Petrology of titanian clinohumite and olivine at the high-pressure breakdown of antigorite serpentinite to chlorite harzburgite (Almirez Massif,S. Spain)

Rocks of the Cerro del Almirez ultramafic massif (Sierra Nevada, Betic Cordillera, S. Spain) record the high-pressure dehydration of antigorite–olivine serpentinite to form chlorite harzburgite (ol + opx + chl). In the field, these two rock types are separated by a well-defined isograd. Titanian clinohumite (TiCl) and olivine show textural and compositional differences depending on the rock type. OH–TiCl occurs in the serpentinite as disseminated grains and in veins. F–OH–TiCl is observed exclusively in the chlorite harzburgite, where it occurs as porphyroblastic grains and within prograde olivine as irregular and lamellar, planar intergrowths at microscopic and submicroscopic scales. Petrological evidence of partial to complete breakdown of TiCl to olivine + ilmenite is preserved in both rock types. Chlorite harzburgite is characterized by a brown pleochroic olivine with abundantally oriented microscopic to submicroscopic oxide particles. The mean Ti-content of the brown olivine is 144 ppm. The brown olivine preserves TiCl lamellae that sometimes grade into ghost lamellae outlined by the oxide trails. This observation suggests that some of the oxide inclusions in the brown olivine are derived from the breakdown of TiCl intergrowths. Thermodynamic modelling of selected Almirez bulk rock compositions indicates a temperature increase from 635°C to 695°C, at pressures ranging from 1.7 GPa to 2.0 GPa, as the cause for the compositional adjustment of TiCl between the Almirez antigorite serpentinite and chlorite harzburgite. These P–T estimates are in good agreement with the sequence of phase relations observed in the field. The computed phase diagrams in conjunction with the geothermal conditions envisaged for different subduction settings indicate that TiCl is stable in the vicinity of the antigorite serpentinite/chlorite harzburgite phase boundary in some subduction settings. In these circumstances, clinohumite–olivine intergrowths in chlorite harzburgite may act as a sink for high field strength elements, and probably other elements, that are present in the mantle–wedge fluids.     

Atmospheric estimates of power-law exponents Μ and Μθ

Measurements in the atmospheric surface layer of sixth-order velocity structure functions and of sixth-order mixed velocity-temperature structure functions support values of and previously obtained in the laboratory at moderate turbulence Reynolds numbers.     

Reynolds number dependence of high-order moments of the streamwise turbulent velocity derivative

Moments, up to order six, of the velocity derivative have been measured in both the atmospheric surface layer and in turbulent jet flows in the laboratory. The exponent which characterises the behaviour of dissipation fluctuations was determined from the autocorrelation of these fluctuations and found to be constant (0.20), independent of Reynolds number. Using this value of , the lognormal model satisfactorily represents the experimental variation with Reynolds number of the measured moments. When moments of ordern are plotted against those of ordern + 1, the scatter in the data is reduced considerably and the adequacy of the lognormal model vis-à-vis other models is more convincingly established.     

Functional attributes of epilithic diatoms for palaeoenvironmental interpretations in South-West Greenland lakes

Benthic diatoms are commonly used for palaeoenvironmental reconstruction in Arctic regions, but interpretation of their ecology remains challenging. We studied epilithic diatom assemblages from the shallow margins of 19 lakes from three areas (coast-inland-ice sheet margin) along a climate gradient in Kangerlussuaq, West Greenland during two periods; shortly after ice-off (spring) and in the middle of the growth season (summer). We aimed to understand the distribution of Arctic epilithic diatoms in relation to water chemistry gradients during the two seasons, to investigate their incorporation into lake sediments and to assess their applicability as palaeoenvironmental indicators. Diatoms were correlated with nutrients in the spring and alkalinity/major ions in the summer, when nutrients were depleted; approximately half of the variance explained was independent of spatial factors. When categorised by functional attributes, diatom seasonal succession differed among regions with the most obvious changes in inland lakes where summer temperatures are warmer, organic nutrient processing is prevalent and silicate is limiting. These conditions led to small, motile and adnate diatoms being abundant in inland lakes during the summer (Nitzschia spp., Encyonopsis microcephala), as these functional attributes are suited to living within complex mats of non-siliceous microbial biofilms. Seasonal succession in silica-rich lakes at the coast was less pronounced and assemblages included Tabellaria flocculosa (indicating more acidic conditions) and Hannaea arcus (indicating input from inflowing rivers). The nitrogen-fixing diatom Epithemia sorex increased from the coast to the ice sheet, negatively correlating with a gradient of reactive nitrogen. The presence of this diatom in Holocene sediment records alongside cyanobacterial carotenoids during arid periods of low nitrogen delivery, suggests that it is a useful indicator of nitrogen limitation. Nitzschia species appear to be associated with high concentrations of organic carbon and heterotrophy, but their poor representation in West Greenland lake sediments due to taphonomic processes limits their palaeoenvironmental application in this region. Proportions of epilithic taxa in lake sediment records of coastal lakes increased during some wetter periods of the Holocene, suggesting that snowpack-derived nutrient delivery may offer diatom taxa living at lake margins a competitive advantage over planktonic diatoms during the “moating” ice melt period. Thus, further research investigating linkages between epilithic diatoms, snowpack and nutrient delivery in seasonally frozen lakes is recommended as these taxa live on the ‘front-line’ during the spring and may be especially sensitive to changes in snowmelt conditions.     

Geochemistry of Cretaceous Magmatism in Eastern Cuba: Recycling of North American Continental Sediments and Implications for Subduction Polarity in the Greater Antilles Paleo-arc

We present whole-rock major- and trace-element and Nd–Sr–Pbradiogenic isotope data for Cretaceous igneous suites from easternCuba. These rocks are related to the Greater Antilles paleo-islandarc magmatism and have three different igneous styles. Group1 consists of tholeiitic basalts and rare basaltic andesitesthat have normal mid-ocean ridge basalt (N-MORB)-like compositionssimilar to those found in back-arc basin basalts (TiO₂ = 1·2–2·9wt%; La/Yb_(N) = 0·7–0·9, Th/Nb = 0·06–0·08,and initial ²⁰⁸Pb/ ²⁰⁴Pb = 37·65–37·74).Group 2 comprises basaltic and rare basaltic andesitic subvolcanicdykes with major- and trace-element and isotopic compositionssimilar to those of island arc tholeiites (TiO₂ = 0·7–1·4wt%; La/Yb_(N) = 0·6–0·9, Th/Nb = 0·06–0·68,and initial ²⁰⁸Pb/ ²⁰⁴Pb = 37·74–38·25).Group 3 is composed of low-Ti (TiO₂ = 0·3–0·9wt%) calcalkaline igneous rocks that have an unambiguous subduction-relatedcharacter (La/Yb_(N) = 1·1–5·0, Th/Nb = 0·35–1·55,and initial ²⁰⁸Pb/ ²⁰⁴Pb = 37·94–38·39).The parental magmas of the three groups formed by variable meltingdegrees (< 5–25%) of spinel lherzolite, with more depletedmantle sources for Groups 2 and 3 than Group 1. The trace-elementand radiogenic isotope compositions of primitive Group 3 samplesare strongly bimodal. One subgroup of samples is characterizedby low Ta/Yb (0·02–0·03) and Th/La (0·10–0·13),slightly subchondritic Nb/Ta (13·3–17·3),and relatively high initial ²⁰⁶Pb/²⁰⁴Pb (18·57–18·62)and _Nd (7·6–9·4). The remaining primitiveGroup 3 samples have higher Ta/Yb (0·06–0·11)and Th/La (0·24–0·32), and highly subchondriticNb/Ta (7·6–9·1), coupled with lower initial²⁰⁶Pb/²⁰⁴Pb (18·24–18·29) and _Nd (3·4–5·5).These signatures were induced by two distinct slab componentsthat mainly reflect the contributions of Cretaceous Atlanticmarine and North American continental sediments, respectively.Nb/Ta in the first subgroup was influenced by melting of rutile-bearingsubducted crust, whereas in the second it was inherited fromrecycled continental sediments. The involvement of Atlanticand North American sediments in Cuban Cretaceous magmatism indicatesthat the Proto-Caribbean (North American-Proto Atlantic) lithospheresubducted beneath the Greater Antilles arc during the Late Cretaceous(pre-Campanian), consistent with geotectonic models involvingonset of SW-dipping subduction beneath the Greater Antillespaleo-arc during the Aptian. The variable mantle source depletionand magnitude of the subduction component probably reflect differentsettings across the arc, from the arc front to a back-arc spreadingridge. KEY WORDS: eastern Cuba; Greater Antilles paleo-island arc; mantle source depletion; Nb/Ta fractionation; slab component     

Relationship between geoacoustic properties and chemical content of submarine polymetallic crusts from offshore Brazil

Abstract

Marine mining is the ocean’s new exploration frontier, and polymetallic crusts (PMCs) and ferromanganese nodules are considered a strategic resource for the future. Acoustic geophysical methods are a valuable tool for oceanic research and have been employed for several decades in the exploration of marine resources and environmental evaluations. The main objective of this work was to investigate the correlation between the chemical composition of PMCs from three different areas along the Brazilian continental margin and their physico-acoustic attributes (P-wave velocity, density and acoustic impedance). The results show that the geoacoustic properties of PMCs are correlated to their chemical composition. Measurements showed positive and negative trends between acoustic impedance and studied elements (Fe, Mn, Co, Cu, Zn, W and Ni) according to the direction of measurement, indicting high anisotropy levels. Our study sheds initial light on the correlation between acoustic properties and metal content of PMCs. The study facilitates assessments of the acoustic responses of PMCs allowing more efficient prospection and exploitation compared to ship-board geophysical techniques that are too qualitative to identify PMCs. The results can contribute to determining the best procedures and techniques for more efficient future exploration of this resource.     

Impact of the Diurnal Cycle of the Atmospheric Boundary Layer on Wind-Turbine Wakes: A Numerical Modelling Study

The wake characteristics of a wind turbine for different regimes occurring throughout the diurnal cycle are investigated systematically by means of large-eddy simulation. Idealized diurnal cycle simulations of the atmospheric boundary layer are performed with the geophysical flow solver EULAG over both homogeneous and heterogeneous terrain. Under homogeneous conditions, the diurnal cycle significantly affects the low-level wind shear and atmospheric turbulence. A strong vertical wind shear and veering with height occur in the nocturnal stable boundary layer and in the morning boundary layer, whereas atmospheric turbulence is much larger in the convective boundary layer and in the evening boundary layer. The increased shear under heterogeneous conditions changes these wind characteristics, counteracting the formation of the night-time Ekman spiral. The convective, stable, evening, and morning regimes of the atmospheric boundary layer over a homogeneous surface as well as the convective and stable regimes over a heterogeneous surface are used to study the flow in a wind-turbine wake. Synchronized turbulent inflow data from the idealized atmospheric boundary-layer simulations with periodic horizontal boundary conditions are applied to the wind-turbine simulations with open streamwise boundary conditions. The resulting wake is strongly influenced by the stability of the atmosphere. In both cases, the flow in the wake recovers more rapidly under convective conditions during the day than under stable conditions at night. The simulated wakes produced for the night-time situation completely differ between heterogeneous and homogeneous surface conditions. The wake characteristics of the transitional periods are influenced by the flow regime prior to the transition. Furthermore, there are different wake deflections over the height of the rotor, which reflect the incoming wind direction.     

On the correlation between turbulent velocity and temperature derivatives in the atmospheric surface layer

Velocity and temperature derivatives were obtained at a height of 4 m in the atmospheric surface layer above land. With the assumption of local isotropy, these measurements are used to obtain some statistics of the turbulent energy and scalar dissipation fields. These statistics include the variances of the logarithms of the scalar and velocity dissipation fields and the correlation between these logarithms. When used in conjunction with the hypotheses for fluctuations in turbulent dissipation rates of Obukhov and Kolmogorov, the statistics suggest that the dependence of the flatness factor of temperature derivative on the turbulent Rynolds number R is not as large as that which had been previously reported in the literature. The experimental data indicate a R ^0.5 dependence for the kurtosis of the temperature derivative and a R ^0.15 variation for the strain rate-scalar dissipation correlation.     

Impact of Neutral Boundary-Layer Turbulence on Wind-Turbine Wakes: A Numerical Modelling Study

The wake characteristics of a wind turbine in a turbulent boundary layer under neutral stratification are investigated systematically by means of large-eddy simulations. A methodology to maintain the turbulence of the background flow for simulations with open horizontal boundaries, without the necessity of the permanent import of turbulence data from a precursor simulation, was implemented in the geophysical flow solver EULAG. These requirements are fulfilled by applying the spectral energy distribution of a neutral boundary layer in the wind-turbine simulations. A detailed analysis of the wake response towards different turbulence levels of the background flow results in a more rapid recovery of the wake for a higher level of turbulence. A modified version of the Rankine–Froude actuator disc model and the blade element momentum method are tested as wind-turbine parametrizations resulting in a strong dependence of the near-wake wind field on the parametrization, whereas the far-wake flow is fairly insensitive to it. The wake characteristics are influenced by the two considered airfoils in the blade element momentum method up to a streamwise distance of 14D (D = rotor diameter). In addition, the swirl induced by the rotation has an impact on the velocity field of the wind turbine even in the far wake. Further, a wake response study reveals a considerable effect of different subgrid-scale closure models on the streamwise turbulent intensity.     

A Numerically Efficient Parametrization of Turbulent Wind-Turbine Flows for Different Thermal Stratifications

The wake characteristics of a wind turbine in a turbulent atmospheric boundary layer under different thermal stratifications are investigated by means of large-eddy simulation with the geophysical flow solver EULAG. The turbulent inflow is based on a method that imposes the spectral energy distribution of a neutral boundary-layer precursor simulation, the turbulence-preserving method. This method is extended herein to make it applicable for different thermal stratification regimes (convective, stable, neutral) by including suitable turbulence assumptions, which are deduced from velocity fields of a diurnal-cycle precursor simulation. The wind-turbine-wake characteristics derived from simulations that include the parametrization result in good agreement with diurnal-cycle-driven wind-turbine simulations. Furthermore, different levels of accuracy are tested in the parametrization assumptions, representing the thermal stratification. These range from three-dimensional matrices of the precursor-simulation wind field to individual values. The resulting wake characteristics are similar, even for the simplest parametrization set-up, making the diurnal-cycle precursor simulation non-essential for the wind-turbine simulations. Therefore, the proposed parametrization results in a computationally fast, simple, and efficient tool for analyzing the effects of different thermal stratifications on wind-turbine wakes by means of large-eddy simulation.