Combined Sr isotope and trace element analysis of melt inclusions at sub-ng levels using micro-milling, TIMS and ICPMS

This paper describes a technique, which allows precise and accurate Sr isotope measurement combined with trace element analysis of individual melt inclusions, of sample sizes  1 ng of Sr. The technique involves sampling by micro-milling, chemical dissolution, micro Sr column chemistry, TIMS, and ICPMS analyses. A 10% aliquot of each sample solution is used for trace element analysis by double focusing magnetic sector field ICPMS, while Sr is chemically separated from the remaining 90% and used for ⁸⁷Sr/⁸⁶Sr determinations by TIMS.During the development of the technique outlined above, we documented in detail the potential sources of blank contributions and their magnitude. The average size and Sr isotope composition of our laboratory total procedural blank during this study was 5.4 pg ± 0.3 pg Sr (n = 21) with an ⁸⁷Sr/⁸⁶Sr of 0.7111 ± 0.0002 (2SE, n = 3). The total procedural Rb blank was 1.9 ± 0.7 pg (n = 21). The total procedural blank was found to have minimal effect (< 150 ppm shift) on the ⁸⁷Sr/⁸⁶Sr of sample material containing down to  250 pg Sr. Applying a blank correction allows ‘in house’ standards of this size to be corrected back to within 175 ppm of their accepted values. By applying blank corrections we can confidently measure the Sr isotope composition on sample sizes down to  25 pg Sr to an accuracy better than 400 ppm.The utility of the technique is illustrated by application to a suite of melt inclusions from NW Iceland and their host olivines. It is shown that the effect of a small amount of entrainment of the host olivine during sampling of 50 μm melt inclusions has a negligible effect on the measured Sr isotope and trace element composition. Furthermore, where melt inclusions are < 50 μm it is possible to obtain Sr isotope and trace element data on multiple melt inclusions hosted in a single olivine. This provides similar information to that of the single melt inclusions.     

Punctuated,long-lived emplacement history of the Renard 2 kimberlite,Canada, revealed by new high precision U-Pb groundmass perovskite dating

Kimberlites are rare volatile-rich ultramafic magmas thought to erupt in short periods of time (<1 Myr) but there is a growing body of evidence that the emplacement history of a kimberlite can be significantly more protracted. In this study we report a detailed geochronology investigation of a single kimberlite pipe from the Renard cluster in north-central Québec. Ten new high precision ID-TIMS (isotope dilution – thermal ionization mass spectrometry) U-Pb groundmass perovskite dates from the main pipe-infilling kimberlites and several small hypabyssal kimberlites from the Renard 2 pipe indicate kimberlite magmatism lasted at least ~20 Myr. Two samples of the main pipe-infilling kimberlites yield identical weighted mean ²⁰⁶Pb/²³⁸U perovskite dates with a composite date of 643.8 ± 1.0 Myr, interpreted to be the best estimate for main pipe emplacement. In contrast, six hypabyssal kimberlite samples yielded a range of weighted mean ²⁰⁶Pb/²³⁸U perovskite dates between ~652-632 Myr. Multiple dates determined from these early-, syn- and late-stage small hypabyssal kimberlites in the Renard 2 pipe demonstrate this rock type (commonly used to date kimberlites) help to constrain the duration of kimberlite intrusion history within a pipe but do not necessarily reliably record the emplacement age of the main diatreme in the Renard cluster. Our results provide the first robust geochronological data on a single kimberlite that confirms the field relationships initially observed by Wagner (1914) and Clement (1982); the presence of antecedent (diatreme precursor) intrusions, contemporaneous (syn-diatreme) intrusions, and consequent (post-diatreme) cross-cutting intrusions. The results of this detailed U-Pb geochronology study indicate a single kimberlite pipe can record millions of years of magmatism, much longer than previously thought from the classical viewpoint of a rapid and short-duration emplacement history.

     

Using micro-catchment experiments for multi-local scale modelling of nature-based solutions

The Q-natural flood management project has co-developed with the Environment Agency 18 monitored micro-catchments (~1 km²) in Cumbria, UK installing calibrated flumes aimed at quantifying the potential shift in observed flows resulting from a range of nature-based-solutions installed by local organizations. The small-scale reduces the influence of variability characterizing larger catchments that would otherwise mask any such shifts, which we attempt to relate to a shift in model parameters. This paper demonstrates an approach to applying donor-parameter-shifts obtained from modelling two of the paired micro-catchments to a much larger scale, in order to understand the potential for improved distributed modelling of nature-based solutions in the form of additional tree-planting. The models include a rainfall-runoff model, Dynamic Topmodel, and a 2D hydrodynamic model, JFlow, permitting analysis of changes in hillslope processes and channel hydrodynamics resulting from a range of distributed measures designed to emulate natural hydrological processes that evaporate, store or infiltrate flows. We report on attempts to detect shift in hydrological response using one of the paired-micro-catchment moorland versus forestry sites in Lorton using Dynamic Topmodel. A donor-parameter-shift approach is used in a hypothetical experiment to represent new woodland in a much larger catchment, although testing all combinations of spatial planting strategies, responses to multiple-extremes, failure-modes and changes to synchronization becomes intractable to support good decision making. We argue that the problem can be re-framed to use donor-parameter-shifts at multi-local-scale catchments above communities known to be at risk, commensurate with most of the evidence of NbS impacts being effective at the small scale (ca. 10 km²). This might lead to more effective modelling to help catchment managers prioritize those communities-at-risk where there is more evidence that NbS might be effective.     

The Sensitivity of Four Monitoring Well Sampling Systems to Low Concentrations of Three Volatile Organics

Four state-of-the-art ground water sampling systems were analyzed to determine their reliability in providing representative samples of the volatile chlorinated hydrocarbons trichloroethylene (TCE), perchloroethylene (PCE), and 1,1,1-trichloroethane (TCA) from a simulated monitoring well. The sampling systems studied represent four commonly used devices, including a stainless steel and Teflon® piston pump, a Teflon bailer, a Teflon bladder pump, and a PVC air-lift pump.
Controlled laboratory sampling experiments were conducted in a tank and well test chamber designed to approximate field conditions. A well purging and sampling procedure was used in the test apparatus to determine the accuracy and precision of each device for detecting low concentrations of the compounds in ground water. The compounds selected are some of the most ubiquitous hazardous contaminants found in shallow aquifers near hazardous waste sites throughout the United States.
No significant statistical difference was found among the four sampling systems in detecting the compounds.     

A discussion on models of thermals

For a thermal starting from rest, the scales of motion consistent with the initial conditions are given. An alternative time scale based on the motion of the thermal is derived. The anticipated similarity solutions for thermals are summarised and possible qualitative differences between solutions are given. Within this consistent framework previously published laboratory and numerical models of thermals are discussed. Reasons why numerical models have not rigorously demonstrated the existence of a self-similarity solution are considered. Comparisons of all available results show that a single similarity solution valid for all thermals does not exist.     

Identification of Mining Blasts at Mid- to Far-regional Distances Using Low Frequency Seismic Signals

—?This paper reports results from two recent monitoring experiments in Wyoming. Broadband seismic recordings of kiloton class delay-fired cast blasts and instantaneous calibration shots in the Black Thunder coal mine were made at four azimuths at ranges from 1° to 2°. The primary focus of this experiment was to observe and to explain low-frequency signals that can be seen at all azimuths and should routinely propagate above noise to mid-regional distances where most events will be recorded by International Monitoring System (IMS) stations.¶The recordings clearly demonstrate that large millisecond delay-fired cast blasts routinely produce seismic signals that have significant spectral modulations below 10?Hz. These modulations are independent of time, the azimuth from the source and the orientation of the sensor. Low-frequency modulations below 5?Hz are seen beyond 9°. The modulations are not due to resonance as they are not produced by the calibration shots. Linear elastic modeling of the blasts that is guided by mine-blast reports fails to reproduce the fine detail of these modulations but clearly indicates that the enhanced “spectral roughness” is due to long interrow delays and source finiteness. The mismatch between the data and the synthetics is likely due to source processes, such as nonlinear interactions between shots, that are poorly understood and to other effects, such as variations of shot time and yield from planned values, that are known to be omnipresent but cannot be described accurately. A variant of the Automated Time-Frequency Discriminant (Hedlin, 1998b), which uses low-frequency spectral modulations, effectively separates these events from the calibration shots.¶The experiment also provided evidence that kiloton class cast blasts consistently yield energetic 2–10 second surface waves. The surface waves are strongly dependent on azimuth but are seen beyond 9°. Physical modeling of these events indicates that the surface waves are due mainly to the extended source duration and to a lesser extent to the slap-down of spalled material. The directionality is largely a path effect. A discriminant that is based on the partitioning of energy between surface and body waves routinely separates these events from the calibration shots.¶The Powder River Basin has essentially no natural seismic activity. How these mining events compare to earthquake observations remains to be determined.     

Vulnerability of population and transportation infrastructure at the east bank of Delaware Bay due to coastal flooding in sea-level rise conditions

Catastrophic flooding associated with sea-level rise and change of hurricane patterns has put the northeastern coastal regions of the United States at a greater risk. In this paper, we predict coastal flooding at the east bank of Delaware Bay and analyze the resulting impact on residents and transportation infrastructure. The three-dimensional coastal ocean model FVCOM coupled with a two-dimensional shallow water model is used to simulate hydrodynamic flooding from coastal ocean water with fine-resolution meshes, and a topography-based hydrologic method is applied to estimate inland flooding due to precipitation. The entire flooded areas with a range of storm intensity (i.e., no storm, 10-, and 50-year storm) and sea-level rise (i.e., current, 10-, and 50-year sea level) are thus determined. The populations in the study region in 10 and 50 years are predicted using an economic-demographic model. With the aid of ArcGIS, detailed analysis of affected population and transportation systems including highway networks, railroads, and bridges is presented for all of the flood scenarios. It is concluded that sea-level rise will lead to a substantial increase in vulnerability of residents and transportation infrastructure to storm floods, and such a flood tends to affect more population in Cape May County but more transportation facilities in Cumberland County, New Jersey.