Problems of ratifying international environmental agreements: Overcoming initial obstacles in the post-agreement negotiation process

The post-agreement period typically is characterized by negotiations between various stakeholders to reach mutually beneficial and acceptable means to achieve national implementation of, and compliance with, treaty provisions. National ratification of international environmental agreements is often the first subprocess of these ‘postagreement negotiations’. This article places ratification negotiations within the larger conceptual context of postagreement negotiations, with the goal of understanding and explaining problems of treaty Implementation. An empirical analysis reveals that delay in national ratification of environmental agreements is a chronic problem, but is worse for complex, multi-issue treaties. Strong public concern over local environmental issues, low quality of life, low national wealth, and low public research and development expenditures for environmental protection contribute to ratification delay. Ultimately, the authors are interested in identifying ways of improving the international negotiation process that initiated these later problems in implementation. Recommendations are offered in this regard.     

The response of lake levels and areas to climatic change

The levels and areas of lakes, particularly closed lakes (those without outlet) are known to be sensitive indicators of changes in climate, and so in principle they can play a role in monitoring current and future climatic changes. In this paper we derive solutions to the water balance equation giving the response of the level and area of closed lakes to steps, spikes and sinusoidal variations in aridity, and show that such a lake acts approximately as a simple low pass filter having a characteristic equilibrium response timeτ _e. We also review the similar response of open lakes to changes in runoff. It is shown howτ _e depends on lake geomorphology and climate, and for a number of lakes we calculateτ _e values, ranging from 1.5 to 350 yr for closed lakes, and from 2.9 days to 2 yr for open lakes. We propose methods involving Fourier analysis for inverting closed lake level or area records to obtain plots of a simple aridity index C. It is shown that for all ≈ 200 of the world's large (? 100 km²) closed lakes, satellite remote sensing of lake levels and areas is currently sensitive enough to monitor variations in C (e.g. in average basin precipitation) of order 1% to 10% on the time-scale of years to decades.     

Recruitment of Mytilus edulis L. in the Thames estuary,with evidence for differences in the time of maximal settling along the Connecticut shore

In the Thames Estuary at the eastern end of Long Island Sound, most mussels achieve maximal gonadal development during the summer and larval settlement occurs primarily during the fall. The timing of reproductive events is several months later than has been reported for other populations of mussels in Long Island Sound but corresponds to that of mussels inhabiting the south shore of Long Island. The data support the growing body of evidence which indicates that temperature is not a major factor determining the reproductive period of this bivalve.     

Accurate and efficient shot-gather dip moveout processing in the log-stretch domain1

An accurate analytical expression for shot-gather dip-moveout (DMO) in the timespace log-stretch domain has until now not been published. We present a simpler, alternative derivation of the exact DMO relationships of Black et al. which correctly take account of the repositioning of the midpoint. A new computationally efficient frequency-wavenumber (F-K) DMO operator for shot profiles is then derived, based on these DMO relationships in the time-space log-stretch domain. The newly derived DMO operator is, unlike most other log-stretch DMO operators) accurate for the full range of reflector dips. Along with other schemes which are performed in the log-stretch domain, it offers considerable time savings over conventional DMO processing. We have compared numerically the impulse response of the new operator with those of a number of other shot-gather DMO operators, and found it to be superior and well match to the theoretical elliptical DMO response.     

PGE fractionation in seafloor hydrothermal systems: examples from mafic- and ultramafic-hosted hydrothermal fields at the slow-spreading Mid-Atlantic Ridge

The distribution of platinum group elements (PGEs) in massive sulfides and hematite–magnetite±pyrite assemblages from the recently discovered basalt-hosted Turtle Pits hydrothermal field and in massive sulfides from the ultramafic-hosted Logatchev vent field both on the Mid-Atlantic Ridge was studied and compared to that from selected ancient volcanic-hosted massive sulfide (VHMS) deposits. Cu-rich samples from black smoker chimneys of both vent fields are enriched in Pd and Rh (Pd up to 227 ppb and Rh up to 149 ppb) when compared to hematite–magnetite-rich samples from Turtle Pits (Pd up to 10 ppb, Rh up to 1.9 ppb). A significant positive correlation was established between Cu and Rh in sulfide samples from Turtle Pits. PGE chondrite-normalized patterns (with a positive Rh anomaly and Pd and Au enrichment), Pd/Pt and Pd/Au ratios close to global MORB, and high values of Pd/Ir and Pt/Ir ratios indicate mafic source rock and seawater involvement in the hydrothermal system at Turtle Pits. Similarly shaped PGE chondrite-normalized patterns and high values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides at Logatchev likely reflect a similar mechanism of PGE enrichment but with involvement of ultramafic source rocks.     

The radio frequency dielectric properties of the stratified UG1–UG2 geological unit in the Bushveld Complex

A new measurement technique enables the complex dielectric properties of the geological strata comprising the UG1–UG2 (Upper Group 1–Upper Group 2) unit of the Bushveld Complex in South Africa to be determined with unprecedented detail at radio frequencies (RF). Results of non-destructive laboratory measurements of representative diamond drill core samples from the UG1–UG2 unit are presented at 25 MHz. These data establish that the UG1 and UG2 chromitite layers are embedded in rock strata (norite, pyroxenite and anorthosite) which are translucent in the HF spectral band, whereas the chromitite layers themselves exhibit significant velocity contrast, making them good radar reflectors. The data presented here is useful for calibration of the radar system, and for predicting the range and resolution performance of borehole radars operating in both the hanging and footwalls of the economically important platiniferous UG2 reef.     

Measured And Simulated Latent And Sensible Heat Fluxes At Two Marine Sites In The Baltic Sea

In this study, turbulent heat flux data from two sites within the Baltic Sea are compared with estimates from two models. The main focus is on the latent heat flux. The measuring sites are located on small islands close to the islands of Bornholm and Gotland. Both sites have a wide wind direction sector with undisturbed over-water fetch. Mean parameters and direct fluxes were measured on masts during May to December 1998.The two models used in this study are the regional-scale atmospheric model HIRLAM and the ocean model PROBE-Baltic. It is shown that both models overestimate the sensible and latent heat fluxes. The overestimation can, to a large extent, be explained by errors in the air-water temperature and humidity differences. From comparing observed and modelled data, the estimated 8-month mean errors in temperature and humidity are up to 1 °C and 1 g kg^-1, respectively. The mean errors in the sensible and latent heat fluxes for the same period are approximately 15 and 30 W m^-2, respectively.Bulk transfer coefficients used for calculating heat and humidity fluxes at the surface were shown to agree rather well with the measurements, at least for the unstable data. For stable stratification, the scatter in data is generally large, and it appears that the bulk formulation chosen overestimates turbulent heat fluxes.     

Broadband synthetic aperture borehole radar interferometry

Trials in mines have established that wideband VHF borehole radars (BHR), working in the 10–100-MHz band, can be used to probe the rockmass between boreholes over ranges from <5 m to as much as 150 m with submeter resolution. There is evidence that ore bodies reflect these radar signals both specularly and diffusely, much as the ground/air interface does when overflown by synthetic aperture radar (SAR). In both SAR and BHR, multiple flight lines, together with diffuse reflections admit the possibility of developing interferometric 3D images of the object. This paper examines the possibility of imaging buried objects in three dimensions by interferometrically combining broadband VHF borehole radar profiles shot in adjacent pairs of boreholes. Broadbanding in BHR has the advantage of releasing the image from 2nπ phase ambiguities, but practically, interferometric borehole radar (InBHR) needs high signal-to-noise ratios (SNR) to avoid noise capture. This means that 3D InBHR is limited to ranges in wavelengths which are less than the rock's attenuation factor Q. Interferometric methods are developed which are capable of mapping ore bodies and other structures in three dimensions. Tangent plane migration methods are developed here in order to reconstruct surfaces that lie in the near-field of sparse interferometric arrays.     

The sources and composition of mercury in Pacific Ocean rain

Here we report measurements of total Hg (Hg_T), reactive Hg (Hg_R), and methylmercury (MMHg) in precipitation from the equatorial Pacific Ocean, collected during a cruise in January and February 1990, and from a mid-continental location in the rural temperate lacustrine northcentral Wisconsin environs. The concentrations of Hg_T (14.4±6.5 pM), Hg_R (8.9±4.5 pM) and MMHg (<50 fM) found in equatorial Pacific rain were less than the average concentrations found in Wisconsin. In general, the results indicate that although particulate Hg is a small fraction of the total atmospheric Hg burden, it is the major contributor to Hg in precipitation. Furthermore, deposition could be an important source of Hg_R to the equatorial Pacific Ocean. In contrast, deposition is not a significant source of MMHg to either the equatorial Pacific Ocean or the remote seepage lakes of Wisconsin. This implies that methylated mercury is formedin situ in these systems.