Earthquake chemical precursors in groundwater: a review

We review changes in groundwater chemistry as precursory signs for earthquakes. In particular, we discuss pH, total dissolved solids (TDS), electrical conductivity, and dissolved gases in relation to their significance for earthquake prediction or forecasting. These parameters are widely believed to vary in response to seismic and pre-seismic activity. However, the same parameters also vary in response to non-seismic processes. The inability to reliably distinguish between changes caused by seismic or pre-seismic activities from changes caused by non-seismic activities has impeded progress in earthquake science. Short-term earthquake prediction is unlikely to be achieved, however, by pH, TDS, electrical conductivity, and dissolved gas measurements alone. On the other hand, the production of free hydroxyl radicals (?OH), subsequent reactions such as formation of H₂O₂ and oxidation of As(III) to As(V) in groundwater, have distinctive precursory characteristics. This study deviates from the prevailing mechanical mantra. It addresses earthquake-related non-seismic mechanisms, but focused on the stress-induced electrification of rocks, the generation of positive hole charge carriers and their long-distance propagation through the rock column, plus on electrochemical processes at the rock-water interface.     

Vodyanitskii mud volcano,Sorokin trough,Black Sea: Geological characterization and quantification of gas bubble streams

Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to ∼650 mmol L⁻¹ at ∼150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at ∼60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (δD-CH₄ = −170.8‰ (SMOW), δ¹³C-CH₄ = −61.0‰ (V-PDB), δ¹³C-C₂H₆ = −44.0‰ (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 × 10⁶ mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.     

Methane in the southern North Sea: Sources, spatial distribution and budgets

Measurements of methane (CH₄) so far have always shown supersaturation in the entire North Sea relative to the atmospheric partial pressure and the distribution of surface CH₄ reveals a distinct increase towards the shore. Since North Sea sediments presumably are an insignificant source for CH₄ the coastal contribution via rivers and tidal flats gains in importance.In this work, CH₄ data from the River Weser, the back barrier tidal flats of Spiekeroog Island (NW Germany), and the German Bight are presented. Results from the River Weser are compared to other rivers draining into the German Bight. Measurements in the tidal flat area of Spiekeroog Island highlight this ecosystem as an additional contributor to the overall CH₄ budget of the southern North Sea. A tidally driven CH₄ pattern is observed for the water column with maximum values during low tide. Tidal flat sediments turn out to be the dominating source because pore waters discharged during low tide are highly enriched in CH₄. In contrast, the freshwater contribution to the tidal flats by small coastal tributaries has almost no impact on water column CH₄ concentrations. The CH₄ level seems to be disturbed irregularly by wind forcing due to elevated degassing and prevention of advective flow when tidal flats remain covered by water.Based on our data, two model calculations were used to estimate the impact of tidal flats on the CH₄ budget in the German Bight. Our results demonstrate that the back barrier tidal flats of the east Frisian Wadden Sea contribute CH₄ in an order of magnitude between the Wash estuary and River Elbe and thus have to be considered in budget calculations.     

Investigating the effect of ballasting by CaCO3 in Emiliania huxleyi: I. Formation, settling velocities and physical properties of aggregates

To investigate the role of ballasting by biogenic minerals in the export of organic matter in the ocean, a laboratory experiment was conducted comparing aggregate formation and settling velocity of non-calcifying and calcifying strains of the coccolithophore Emiliania huxleyi. Experiments were conducted by making aggregates using a roller table and following aggregate properties during incubation for a period of 40 days. Size, shape, and settling velocities of aggregates were described by image analysis of video pictures recorded during the roller tank incubation. Our results show that biogenic calcite has a strong effect on the formation rate and abundance of aggregates and on aggregate properties such as size, excess density, porosity, and settling velocity. Aggregates of calcifying cells (AGG_CAL) formed faster, were smaller and had higher settling velocities, excess densities, and mass than those of non-calcifying cells (AGG_NCAL). AGG_CAL showed no loss during the duration of the experiment, whereas AGG_NCAL decreased in size after 1 month of incubation. Potential mechanisms that can explain the different patterns in aggregate formation are discussed. Comparison of settling velocities of AGG_CAL and AGG_NCAL with aggregates formed by diatoms furthermore indicated that the ballast effect of calcite is greater than that of opal. Together these results help to better understand why calcite is of major importance for organic matter fluxes to the deep ocean.     

Abundance and size distribution of transparent exopolymer particles (TEP) in a coccolithophorid bloom in the northern Bay of Biscay

The distribution of transparent exopolymer particles (TEP) was investigated during a coccolithophorid bloom in the northern Bay of Biscay (North Atlantic Ocean) in early June 2006. MODIS chlorophyll-a (Chl-a) and reflectance images before and during the cruise were used to localize areas of important biological activity and high reflectance (HR). TEP profiles along the continental margin, determined using microscopic (TEP_micro) and colorimetric (TEP_color) methods, showed abundant (6.1×10⁶–4.4×10⁷ L^?1) and relatively small (0.5–20 μm) particles, leading to a low total volume fraction (0.05–2.2 ppm) of TEP_micro and similar vertical profiles of TEP_color. Estimates of carbon content in TEP (TEP-C) derived from the microscopic approach yielded surface concentration of 1.50 μmol C L^?1. The contribution of TEP-C to particulate organic carbon (POC) was estimated to be 12% (molar C ratio) during this survey. Our results suggest that TEP formation is a probable first step to rapid and efficient export of C during declining coccolithophorid blooms.     

The Chemical Evolution of the Universe on its Smallest Scales: Dust in Stars,Disks and Planets

D15 Dust and gas in the inner accretion disk around the Herbig star MWC 147 resolved with infrared spectro‐interferometry D21 The effective temperature of OGLE‐TR‐10 – The Balmer α line D29 Metal Injection into the Intracluster Medium D30 Eigenmodes of circumstellar dust shells D40 Numerical Modelling Approach of Circumstellar Dust Shells Around Pulsating AGB Stars Aiming at Multi Time Scale Processes D45 UV radiation induced CO molecule formation patterns in low density PDRs D46 IR properties of calcite and dolomite at low temperatures D47 Observations and Models of Dusty Giants – Past and Present D51 A multi‐method approach to the outer layers of AGB stars D53 On the convective energy transport in M‐type brown dwarf atmospheres D70 Structure and Dust Composition of the TW Hya Disc D75 Chemical Abundances in the Carina Dwarf Spheroidal Galaxy D76 Kinematic and chemical constraints on the formation of M31's inner halo structures D77 IR band profiles of silicate and oxide dust obtained by laboratory measurements of free‐flying particles D98 Dust particle growth in protoplanetary disks D134 Comparative study of dust cloud modelling for substellar atmospheres D137 Photometric study of neglected binary DV Psc D154 Quantitative Spectroscopy of Deneb D160 Hot subluminous Ostars from the SDSS D166 Simultaneous Observations of Solar Ca II H and Ca II 8662 lines and Numerical Simulation of these lines D182 Present‐day carbon abundances in the solar vicinity D189 Detection of a giant planet around a pulsating extreme horizontal branch star: the oldest known planet? D200 Confirmation of a very young binary brown dwarf candidate with disk in Chamaeleon D208 Galaxy ages and metallicities in the cluster A1314 D217 Charge‐dipole induced dust gelation – fastening the process of dust growth in protoplanetary disks D246 Protoplanetary Disk Structure and Evolution     

Mass-cargo-affine industries and climate change

The impact of low water periods on inland navigation and companies is well known by ship-operators and companies that rely on this mode of transport but it is rarely a topic of climate impact research. As climate change might affect the frequency and intensity of low water periods, quantifying the impact of climate change on companies and the effects of possible adaptation measures is vital. In this study, we present a model for quantifying the impact of low water events on companies which rely on inland navigation and apply that model to three anonymous iron and steel companies along the River Rhine. The deviation of optimal storage, the storage level that evens out risk vs. fixed capital, is used in the model to measure the vulnerability of companies. The results show that, depending on the climate scenario, the companies might have to deal with either one or five additional days of empty storage in the near future (2021–2050) and up to nine more days by the 2071–2100 period. Seasonal analysis shows that, consistent with the change in the river discharge, the biggest deviations from optimal storage level occur in the late summer/early autumn. Analysis of adaptation options shows that companies would need to increase storage capacity by 2.5 % for the 2021–2050 period, and by 25 % by the 2071–2100 period. A reduction of ship sizes is not an adaptation option for the three companies in this study, because these companies already use relatively small vessels. This is however an efficient adaptation option for companies which employ larger vessels for transport. Another adaptation option would be to reduce the share of transportation via inland waters, but the feasibility of this option depends on the availability and cost of other modes of transport.     

Sources of fluids and gases expelled at cold seeps offshore Georgia, eastern Black Sea

Four seep sites located within an ∼20 km² area offshore Georgia (Batumi seep area, Pechori Mound, Iberia Mound, and Colkheti Seep) show characteristic differences with respect to element concentrations, and oxygen, hydrogen, strontium, and chlorine isotope signatures in pore waters, as well as impregnation of sediments with petroleum and hydrocarbon potential. All seep sites have active gas seepage, near surface authigenic carbonates and gas hydrates. Cokheti Seep, Iberia Mound, and Pechori Mound are characterized by oil-stained sediments and gas seepage decoupled from deep fluid advection and bottom water intrusion induced by gas bubble release. Pechori Mound is further characterized by deep fluid advection of lower salinity pore fluids. The Pechori Mound pore fluids are altered by mineral/water reactions at elevated temperatures (between 60 and 110 °C) indicated by heavier oxygen and lighter chlorine isotope values, distinct Li and B enrichment, and K depletion. Strontium isotope ratios indicate that fluids originate from late Oligocene strata. This finding is supported by the occurrence of hydrocarbon impregnations within the sediments. Furthermore, light hydrocarbons and high molecular weight impregnates indicate a predominant thermogenic origin for the gas and oil at Pechori Mound, Iberia Mound, and Colkheti Seep. C₁₅₊ hydrocarbons at the oil seeps are allochtonous, whereas those at the Batumi seep area are autochthonous. The presence of oleanane, an angiosperm biomarker, suggests that the hydrocarbon source rocks belong to the Maikopian Formation. In summary, all investigated seep sites show a high hydrocarbon potential and hydrocarbons of Iberia Mound, Colkheti Seep, and Pechori Mound are predominantly of thermogenic origin. However, only at the latter seep site advection of deep pore fluids is indicated.