Insights into preservation of fossil plant cuticles using thermally assisted hydrolysis methylation

The chemical composition of Cretaceous leaf remains showing exceptionally well preserved cuticles was investigated using pyrolysis gas chromatography–mass spectrometry (Py-GC–MS) and thermally assisted hydrolysis methylation (THM)-GC–MS. Samples of Coniferales (Frenelopsis) and Ginkgoales (Nehvizdya penalveri) leaf remains were collected from freshwater and coastal marine depositional environments. Material for pyrolysis included (i) untreated leaves and cuticles obtained after extraction from mineral rock matrix and bleaching, (ii) kerogen fraction from both materials, (iii) non-hydrolysable fraction from kerogen. The THM-GC–MS data from untreated leaves and bleached cuticles show that the fossil cuticle geopolymer essentially released aliphatic components upon thermal treatment, with a dominance of fatty acids (FAs) and n-alkanes/n-alkenes. The FAs are essentially resistant to bleaching and remain after solvent extraction. They occur mainly as short chain compounds ranging from C₆ to C₁₆ and with maximum abundance at C₈–C₉. The n-alkanes/n-alkenes from kerogen and the non-hydrolysable residue occur mainly as short chain compounds in the range C₁₀–C₁₆, with the highest abundance at C₉–C₁₂. The THM-GC–MS pyrograms of the fossil cuticles differ from those of cutan from fresh living plants. They support the preservation model via polymerization of monomers derived from cutin or from unsaturated cell FAs.     

Stratification and water mass formation in the Arctic Ocean: some implications for the nutrient distribution

The mixing processes and the water formations (transformations) in the Arctic Ocean are reviewed and their influence on the stratification discussed. The relations between the stratification and the nutrient distribution are examined. The interactions between drifting sea ice and advected warmer and nutrient-rich waters favour an early biological activity. By contrast, in the central Arctic Ocean and over comparably deep shelf areas such as the northern Barents Sea, the possibilities for large productivity are more limited because of late melting, less nutrient supply, and in the central Arctic, less available light. The sedimentation of organic matter on the shelves and the remineralisation into cold, dense waters formed by brine rejection and draining off the shelves lead to a loss of nutrients to the deep waters, which must be compensated for by advection of nutrient rich waters to the Arctic Ocean.
Possible effects of a reduction of the river run-off on the stratification and the nutrient distribution are discussed.     

SP-Mylonites: Origin of some mylonites by superplastic flow

Superplasticity in fine-grained materials is characterized by extensive grain boundary sliding. This phenomenon can take place only in special conditions. Six criteria are thus defined to determine when Superplasticity has been active. Applications of these criteria to several examples of mylonites are discussed and we conclude that superplasticity explains some types of mylonites and the tectonic banding that they exhibit.     

Development of schistosity by dissolution–crystallization in a Californian serpentinite gouge

To understand the behaviour and deformation mechanisms of serpentinites in the seismogenic zone we study the deformation macro- and microstructures of serpentinites along the Santa Ynez Fault in the San Andreas System. At the outcrop scale, deformation is localized in a gouge zone that shows three different structures: (1) micrometric undeformed fragments (clasts) of the previously serpentinized peridotite, (2) localized shear planes (Y and R) and (3) a penetrative schistosity (S). Observations under SEM and TEM reveal that the schistosity corresponds to serpentine fibres, parallel to each other, and whose orientation varies as they wrap around clasts. TEM micro-textures indicate that these long fibres result from continuous syntectonic growth rather than from reorientation of pre-existing fibres implying a slow transfer process that occurs at short distances. We propose a dissolution–diffusion–crystallization process for the formation of the schistosity that corresponds to a low strain-rate creeping process of deformation that can be effective in aseismic fault segments.     

Embracing postcolonial geographies: Contributions by Dame Evelyn Stokes to the development of postcolonial geography in New Zealand

Abstract: This paper acknowledges Dame Evelyn Stokes’ introduction of postcolonial critical analysis of Māori/Pākehā relationships before postcolonialism was established as a field of theoretical enquiry. The paper reviews research I have done on some of the issues faced by the Mashantucket Pequots in the wider context of the contribution Dame Evelyn Stokes was making to similar debates in New Zealand. She emphasized that Māori research and knowledge provide a different world view and that this world view needs to be taken into account in any geographical study of New Zealand. Only in this way will it be possible to avoid the continued marginalization of Māoris from nation building in their own country.     

Seismic Microzonation: A Comparison between Geotechnical and Seismological Approaches in Pointe-à-Pitre (French West Indies)

Pointe-à-Pitre, the main city of Guadeloupe in the French West Indies, has on several occasions been partially destroyed by major historical earthquakes. Moreover, a post-seismic assessment of the damage from the 1985 Montserrat earthquake indicates that the town is prone to site effects. Consequently, from 1996 to 1998, BRGM conducted a seismic microzonation study based on geotechnical and geological data. At the same time, three seismological studies were being conducted – two based on earthquake recordings using a time-series analysis and the classical spectral ratio (CSR) method (CETE/LCPC and BRGM), and the third based on noise measurement at 400 points using the horizontal-to-vertical noise ratio (HVNR) method (CETE/LCPC). The objective of this paper is not to carry out a new microzonation study by taking into account all the results, but rather to show in what respects the results of these different methods are in agreement or not. A comparison of the results of the seismological studies with the geotechnical microzonation shows that they are in fairly good agreement, albeit with some discrepancies. The results indicate that the seismological methods and the geotechnical data are highly complementary and should be used together in compiling seismic transfer-function microzonation maps. This revised version was published online in July 2006 with corrections to the Cover Date.