Early fill of the Western Irish Namurian Basin: a complex relationship between turbidites and deltas

The Western Irish Namurian Basin developed in Early Carboniferous times as a result of extension across the Shannon Lineament which probably coincides with the lapetus Suture. During the late Dinantian, axial areas of the NE-SW elongate trough became deep, whilst shallow-water limestones were deposited on the flanks. This bathymetry persisted into the Namurian when carbonate deposition ceased. In axial areas, a relatively thick mudstone succession spans earliest Namurian to Chokierian whilst on the northwestern marginal shelf, a thin, condensed Namurian mudstone sequence, in which pre-Chokierian sediments are apparently absent, rests unconformably on the Dinantian. From late Chokierian to early Kinderscoutian, the basin was filled by sand-dominated clastic sediments. Sand deposition began in the axial area with deposition of a thick turbidite sequence, the Ross Formation, which is largely equivalent to the condensed mudstone succession on the flanks. Turbidity currents flowed mainly axially towards the north-east and deposited a sequence lacking well-defined patterns of vertical bed-thickness change. Channels and slide sheets occur towards the top of the formation. The turbidite system seems to have lacked well-defined lobes and stable distributary channels. Overlying the Ross Formation, the Gull Island Formation shows a decreasing incidence of turbidite sandstones at the expense of increasing siltstones. This formation is characterized by major slides and slumps interbedded with undisturbed strata. In the flanking areas of the basin, the formation is thinner, has only a few turbidites in the sequence above the condensed mudstones and contains only one slide sheet. Overall the formation is interpreted as the deposit of a major prograding slope, the lower part representing a ramp upon which turbidites were deposited, the upper part a highly unstable muddy slope lacking any conspicuous feeder channels through which sand might have been transferred to deeper water. Progradation of the slope appears to have been increasingly from the northwestern flank of the trough which is similar to the direction deduced for the overlying deltaic Tullig cyclothem which completes the initial basin fill. Whilst several features of the succession can be explained by envisaging the whole sequence as the product of one linked depositional system, the shifting directions of palaeocurrents and palaeoslope raise problems. The switch from axial to lateral supply casts doubt on the strict application of Walther's Law to the total sequence and seems to demand large avulsive shifts of the delta system on the shelf area to the west.     

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Element partitioning during precipitation of aragonite from seawater: A framework for understanding paleoproxies

This study presents the results from precipitation experiments carried out to investigate the partitioning of the alkaline earth cations Mg²⁺, Ca²⁺, Sr²⁺, and Ba²⁺ between abiogenic aragonite and seawater as a function of temperature. Experiments were carried out at 5 to 75 °C, using the protocol of Kinsman and Holland [Kinsman, D.J.J., Holland, H.D., 1969. The coprecipitation of cations with CaCO₃ IV. The coprecipitation of Sr²⁺ with aragonite between 16 and 96 °C. Geochim. Cosmochim. Acta33, 1-17.] The concentrations of Mg Sr and Ba were determined in the fluid from each experiment by inductively coupled plasma-mass spectrometry, and in individual aragonite grains by secondary ion mass spectrometry. The experimentally produced aragonite grains are enriched in trace components (“impurities”) relative to the concentrations expected from crystal-fluid equilibrium, indicating that kinetic processes are controlling element distribution. Our data are not consistent with fractionations produced kinetically in a boundary layer adjacent to the growing crystal because Sr²⁺, a compatible element, is enriched rather than depleted in the aragonite. Element compatibilities, and the systematic change in partitioning with temperature, can be explained by the process of surface entrapment proposed by Watson and Liang [Watson, E.B., Liang, Y., 1995. A simple model for sector zoning in slowly grown crystals: implications for growth rate and lattice diffusion, with emphasis on accessory minerals in crustal rocks. Am. Mineral.80, 1179-1187] and Watson [Watson, E.B., 1996. Surface enrichment and trace-element uptake during crystal growth. Geochim. Cosmochim. Acta60, 5013-5020; Watson, E.B., 2004. A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals. Geochim. Cosmochim. Acta68, 1473-1488]. This process is thought to operate in regimes where the competition between crystal growth rate and diffusivity in the near-surface region limits the extent to which the solid can achieve partitioning equilibrium with the fluid. A comparison of the skeletal composition of Diploria labyrinthiformis (brain coral) collected on Bermuda with results from precipitation calculations carried out using our experimentally determined partition coefficients indicate that the fluid from which coral skeleton precipitates has a Sr/Ca ratio comparable to that of seawater, but is depleted in Mg and Ba, and that there are seasonal fluctuations in the mass fraction of aragonite precipitated from the calcifying fluid (“precipitation efficiency”). The combined effects of surface entrapment during aragonite growth and seasonal fluctuations in “precipitation efficiency” likely forms the basis for the temperature information recorded in the aragonite skeletons of Scleractinian corals.     

Analysis of the Devonian (Frasnian) platform from Belgium: a multi‐faceted approach for basin evolution reconstruction

This study undertakes a multi‐disciplinary approach (sedimentology, carbon isotopes, magnetic susceptibility and thickness distribution) to improve understanding of a major Palaeozoic carbonate platform, the Frasnian platform of Belgium. These combined techniques are used to reconstruct the platform history, which evolved in two main steps. During the first phase, the basin was strongly influenced by faulting, producing notable thickness and facies variations, with open ocean conditions, with good water circulation and no/or limited barrier reef. The second phase of platform development was less influenced by differential subsidence, as indicated by homogeneous facies distribution. However, this platform developed under restricted waters, with low circulation which is likely related to the development of a barrier reef.     

The Livelihood Vulnerability Index: A pragmatic approach to assessing risks from climate variability and change—A case study in Mozambique

We developed the Livelihood Vulnerability Index (LVI) to estimate climate change vulnerability in the Mabote and Moma Districts of Mozambique. We surveyed 200 households in each district to collect data on socio-demographics, livelihoods, social networks, health, food and water security, natural disasters and climate variability. Data were aggregated using a composite index and differential vulnerabilities were compared. Results suggest that Moma may be more vulnerable in terms of water resources while Mabote may be more vulnerable in terms of socio-demographic structure. This pragmatic approach may be used to monitor vulnerability, program resources for assistance, and/or evaluate potential program/policy effectiveness in data-scarce regions by introducing scenarios into the LVI model for baseline comparison.     

New snow metrics for a warming world

Snow is Earth's most climatically sensitive land cover type. Traditional snow metrics may not be able to adequately capture the changing nature of snow cover. For example, April 1 snow water equivalent (SWE) has been an effective index for streamflow forecasting, but it cannot express the effects of midwinter melt events, now expected in warming snow climates, nor can we assume that station-based measurements will be representative of snow conditions in future decades. Remote sensing and climate model data provide capacity for a suite of multi-use snow metrics from local to global scales. Such indicators need to be simple enough to “tell the story” of snowpack changes over space and time, but not overly simplistic or overly complicated in their interpretation. We describe a suite of spatially explicit, multi-temporal snow metrics based on global satellite data from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) and downscaled climate model output for the U.S. We describe and provide examples for Snow Cover Frequency (SCF), Snow Disappearance Date (SDD), At-Risk Snow (ARS), and Frequency of a Warm Winter (FWW). Using these retrospective and prospective snow metrics, we assess the current and future snow-related conditions in three hydroclimatically different U.S. watersheds: the Truckee, Colorado Headwaters, and Upper Connecticut. In the two western U.S. watersheds, SCF and SDD show greater sensitivity to annual differences in snow cover compared with data from the ground-based Snow Telemetry (SNOTEL) network. The eastern U.S. watershed does not have a ground-based network of data, so these MODIS-derived metrics provide uniquely valuable snow information. The ARS and FWW metrics show that the Truckee Watershed is highly vulnerable to conversion from snowfall to rainfall (ARS) and midwinter melt events (FWW) throughout the seasonal snow zone. In comparison, the Colorado Headwaters and Upper Connecticut Watersheds are colder and much less vulnerable through mid- and late-century.     

Northern boundary current variability and mesoscale dynamics: a long-term HF RADAR monitoring in the North-Western Mediterranean Sea

Ocean Dynamics - Coastal waters are globally challenging areas to monitor not only because of the high resolution needed to resolve the scales at stake but also because most satellites are not yet...