Diffusion of Ar in muscovite

Hydrothermal treatment of closely sized muscovite aggregates in a piston-cylinder apparatus induced ⁴⁰Ar^∗ loss that is revealed in ⁴⁰Ar/³⁹Ar step heating spectra. Age spectra and Arrhenius data, however, differ from that expected from a single diffusion length scale. A numerical model of episodic loss assuming the presence of multiple diffusion domains yields excellent fits between synthetic and actual degassing spectra. We used this model to isolate ⁴⁰Ar^∗ loss from the grains that remained intact during hydrothermal treatment at 10 kbar permitting calculation of diffusion coefficients in the temperature range 730-600 °C. Diffusion data generated in this manner yield an activation energy (E) of 63 ± 7 kcal/mol and frequency factor (D_o) of 2.3  cm²/s. Experiments at 20 kbar yield diffusivities lower by about an order of magnitude and correspond to an activation volume of ∼14 cm³/mol. Together, these parameters predict substantially greater retentivity of Ar in muscovite than previously assumed and correspond to a closure temperature (T_c) of 425 °C for a 100 μm radius grain cooling at 10 °C/Ma at 10 kbar (T_c = 405 °C at 5 kbar. Age and log (r/r_o) spectra for the run products show strong correlations indicating that muscovites can retain Ar diffusion boundaries and mechanisms that define their natural retentivity during vacuum step heating. This may permit the application of high resolution, continuous ⁴⁰Ar/³⁹Ar thermochronology to low grade, regionally metamorphosed terranes.     

Stardust impact analogs: Resolving pre‐ and postimpact mineralogy in Stardust Al foils

Abstract– The grains returned by NASA’s Stardust mission from comet 81P/Wild 2 represent a valuable sample set that is significantly advancing our understanding of small solar system bodies. However, the grains were captured via impact at ～6.1 km s^?1 and have experienced pressures and temperatures that caused alteration. To ensure correct interpretations of comet 81P/Wild 2 mineralogy, and therefore preaccretional or parent body processes, an understanding of the effects of capture is required. Using a two‐stage light‐gas gun, we recreated Stardust encounter conditions and generated a series of impact analogs for a range of minerals of cometary relevance into flight spare Al foils. Through analyses of both preimpact projectiles and postimpact analogs by transmission electron microscopy, we explore the impact processes occurring during capture and distinguish between those materials inherent to the impactor and those that are the product of capture. We review existing and present additional data on olivine, diopside, pyrrhotite, and pentlandite. We find that surviving crystalline material is observed in most single grain impactor residues. However, none is found in that of a relatively monodisperse aggregate. A variety of impact‐generated components are observed in all samples. Al incorporation into melt‐derived phases allows differentiation between melt and shock‐induced phases. In single grain impactor residues, impact‐generated phases largely retain original (nonvolatile) major element ratios. We conclude that both surviving and impact‐generated phases in residues of single grain impactors provide valuable information regarding the mineralogy of the impacting grain whilst further studies are required to fully understand aggregate impacts and the role of subgrain interactions during impact.     

Subarctic catchment water storage and carbon cycling – Leading the way for future studies using integrated datasets at Pallas,Finland

Subarctic ecohydrological processes are changing rapidly, but detailed and integrated ecohydrological investigations are not as widespread as necessary. We introduce an integrated research catchment site (Pallas) for atmosphere, ecosystems, and ecohydrology studies in subarctic conditions in Finland that can be used for a new set of comparative catchment investigations. The Pallas site provides unique observational data and high-intensity field measurement datasets over long periods. The infrastructure for atmosphere- to landscape-scale research in ecosystem processes in a subarctic landscape has recently been complemented with detailed ecohydrological measurements. We identify three dominant processes in subarctic ecohydrology: (a) strong seasonality drives ecohydrological regimes, (b) limited dynamic storage causes rapid stream response to water inputs (snowmelt and intensive storms), and (c) hydrological state of the system regulates catchment-scale dissolved carbon dynamics and greenhouse (GHG) fluxes. Surface water and groundwater interactions play an important role in regulating catchment-scale carbon balances and ecosystem respiration within subarctic peatlands, particularly their spatial variability in the landscape. Based on our observations from Pallas, we highlight key research gaps in subarctic ecohydrology and propose several ways forward. We also demonstrate that the Pallas catchment meets the need for sustaining and pushing the boundaries of critical long-term integrated ecohydrological research in high-latitude environments.     

Spatially distributed modelling of soil erosion and sediment yield at regional scales in Spain

Initiated by the need to quantify erosion rates and the impacts of global changes on erosion, several attempts have been made to apply erosion models at regional scales. However, these models have often been directed towards on-site soil erosion estimates, emphasising sheet and rill erosion processes, and disregarding gully erosion, channel erosion and sediment transport. These models are therefore of limited use for the assessment of sediment yield, off-site impacts of erosion, and for the development of environmental management to control these impacts at regional scale. This study analyses and compares three spatially distributed models for the prediction of soil erosion and/or sediment yield at regional scales: the WATEM-SEDEM model that is based on the empirical Revised Universal Soil Loss Equation (RUSLE) in combination with a sediment transport equation, the physics-based Pan European Soil Erosion Risk Assessment model (PESERA), and a newly developed Spatially Distributed Scoring model (SPADS). The three models were applied to 61 Spanish drainage basins and model predictions were evaluated against data on measured reservoir sedimentation rates. Global data sets on land use, climate, elevation and soil characteristics were used as model input for WATEM-SEDEM and SPADS, whereas published soil erosion estimates of PESERA at 1 km² resolution were used directly. SPADS and WATEM-SEDEM provided best results after separate calibration for basins with a Sediment Delivery Ratio (SDR) higher than 5% and those with an SDR lower than 5%. In this way, SPADS explained 67% of variation in sediment yield, while WATEM-SEDEM explained 48% of the variation. PESERA represents a promising alternative to the use of empirical models at the regional scale as it can be applied to very diverse environments with little calibration. However, PESERA provides soil erosion rates and not sediment yield estimates. For most basins PESERA soil erosion rates vary between fifty and close to zero percent of total sediment yield. Two major factors may explain this discrepancy between modelled soil erosion rates and measured sediment yield. First, it may be that PESERA underestimates soil erosion under Mediterranean conditions, although PESERA soil erosion rates are of the same order of magnitude as erosion rates measured in erosion plot studies. Second, gully-, river channel erosion and sediment transport processes may be much more important than sheet- and rill erosion for regional scale sediment yield in these environments. These issues therefore require further attention in future model development. Although spatially lumped models provide better predictions of sediment yield at the basin scale, and while validation of the predicted spatial patterns of sources and sinks of sediment requires further research, spatially distributed models are expected to be of value to support management decisions regarding the assessment of on-site and off-site impacts of erosion at the regional scale.     

Shalstab mathematical model and WorldView-2 satellite images to identification of landslide-susceptible areas

Natural Hazards - Natural hazards, occurring all over the world, may become a disaster when humans and nature interact. In Brazil, landslides triggered by heavy rainfall are the most common...     

Stratigraphische Untersuchungen im Unterrotliegenden des Pfälzer Sattels

Ohne Zusammenfassung     

Kleintektonik im Gebiet der Glarner überschiebung

Ohne Zusammenfassung