Optically stimulated luminescence dating of sublittoral and intertidal sediments from Dubai, UAE: Radioactive disequilibria in the uranium decay series

Shallow marine and intertidal shell rich sediments from the low coastal plain of Dubai were dated by optically stimulated luminescence. Combined high-resolution gamma spectrometry and ICP–MS analyses revealed significant disequilibria in the ²³⁸U decay series. Time dependent dose rates were modelled for two scenarios including a closed system and an open system with linear U and Ra uptake. OSL ages that were calculated using the linear uptake model are in good agreement with archaeological evidence and radiocarbon datings on shells and wood. The presented results illustrate that luminescence-dating techniques are suitable to set up a chronostratigraphic frame for calcareous coastal environments if an appropriate model is applied to consider the influence of radioactive disequilibria and time dependent dose rates. A comprehensive radionuclide analysis of the sediments is thought necessary to perform geochemically supported dose rate simulations.     

Traces of historical tropical cyclones and tsunamis in the Ashburton Delta (north‐west Australia)

Although the north‐western coast of Western Australia is highly vulnerable to tropical cyclones and tsunamis, little is known about the geological imprint of historic and prehistoric extreme wave events in this particular area. Despite a number of site‐specific difficulties such as post‐depositional changes and the preservation potential of event deposits, both tropical cyclones and tsunamis may be inferred from the geomorphology and the stratigraphy of beach ridge sequences, washover fans and coastal lagoons or marshes. A further challenge is the differentiation between tsunami and storm deposits in the geological record, particularly where modern deposits and/or historical reports on the event are not available. This study presents a high‐resolution sedimentary record of washover events from the Ashburton River delta (Western Australia) spanning approximately the last 150 years. A detailed characterization of event deposits is provided, and a robust chronostratigraphy for the investigated washover sequence is established based on multi‐proxy sediment analyses and optically stimulated luminescence dating. Combining sedimentological, geochemical and high‐resolution optically stimulated luminescence data, event layers are assigned to known historical events and tropical cyclone deposits are separated from tsunami deposits. For the first time, the 1883 Krakatoa and 1977 Sumba tsunamis are inferred from sedimentary records of the north‐western part of Western Australia. It is demonstrated that optically stimulated luminescence applied in coastal sedimentary archives with favourable luminescence characteristics can provide accurate chronostratigraphies even on a decadal timescale. The results contribute to the data pool of tropical cyclone and tsunami deposits in Holocene stratigraphies; however, they also demonstrate how short‐lived sediment archives may be in dynamic sedimentary environments.     

Determination of volatile concentrations in fluorapatite of Martian shergottite NWA 2975 by combining synchrotron FTIR,Raman spectroscopy,EMPA, and TEM,and inferences on the volatile budget of the apatite host‐magma

We combined the focused ion beam sample preparation technique with polarized synchrotron‐based FTIR (Fourier transform infrared) spectroscopy, laser‐Raman spectroscopy, electron microprobe analysis (EMPA), and transmission electron microscope (TEM) analysis to identify and quantify structurally bound OH, F, Cl, and CO₃ groups in fluorapatite from the Northwest Africa 2975 (NWA 2975) shergottite. In this study, the first FTIR spectra of the OH‐stretching region from a Martian apatite are presented that show characteristic OH‐bands of a F‐rich, hydroxyl‐bearing apatite. Depending on the method of apatite‐formula calculation and whether charge balance is assumed or not, the FTIR‐based quantification of the incorporated OH, expressed as wt% H₂O, is in variably good agreement with the H₂O concentration calculated from electron microprobe data. EMP analyses yielded between 0.35 and 0.54 wt% H₂O, and IR data yielded an average H₂O content of 0.31 ± 0.03 wt%, consistent with the lower range determined from EMP analyses. The TEM observations implied that the volatiles budget of fluorapatite is magmatic. The water content and the relative volatile ratios calculated for the NWA 2975 magma are similar to those established for other enriched or intermediate shergottites. It is difficult to define the source of enrichment: either Martian wet mantle or crustal assimilation. Comparing the environment of parental magma generation for NWA 2975 with the terrestrial mantle in terms of water content, it displays a composition intermediate between enriched and depleted MORB.     

Trace metal dynamics in the water column and pore waters in a temperate tidal system: response to the fate of algae-derived organic matter

Tidal and seasonal behaviour of the redox-sensitive trace metals Mn, Fe, Mo, U, and V have been investigated in the open-water column and shallow pore waters of the backbarrier tidal flats of the island of Spiekeroog (Southern North Sea) in 2002 and 2007. The purpose was to study the response of trace metal cycles on algae blooms, which are assumed to cause significant changes in the redox state of the entire ecosystem. Trace metal data were complemented by measurements of nutrients and enumeration of algae cells in 2007. Generally, Mn and V show a tidal cyclicity in the water column with maximum values during low tide which is most pronounced in summer due to elevated microbial activity in the sediments. Mo and U behave almost conservatively throughout the year with slightly increasing levels towards high tide. Exceptions are observed for both metals after summer algae blooms. Thus, the seasonal behaviour of the trace metals appear to be significantly influenced by productivity in the water column as the occurrence of algae blooms is associated with an intense release of organic matter (e.g. transparent exopolymer particles, TEP) thereby forming larger organic-rich aggregates. Along with elevated temperatures in summer, the deposition of such aggregates favours microbial activity within the surface sediments and release of DOC, nutrients and trace metals (Mn, Mo and V) during the degradation of the aggregates. Additionally, pronounced reducing conditions lead to the reduction of Mn(IV)-oxides and Fe(III)-(oxihydr)oxides, thereby releasing formerly scavenged compounds as V and phosphate. Therefore, pore-water profiles show significant enrichments in trace metals especially from July to September. Finally, the trace metals are released to the open water column via draining pore waters (esp. Mo, Mn, and V) and/or fixed in the sediment as sulphides (Fe, Mo) and bound to organic matter (U). Non-conservative behaviour of Mo in oxygenated seawater, first observed in the investigation area by Dellwig et al. (Geochim Cosmochim Acta 71:2745–2761, 2007a), was shown to be a recurrent phenomenon which is closely coupled to bacterial activity after the breakdown of algae blooms. In addition to the postulated fixation of Mo in oxygen-depleted micro-zones of the aggregates or by freshly formed organic matter, a direct removal of Mo from the water column by reduced sediment surfaces may also play an important role.     

Air ionization at rock surfaces and pre-earthquake signals

Pre-earthquake signals have been widely reported, including perturbations in the ionosphere. These precursory signals, though highly diverse, may be caused by just one underlying physical process: activation of highly mobile electronic charge carriers in rocks that are subjected to ever increasing levels of stress. The charge carriers are defect electrons associated with O^? in a matrix of O^2?. Known as positive holes or pholes h, they flow out of the stressed rock into the unstressed rock volume, traveling meters in the laboratory, probably kilometers in the field. At the rock–air interface they cause: (i) positive surface potential, (ii) field-ionization of air molecules, (iii) corona discharges. The rate of formation of airborne ions can exceed 10⁹ cm^?2 s^?1. Massive air ionization prior to major earthquakes increases the electrical conductivity in the air column and may cause ionospheric perturbations, earthquake lights, and unusual animal behavior as well as infrared emission.     

Tidal gravity variations revisited at Vostok Station, Antarctica

In 1969, prior to the discovery of the subglacial Lake Vostok, an Askania Gs-11 gravimeter was operated at Vostok Station (78.466°S, 106.832°E; 3478 m asl) to observe tidal gravity variations. To gain a better understanding of the lake's tidal dynamics, we reanalyzed these data using a Bayesian Tidal Analysis Program Grouping method (BAYTAP-G and -L programs). The obtained phase leads for the semidiurnal waves M2 (6.6 ± 2.1°) and S2 (10.1 ± 4.2°) are more pronounced than those of the diurnal waves, among which the largest phase lead (for K1) was 5.0 ± 0.5°. The obtained δ factor for M2 was 0.890 ± 0.032, significantly less than the theoretical value of 1.16. For three global ocean tide models (NAO99b, FES2004, and TPXO6.2), the estimated load tides on waves Q1, O1, P1, K1, M2, and S2 range from 0.1–0.2 μGal (Q1 and S2) to 0.6–0.7 μGal (K1). The difference in amplitude among the three models is less than 0.14 μGal (M2), and the difference in phase is generally less than 10°. In calculating the residual tide vectors using the ocean models, the TPXO6.2 model generally gave the smallest residual amplitudes. Our result for the K1 wave was anomalously large (1.36 ± 0.25 μGal), while that for the M2 wave was sufficiently small (0.37 ± 0.17 μGal). The associated uncertainty is half that reported in previous studies. It is interesting that the residual K1 tide is approximately 90° phase-leaded, while the M2 tide is approximately 180° phase-leaded (delayed). Importantly, a similar reanalysis of data collected at Asuka Station (71.5°S, 24.1°E) gave residual tides within 0.2–0.3 μGal for all major diurnal and semidiurnal waves, including the K1 wave. Therefore, the anomalous K1 residual tide observed at Vostok Station must be linked to the existence of the subglacial lake and the nature of solid–ice–water dynamics in the region.     

Crater morphology in sandstone targets: The MEMIN impact parameter study

Abstract– Hypervelocity (2.5–7.8 km s^?1) impact experiments into sandstone were carried out to investigate the influence of projectile velocity and mass, target pore space saturation, target‐projectile density contrast, and target layer orientation on crater size and shape. Crater size increases with increasing projectile velocity and mass as well as with increasing target pore space saturation. Craters in water‐saturated porous targets are generally shallower and larger in volume and in diameter than craters from equivalent impacts into dry porous sandstone. Morphometric analyses of the resultant craters, 5–40 cm in diameter, reveal features that are characteristic of all of our experimental craters regardless of impact conditions (I) a large central depression within a fragile, light‐colored central part, and (II) an outer spallation zone with areas of incipient spallation. Two different mechanical processes, grain fragmentation and intergranular tensile fracturing, are recorded within these crater morphologies. Zone (I) approximates the shape of the transient crater formed by material compression, displacement, comminution, and excavation flow, whereas (II) is the result of intergranular tensile fracturing and spallation. The transient crater dimensions are reconstructed by fitting quadric parabolas to crater profiles from digital elevation models. The dimensions of this transient and of the final crater show the same trends: both increase in volume with increasing impact energy, and with increasing water saturation of the target pore space. The relative size of the transient crater (in percent of the final crater volume) decreases with increasing projectile mass and velocity, signifying a greater contribution of spallation on the final crater size when projectile mass and velocity are increased.     

SBAS orbit and satellite clock corrections for precise point positioning

The quality of real-time GPS positions based on the method of precise point positioning (PPP) heavily depends on the availability and accuracy of GPS satellite orbits and satellite clock corrections. Satellite-based augmentation systems (SBAS) provide such corrections but they are actually intended to be used for wide area differential GPS with positioning results on the 1-m accuracy level. Nevertheless, carrier phase-based PPP is able to achieve much more accurate results with the same correction values. We applied SBAS corrections for dual-frequency PPP and compared the results with PPP obtained using other real-time correction data streams, for example, the GPS broadcast message and precise corrections from the French Centre National d’Etudes Spatiales and the German Deutsches Zentrum für Luft- und Raumfahrt. Among the three existing SBAS, the best results were achieved for the North American wide area augmentation system (WAAS): horizontal and vertical position accuracies were considerably smaller than 10 cm for static 24-h observation data sets and smaller than 30 cm for epoch-by-epoch solutions with 2 h of continuous observations. The European geostationary navigation overlay service and the Japanese multi-functional satellite augmentation system yield positioning results with biases of several tens of centimeters and variations larger by factors of 2–4 as compared to WAAS.     

The UV-optical colours of brightest cluster galaxies in optically and X-ray selected clusters

Many brightest cluster galaxies (BCGs) at the centres of X-ray selected clusters exhibit clear evidence for recent star formation. However, studies of BCGs in optically selected clusters show that star formation is not enhanced when compared to control samples of non-BCGs of similar stellar mass. Here, we analyse a sample of 113 BCGs in low-redshift  ( z < 0.1)  , optically selected clusters, a matched control sample of non-BCGs, and a smaller sample of BCGs in X-ray selected clusters. We convolve the Sloan Digital Sky Survey images of the BCGs to match the resolution of the Galaxy Evolution Explorer ( GALEX ) data and we measure UV-optical colours in their inner and outer regions. We find that optically selected BCGs exhibit smaller scatter in optical colours and redder inner  NUV − r   colours than the control galaxies, indicating that they are a homogenous population with very little ongoing star formation. The BCGs in the X-ray selected cluster sample span a similar range in optical colours, but have bluer  NUV − r   colours. Among X-ray selected BCGs, those located in clusters with central cooling times of less than 1 Gyr are significantly bluer than those located in clusters where the central gas cooling times are long. Our main conclusion is that the location of a galaxy at the centre of its halo is not sufficient to determine whether or not it is currently forming stars. One must also have information about the thermodynamic state of the gas in the core of the halo.