagenesis by means of multivariate statistical methods (PCA, discriminant function analysis) designed for non-negative constant-sum data. The Sicilian Alpine Tethydes comprise Cretaceous–Eocene scaly shales (Mt. Soro and Upper Scagliose Shales Units), Eocene–Oligocene variegated shales (Troina and Nicosia Units), and Miocene Numidian shales (Nicosia Unit). The use of biplots of clr-transformed variables allows discrimination of two different groups of shales. High CIA values reveal a strongly weathered source area especially for the Numidian shales. The analyses of mixed-layered clay minerals indicate that the behaviour of K2O and geochemical affine elements is controlled by the diagenetic grade, which increases from south-west to north-east in response to tectonic loading. Ratios of selected elements (Zr, Y, La, Nb, Ti, Co, Cr, Ni), considered essentially unchanged with respect to the source rocks, are similar in the scaly and variegated shales, and resemble the Variscan Peloritani metamorphic basement. In contrast, the distinct geochemical signature of the Numidian shales reveals a source similar to the average cratonic sandstone, suggesting derivation from external sources located in the foreland. Multivariate discriminant analysis performed on selected trace elements confirms the previous suggestions.     

An automated station for the detection of bursts of cosmic origin at VHF and UHF

An automated system for the detection of bursts of cosmic origin at radio frequencies has been built at Medicina (Bologna). The station, completely independent, is part of a network of observatories based in Ireland, United Kingdom, Switzerland and Italy. The receiving apparatus, operating at 151 and 408 MHz, and the experimental method used to reject unwanted events is described. Observational programmes include a search for the radio counterpart of X-and -ray bursts, observations of the galactic centre and Cygnus regions, and a full sky monitoring. Sensitivity limits as well as preliminary results are discussed.