FTIR spectroscopy of Ti-chondrodite,Ti-clinohumite,and olivine in deeply subducted serpentinites and implications for the deep water cycle

Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/?0.017 ppm cm² based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm^?1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.     

On the gravitation absorption hypothesis

Summary It is recommended that the data from measurements with supraconducting gravity meters be also analysed with regard to verifying the gravitation absorption hypothesis. Based on theoretical data from a3-year period, the spectrum of the assumed effect of shielding the gravitational influence of the Sun by the Earth's body on the value of the acceleration of gravity has been calculated for the tidal station Brussels (Figs 2a–e).

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The design of the Central-Axis Reflector (ZAS)

The Central-Axis Reflector, the design principle which is presented below is a segmented-mirror telescope. The inventions relate mainly to the optical system and to the tracking apparatus.A large number of small individual mirror bodies, ground off-axis (hexagonal/polygonal) produce one primary mirror with closed circular aperture when joined together.The overall design of the tracking apperatus results directly —and thus without unnecessary adornment — from the two planes of to aminimum but which are required for tracking of the telescope.Paper presented at the Symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.     

Scientific challenges and instrumentation for the International Meridian Circle Program

Earth's ecosystems and human activities are threatened by a broad spectrum of hazards of major importance for the safety of ground infrastructures,space systems...     

Adjustment of a Formulated Sediment for Sediment Testing with Caenorhabditis elegans (Nematoda)

The OECD soil, which is standardised for use in the sediment toxicity with the midge Chironomus riparius revealed inhibition of the nematode Caenorhabditis elegans in body growth length and egg production of 41.0% and 84%, respectively. 18 formulated sediments were tested to optimise the sediment composition for growth and reproduction of C. elegans. Their components were chosen to simulate native sediments, whereby different quantities and different clay minerals were tested. The mixture that we found to be optimal in our experiments consisted of 5% sphagnum peat, 70% calcitic sand, 0.5% dolomite limestone, 4.5% iron(III) oxide, and a clay combination of 1.5% chlorite and 18.5% aluminium(III) oxide. When applying this mixture to C. riparius, the new formulated sediment improved also growth in comparison to the OECD sediment.     

Klimazonen der Verwitterung und ihre Bedeutung für die jüngste geologische Geschichte Deutschlands

Ohne Zusammenfassung     

Eine Kartierung der Bewegungsspuren im obersten Höllental (Schwarzwald)

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