Bioremediation Management Reduces Mass Discharge at a Chlorinated DNAPL Site

Adaptive site management and aggressive bioremediation in the source zone of a complex chlorinated dense nonaqueous phase liquid (DNAPL) site reduced total chlorinated hydrocarbon mass discharge by nearly 80%. Successful anaerobic bioremediation of chlorinated hydrocarbons can be impaired by inadequate concentrations of electron donors, competing electron acceptors, specific inhibitors such as chloroform, and potentially by high contaminant concentrations associated with residual DNAPL. At the study site, the fractured bedrock aquifer was impacted by a mixture of chlorinated solvents and associated daughter products. Concentrations of 1,1,2,2‐tetrachloroethane (1,1,2,2‐TeCA), 1,1,2‐trichloroethane (1,1,2‐TCA), and 1,2‐dichloroethane (1,2‐DCA) were on the order of 100 to 1000 mg/L. Chloroform was present as a co‐contaminant and background sulfate concentrations were approximately 400 mg/L. Following propylene glycol injections, concentrations of organohalide‐respiring bacteria including Dehalococcoides and Dehalogenimonas spp. increased by two to three orders of magnitude across most of the source area. Statistical analysis indicated that reaching volatile fatty acid concentrations greater than 1000 mg/L and depleting sulfate to concentrations less than 50 mg/L were required to achieve a Dehalococcoides concentration greater than the 10⁴ cells/mL recommended for generally effective reductive dechlorination. In a limited area, chloroform concentrations greater than 5 mg/L inhibited growth of Dehalococcoides populations despite the availability of electron donor and otherwise appropriate geochemical conditions. After implementing a groundwater recirculation system targeting the inhibited area, chloroform concentrations decreased permitting significant increases in concentrations of Dehalococcoides and vinyl chloride reductase gene copies.     

Flounder growth and production as indicators of the nursery value of marsh habitats in a Mediterranean lagoon

Estuarine marshes are known as suitable nursery areas for many marine migrant fishes, such as flounder. The potential nursery value of such habitats was investigated in the Venice lagoon, by using growth and production of 0-group flounder as indicators. Size–frequency distribution analysis was performed on fish samples collected fortnightly, from March 2004 to June 2005, in two marsh sites, Dese and Tessera, differing in their origin and environmental conditions. Samples were mostly composed of juvenile individuals, belonging to 0- and 1-group cohorts (the latter being present in Tessera only). A higher total production, either annual or monthly, and faster growth of 0-group flounder was observed in Dese, associated to a higher ecological performance of 0-group individuals in this site, as indicated by the higher P:B ratio values. Dese is a site located in a marsh complex characterized by the relevant influence of a nearby river, and the observed higher potential nursery value of this marsh area with respect to the other is discussed in the light of the higher trophic status and other environmental conditions in this site. The production results were also compared to those from other estuarine environments commonly acknowledged as important nurseries for European flounder.     

Surface ozone concentrations in Agra: links with the prevailing meteorological parameters

Measurements of surface ozone (O₃), nitric oxide (NO), nitrogen dioxide (NO₂), oxides of nitrogen (NO_x=NO+NO₂) and meteorological parameters have been made at Agra (North Central India, 27°10??N, 78°05??E) in post monsoon and winter season. The diurnal variation in O₃ concentration shows daytime in situ photochemical production with diurnal maximum in noon hours ranging from 51 to 54 ppb in post monsoon and from 76 to 82 ppb in winter, while minimum (16?C24 ppb) during nighttime and early morning hours. Average 8-h O₃ concentration varied from 12.4 to 83.9 ppb. The relationship between meteorological parameters (solar radiation intensity, temperature, relative humidity, wind speed and wind direction) and surface O₃ variability was studied using principal component analysis (PCA), multiple linear regression (MLR) and correlation analysis (CA). PCA and MLR of daily mean O₃ concentrations on meteorological parameters explain up to 80 % of day to day ozone variability. Correlation with meteorology is strongly emphasized on days having strong solar radiation intensity and longer sunshine time.     

Are there social limits to adaptation to climate change?

While there is a recognised need to adapt to changing climatic conditions, there is an emerging discourse of limits to such adaptation. Limits are traditionally analysed as a set of immutable thresholds in biological, economic or technological parameters. This paper contends that limits to adaptation are endogenous to society and hence contingent on ethics, knowledge, attitudes to risk and culture. We review insights from history, sociology and psychology of risk, economics and political science to develop four propositions concerning limits to adaptation. First, any limits to adaptation depend on the ultimate goals of adaptation underpinned by diverse values. Second, adaptation need not be limited by uncertainty around future foresight of risk. Third, social and individual factors limit adaptation action. Fourth, systematic undervaluation of loss of places and culture disguises real, experienced but subjective limits to adaptation. We conclude that these issues of values and ethics, risk, knowledge and culture construct societal limits to adaptation, but that these limits are mutable.     

Understanding carbon trading: Effects of delegating CO2 responsibility on organizations’ trading behaviour

The establishment of a carbon market assumes that there is an effective means of transforming price information into technical carbon reduction measures. However, empirical evidence reveals that the links between price information and carbon management strategies are far from obvious. To understand how delegating CO₂ responsibility affects CO₂ trading behaviour, this article proposes a neo-institutionalist approach to answering the question of why companies became sellers, buyers or a combination of both during phase I of the European Emissions Trading Scheme (EU ETS). Original data from a survey on companies that participated in this scheme were collected and analysed. It was assumed that the trading scheme offered two ways to delegate decisions regarding emissions trading: decoupling from technical knowledge and financialization (i.e. delegating to financial departments) or coupling using technicalization (i.e. delegating to manufacturing departments). The results support the hypothesis that a company that adopts a decoupling strategy is more likely to buy certificates to fulfil their emissions targets. Adopting a coupling strategy indicates that a company is more likely to become a seller, all else equal. Professional identity is the theoretical basis for this relationship. Delegating carbon management to different departments represents either a stronger coupling or a stronger decoupling from core technological processes.

Policy relevance

The transaction data from phase I of the EU ETS open new questions and possibilities regarding the reasons that drive selling and buying in companies. It is important to look not only at the traditional sources of transaction costs, but rather also at the reasons for these tensions. One important source is the professional education of the people in charge of the EU ETS. Tailored information that directly addresses the different professional backgrounds of managers working in both financial departments and more technical departments might help to lower these types of transaction costs. In today's context, important emitter countries, such as China and Korea, have launched their own emissions markets, copying many aspects of the EU ETS. For the positive development of these markets and as a way of establishing a global emissions market, these new schemes should learn from the EU ETS experience.     

Distribution of butyltins in the waters and sediments along the coast of India

Water and surface sediment samples were analyzed for butyltins (TBT, DBT, MBT) from various ports along the east and west coast of India. The total butyltin (TB) in water samples varied between ∼1.7 and 342 ng Sn l⁻¹, whereas for sediments it varied between below detection limit to 14861 ng Sn g⁻¹ dry weight of sediment. On an average Chennai port recorded the highest level of butyltins in the sediments while Paradip recorded the highest level of butylins in the waters. A fairly good relationship between the TB in the sediment and overlying water samples, as well as between organic carbon and TB, implicates the importance of adsorption/desorption process in controlling the levels of TBT in these port areas. In India the data on organotin pollution is very sparse; most of the port areas have been surveyed for butyltins for the first time during this study.     

Scaling of fault attributes: A review

The present paper reviews our current understanding of fault dimensions and their scaling laws, with special focus on faults in siliciclastic rocks. The aim is to provide a comprehensive overview of recent research in order to identify strengths and challenges related to the way this topic is being addressed. We here investigate the statistical distributions of different fault attributes, e.g. fault length, displacement, damage zone width, core thickness at different scales and tectonic regimes. Biases related to sampling (resolution effect) and statistical visualization of data are discussed. The interrelationship between different faults attributes is addressed, e.g. fault displacement versus length, and fault core thickness and fault damage zone width. The results of this study show that global statistical relationships for fault attribute populations may not be valid, since the fault attributes at different scales behave differently and the compiled data on fault displacement-length exhibit breaks in the transition between faults at different scales, i.e. from small to medium scale faults at ∼1 m displacement and from medium to large scale faults at ∼1000 m displacement. This may also be the case for fault displacement-core thickness and fault displacement-damage zone width, as slight variation in the relationship can be observed between attribute populations derived from small- and medium-size faults at ∼1 m displacement. These differences may indicate the existence of characteristic length scales in fault populations, which could imply a hierarchical ordering of fault systems. The majority of data in our compiled database show no clear distinction between rocks from different lithologies and tectonic settings. Finally, the mechanical aspects of the processes of faulting with respect to the scaling relationships are discussed. Conceptual diagrams for the evolutionary processes of faulting at different scales based on the observed relationships on the plotted datasets of faults’ main attributes (fault displacement, length, core thickness and damage zone width) are proposed.     

Crystallization and welding variations in a widespread ignimbrite sheet; the Rattlesnake Tuff,eastern Oregon,USA

The 7.05 Ma Rattlesnake Tuff covers ca. 9000 km², but the reconstructed original coverage was between 30000 and 40000 km². Thicknesses are remarkably uniform, ranging between 15 and 30 m for the most complete sections. Only 13% of the area is covered with tuff thicker than 30 m, to a maximum of 70 m. The present day estimated tuff volume is 130 km³ and the reconstructed magma volume of the outflow is 280 km³ DRE (dense rock equivalent). The source area of the tuff is inferred to be in the western Harney Basin, near the center of the tuff distribution, based mainly on a radial exponential decrease in average pumice size, and is consistent with a general radial decrease in welding and degree of post-emplacement crystallization. Rheomorphic tuff is found to a radius of 40–60 km from the inferred source.Four facies of welding and four of post-emplacement crystallization are distinguishable. They are: non-welded, incipiently welded, partially welded and densely welded zones; and vapor phase, pervasively devitrified, spherulite and lithophysae zones. The vapor phase, pervasively devitrified and lithophysae zones are divided into macroscopically distinguishable subzones. At constant thickness (20±3 m), and over a distance of 1–3 km, nonrheomorphic sections can cary between two extremes: (a) entirely vitric sections grading from nonwelded to incipiently welded; and (b) highly zoned sections. Highly zoned sections have a basal non- to densely welded vitric tuff overlain by a spherulite zone that grades upward through a lithophysae-dominated zone to a zone of pervasive devitrification, which, in turn, is overlain by a zone of vapor-phase crystallization and is capped by partially welded vitric tuff. A three-dimensional welding and crystallization model has been developed based on integrating local and regional variations of 85 measured sections.Strong local variations are interpreted to be the result of threshold-governed welding and crystallization controlled by residence time above a critical temperature, which is achieved through differences in thickness and accumulation rate.