The ITG-Goce02 gravity field model from GOCE orbit and gradiometer data based on the short arc approach

In this contribution, we describe the global GOCE-only gravity field model ITG-Goce02 derived from 7.5 months of gradiometer and orbit data. This model represents an alternative to the official ESA products as it is computed completely independently, using a different processing strategy and a separate software package. Our model is derived using the short arc approach, which allows a very effective decorrelation of the highly correlated GOCE gradiometer and orbit data noise by introducing a full empirical covariance matrix for each arc, and gives the possibility to downweight ‘bad’ arcs. For the processing of the orbit data we rely on the integral equation approach instead of the energy integral method, which has been applied in several other GOCE models. An evaluation against high-resolution global gravity field models shows very similar differences of our model compared to the official GOCE results published by ESA (release 2), especially to the model derived by the time-wise approach. This conclusion is confirmed by comparison of the GOCE models to GPS/levelling and altimetry data.     

Placing dots in dot maps

Dot mapping is a cartographic representation method to visualise discrete absolute values and their spatial distribution. To achieve this, dots equal in size and represented value are used. According to the dot value, a certain number of dots are used to depict a data value. These dots usually form dot clusters. The data value needs to be rounded to a multiple of the dot value. It is possible to roughly determine the visualised data value by counting the dots and multiplying this number with the dot value. As there are many parameters – dot size, dot value, map scale – to consider when designing a dot map, the manual way is very complex and time consuming. This paper presents a method to automatically create a dot representation of a dot map from given statistical data that needs no cartographic expertise. The dot representation may be combined with other elements, such as a topographic background, to form a complete map. So the algorithm can easily be integrated into the map design process. The paper refines the basic approach of automated dot mapping published earlier. The dot placement and arrangement have been improved compared to the basic method.     

Isotopic evidence (He,B, C) for deep fluid and mud mobilization from mud volcanoes in the Caucasus continental collision zone

The Caucasian orogenic wedge formed as a consequence of the closure of the Tethyan Ocean, and numerous fields of active mud volcanoes pepper the area adjacent to the Black and Caspian Seas. Stable isotope ratios of boron, helium, and carbon have been measured for gas, fluid and sediment samples from active mud volcanoes of Taman Peninsula and Georgia to estimate the sources and mobilization depths of the fluid phase and mud. Boron concentrations in mud volcano fluids were found to be 5–35× higher than seawater. Fluid isotope ratios vary between ¹¹B=22 and 39, while isotope ratios of the smectite- and illite-rich extruded mud are considerably depleted in heavy ¹¹B (¹¹B=–8 to +7). B contents of these muds are ~8× higher than modern marine sediments. This suggests that liquefaction prior to mud volcanism was accompanied by both B enrichment and isotope fractionation, most likely at an intermediate depth mud reservoir at 2–4 km.The hydrocarbon-generating source beds to the mud volcanoes are located at 7 to >10 km depth in the folded Maikop Formation and are of proposed Oligocene–Miocene age. The most likely mechanism is re-hydration of these shales by both hydrocarbons and a geochemically mature fluid from greater depth within the orogenic wedge. Such a deep fluid source is supported by our results from gas analyses, which imply an admixture of minor amounts (less than 1%vol) of ³He (Georgia), thermogenic ¹³C in methane as well as "ultraheavy" ¹³C in CO₂ (both Taman and Georgia). The overall results attest active local flow of geochemically different fluids along deep-seated faults penetrating the two study areas in the Caucasian orogenic wedge, with the waters as well as the gases coming from below the Maikop Formation.     

Regional gravity modeling in terms of spherical base functions

This article provides a survey on modern methods of regional gravity field modeling on the sphere. Starting with the classical theory of spherical harmonics, we outline the transition towards space-localizing methods such as spherical splines and wavelets. Special emphasis is given to the relations among these methods, which all involve radial base functions. Moreover, we provide extensive applications of these methods and numerical results from real space-borne data of recent satellite gravity missions, namely the Challenging Minisatellite Payload (CHAMP) and the Gravity Recovery and Climate Experiment (GRACE). We also derive high-resolution gravity field models by effectively combining space-borne and surface measurements using a new weighted level-combination concept. In addition, we outline and apply a strategy for constructing spatio-temporal fields from regional data sets spanning different observation periods.     

Distribution of sedimentary organic matter in Anisian carbonate series of S Poland: evidence of third-order sea-level fluctuations

The stratigraphic distribution of sedimentary organic matter in Anisian carbonate series of southern Poland is studied with respect to relative sea-level fluctuations. Palynofacies patterns clearly reflect transgressive–regressive trends that are interpreted in terms of third-order cyclicity. Major flooding phases are detected by maximum abundance of marine plankton in the upper Bithynian and Pelsonian. Transgressive and highstand deposits are recognized by changes in the terrestrial input of organic particles and the relative percentages and diversity of the plankton group. The palynological data support the sequence stratigraphic interpretation based on sedimentological features and geochemical signatures. The corresponding eustatic signals of sedimentary and organic facies are discussed. The study highlights the potential of palynofacies analysis for sequence stratigraphical interpretation.     

Combined effects of ethanol and cinnamaldehyde in the Japanese medaka embryo-larval assay (MELA)

The Japanese medaka (Oryzias latipes) was used in the medaka embryo-larval assay (MELA) to determine possible adverse developmental effects of ethanol and the spice component, cinnamaldehyde (CAD). Fish may be exposed to waterborne ethanol and a variety of natural products from non-point sources or leaks during ethanol use as a fuel and from point source processing plant effluents. Consumption of ethanol during human pregnancy is known to cause fetal alcohol syndrome (FAS), a collection of birth defects including craniofacial abnormalities thought to be caused by the generation of free radicals during ethanol metabolism by both alcohol and aldehyde dehydrogenase(s). Fish are also susceptible to FAS (Dasmahapatra et al., meeting abstract). The activity of aldehyde dehydrogenase is inhibited by CAD [Biochem. J. 282 (1992) 353-360; Biochem. Pharmacol. 45 (1993) 1621-1630], and CAD is known to cause developmental abnormalities in the rat [Food Chem. Toxicol. 27 (1989) 781-786]. Therefore, the combined effects of treatment with both ethanol and CAD would be expected to produce additive or greater than additive effects in the MELA assay. Medaka were exposed to ethanol at 100 mM, CAD at 10, 1.0, 0.67 or 0.50 mM, to ethanol and CAD combined, or were non-treated controls. Ethanol at 100 mM was without effect. CAD alone at 10 mM and 1.0 mM was lethal by 1 dpf. Embryos exposed to 100 mM ethanol and 0.67 mM CAD exhibited cardiovascular and pigmentation defects and delayed hatching. Embryos exposed to 0.50 mM CAD alone had less severe cardiovascular problems as compared to the combined ethanol and CAD treatment. Taken together the results indicate that the combined effects of ethanol and CAD are greater than the individual effects and indicate the need to monitor effluents in fish nursery areas to protect natural fish populations. Supported by PHS/NIH ES07929.     

Climate Change,Bushfire Risk,and Environmental Values: Examining a Potential Risk Perception Threshold in Peri-Urban South Australia

Striking a balance between the management of environmental risks and values is a challenge for decision-makers. If people perceive that environmental risks are increasing they may be willing to discount local values to manage those risks, so the identification of thresholds in risk perception in relation to specific behaviors could help to avoid policy failures. The complex relationships between perceptions of climate change and bushfire risks, environmental values and support for actions to mitigate local risks are presented for peri-urban regions in South Australia. The results of a household survey (N=988) suggest that a threshold of risk perception in relation to climate change and bushfire management has not been exceeded and people are broadly supportive of balanced management interventions. A minority of people still do not perceive that climate change is increasing bushfire risk, and are supportive of risk mitigation interventions even at the expense of local biodiversity. However, a larger group believe that climate change is a driver of bushfire risk, yet are still more likely to prioritize ecological values and are unwilling to discount those values for risk mitigation. Targeted communication could assist different groups to respond to gaps in knowledge and action to facilitate effective, differentiated interventions within forested landscapes on the margins of urban areas.     

Light-induced conversion of refractory,high molecular weight lake water constituents

High molecular weight DOM (apparent mol wt. ≥1500) was isolated from lake water, both in summer and in winter. Sephadex G-15 gel permeation chromatography with 0.02 M phosphate buffer yielded one peak. Elution with distilled water gave rise to distinct smaller sized subfractions. It was concluded that these compounds are weakly bound subunits of the macromolecules, which are liberated on elution with distilled water. The macromolecules were not stable in the dark. Exposing them to daylight in the laboratory and to sunlight, in quartz bottles enhanced conversion. During 6 weeks' exposure to weakly photolytic conditions (daylight >300 nm), organic carbon of the high molecular bulk substances decreased by 15% (winter) and by 25% (summer), while the concentrations of the apparent low molecular weight substances increased accordingly. Such a slow but continuous transformation may reduce also the <in situ> persistence of the macromolecules gradually.