Analyses of pre-injection reservoir data for stable carbon isotope trend predictions in CO2 monitoring: preparing for CO2 injection

Baseline monitoring at the proposed enhanced gas recovery site in Altmark (Germany) was carried out in combination with theoretical and laboratory investigations to describe and predict the principles of expected stable carbon isotope and dissolved inorganic carbon (DIC) trends during CO₂ injection in reservoirs. This provides fundamental data for site-specific characterisation for monitoring purposes. Baseline ??¹³C values at the Altmark site ranged between ?1.8 and ?11.5??? and DIC values were about 2?mmol?L^?1. These baseline values form the basis for a theoretical study on the influences of the ambient reservoir conditions on the state of geochemical and isotope equilibrium of the reservoir fluids. Transferring this theoretical study to the Altmark site enables predictions on geochemical trends during potential injection. Assuming that CO₂ would be injected at the Altmark site to pCO₂?=?100?bar and with a ??¹³C of ?30???, at isotopic and geochemical equilibrium, ??¹³C_DIC values would approach this end-member, and DIC concentrations of 1,000?mmol L^?1 would be expected. Laboratory experiments were conducted at low pCO₂ levels (4?C35?bars) to mimic the approach of a CO₂ plume at a monitoring well. These results support field investigations from other sites: that ??¹³C_DIC is a sensitive tool for monitoring CO₂ migration in the subsurface and simultaneously allows quantification of geochemical trapping of CO₂.     

The effect of an interface boundary layer on the resonance properties of a buried structure

This paper presents a model for the analysis of the diffraction of plane waves at a cavity in an infinite homogeneous linear elastic medium supported by a segmented lining. An elastic boundary layer is introduced between the cavity lining and the infinite medium. The boundary layer is simulated by ‘elastic boundary conditions’ in which the stress is proportional to the relative displacement of the lining and of the surrounding medium boundary. A closed‐form analytical solution of the problem was obtained using the Fourier–Bessel series, the convergence of which was proven. It was shown that the number of series terms required to obtain a desired level of accuracy can be determined in advance. Using amplitude–frequency response analysis it was shown that the boundary layer produces additional ‘pseudo‐resonance’ frequencies that depend on the layer properties. These frequencies are almost identical to the eigenvalues obtained from the simple analysis of a segmented elastically supported lining. Copyright © 2003 John Wiley & Sons, Ltd.     

A Challenging Solar Eruptive Event of 18 November 2003 and the Causes of the 20 November Geomagnetic Superstorm. III. Catastrophe of the Eruptive Filament at a Magnetic Null Point and Formation of an Opposite-Handedness CME

Our analysis in Papers I and II (Grechnev et al., Solar Phys. 289, 289, 2014b and Solar Phys. 289, 1279, 2014c) of the 18 November 2003 solar event responsible for the 20 November geomagnetic superstorm has revealed a complex chain of eruptions. In particular, the eruptive filament encountered a topological discontinuity located near the solar disk center at a height of about 100 Mm, bifurcated, and transformed into a large cloud, which did not leave the Sun. Concurrently, an additional CME presumably erupted close to the bifurcation region. The conjectures about the responsibility of this compact CME for the superstorm and its disconnection from the Sun are confirmed in Paper IV (Grechnev et al., Solar Phys. submitted, 2014a), which concludes about its probable spheromak-like structure. The present article confirms the presence of a magnetic null point near the bifurcation region and addresses the origin of the magnetic helicity of the interplanetary magnetic clouds and their connection to the Sun. We find that the orientation of a magnetic dipole constituted by dimmed regions with the opposite magnetic polarities away from the parent active region corresponded to the direction of the axial field in the magnetic cloud, while the pre-eruptive filament mismatched it. To combine all of the listed findings, we propose an intrinsically three-dimensional scheme, in which a spheromak-like eruption originates via the interaction of the initially unconnected magnetic fluxes of the eruptive filament and pre-existing ones in the corona. Through a chain of magnetic reconnections their positive mutual helicity was transformed into the self-helicity of the spheromak-like magnetic cloud.     

On the theoretical evaluation of the hubble red-shift constant

Some modifications to the model of M17 proposed by Elliott and Meaburn (1975) are suggested.     

Serum biochemical and cellular responses to experimental cupric ion challenge in mussels

Our intent has been to develop rapid and sensitive bioassay procedures for laboratory and field applications based on hemolymph factors in animals such as the bay mussel, Mytilus edulis. We found that mussel hemolymph could be easily and repeatedly sampled from individual animals in sufficient amounts to allow analyses for lysozyme, proteolytic activity, total protein and hemocyte counts. In static tests there seemed to be graded responses indicating release of increasing amounts of the above factors into the hemolymph in roughly direct proportion to Cu²⁺ concentration at lethal and sublethal levels. We interpreted this to be evidence for increased lysosomal and cellular disruption as cupric ion exposure was increased or prolonged. At the same time, Cu²⁺ concentrations in the mussel hemolymph increased up to an order of magnitude above ambient in the range of 26 to 267 ppb. We felt that this was evidence for the release of Cu-binding proteins into the mussel hemolymph. Simultaneously with the above events the serum granulocytes increased in numbers above control values by factors of 3 or 4 in response to copper challenge while macrophage (terminology of Moore & Lowe, 1977) counts, including controls, declined precipitously.     

The Middle and Upper Devonian in southeastern flank of the Siberian platform (Southern Verkhoyansk Region,Sette-Daban Mountain Range)

Data on Middle and Upper Devonian deposits studied in southeastern flank of the Siberian platform are considered. A scheme of stratigraphic zoning in the study region is presented. Nineteen sedimentological and biotic events, which are recorded in the studied sections, are of the regional, interregional and global ranks. Their connection with eustatic sea-level fluctuations is established. Sections of the formation and regional horizon stratotypes and parastratotypes are described. The revision of species Mucrospirifer novosibiricus (Toll) is carried out.     

Petrogenesis and geotectonic setting of the PanAfrican basement rocks in Bamenda Massif, Obudu Plateau, southeastern Nigeria： Evidence from trace element geochemistry

1 IntroductionThe study area is part of the Obudu Plateau,which forms part of the Precambrian Pan-African tec-tonothermal belt, lying between the West African Cra-ton and the Gabon-Congo Craton ( Fig. 1). It isbounded by the Benue Trough, in the NE-SW axi…