Declining Oxygen on the British Columbia Continental Shelf

The first thorough examination of oxygen concentrations in Canadian waters of the Pacific Ocean reveals several patterns in space and time. Sub-surface concentrations of oxygen tend to be lower in shelf waters than in deep-sea waters on the same isopycnal and lower in southern waters of the continental shelf than farther north. The lowest near-bottom concentration was 0.7 ml L^?1 (31 μmol kg^?1) in mid-shelf waters in summer off southwest Vancouver Island in the Juan de Fuca Eddy region. Oxygen concentration there declined at a rate of 0.019 ml L^?1 y^?1 (0.83 μmol kg^?1 y^?1) from 1979 to 2011. This decline is attributed mainly to changes in oxygen concentrations on the same density surfaces, rather than to changes in the depth of constant-density surfaces. A numerical simulation of ocean currents and nutrient concentrations in and surrounding the Juan de Fuca Eddy in summer reveals persistent upwelling into the centre of this eddy and slow bottom currents within the eddy. Upwelled water at bottom of the Juan de Fuca Eddy has water properties associated with the California Undercurrent on the 26.6 sigma-t surface at 200 m depth, where oxygen concentration is typically 2.0 ml L^?1 (87 μmol kg^?1) and declined at a rate of 0.025 ml L^?1 y^?1 (1.1 μmol kg^?1 y^?1) from 1981 to 2011, mainly as a result of changes on constant-density surfaces rather than to uplifting isopycnals. We propose that upwelling advects deep, oxygen-poor water onto the continental shelf bottom, and the slow bottom currents allow time for oxidation of organic material in bottom waters to further reduce the oxygen concentration.

RÉSUMÉ?[Traduit par la rédaction] Le premier examen approfondi des concentrations d'oxygène dans les eaux canadiennes de l'océan Pacifique révèle plusieurs configurations dans le temps et dans l'espace. Les concentrations d'oxygène sous la surface ont tendance à être plus faibles dans les eaux de la plate-forme continentale que dans les eaux de l'océan profond sur la même isopycne et plus faibles dans les eaux du sud de la plate-forme que plus loin au nord. La concentration la plus faible près du fond était de 0.7 ml L^?1 (31 μmol kg^?1) dans les eaux du milieu de la plate-forme en été au large du sud-ouest de l’île de Vancouver dans la région du remous de Juan de Fuca. Les concentrations en oxygène à cet endroit ont diminué au rythme de 0.019 ml L^?1 a^?1 (0.83 μmol kg^?1 a^?1) entre 1979 et 2011. Cette diminution est principalement attribuée aux changements dans les concentrations d'oxygène sur les surfaces d’égale densité plutôt qu'aux changements dans la profondeur des surfaces de densité constante. Une simulation numérique des courants océaniques et des concentrations de nutrients dans le remous de Juan de Fuca et dans les régions avoisinantes en été révèle des remontées d'eau froide persistantes vers le centre de ce remous et des courants de fond lents à l'intérieur du remous. L'eau qui a remonté au fond du remous de Juan de Fuca a des propriétés liées au sous-courant de Californie sur la surface sigma–t 26.6 à une profondeur de 200 m, où la concentration en oxygène est normalement de 2.0 ml L^?1 (87 μmol kg^?1), et a diminué au taux de 0.025 ml L^?1 a^?1 (1.1 μmol kg^?1 a^?1) de 1981 à 2011, principalement à cause des changements sur les surfaces de densité constante plutôt que du soulèvement des isopycnes. Nous pausons l'hypothèse que les remontées d'eau advectent des eaux profondes pauvres en oxygène au bas de la plate-forme continentale et que les lents courants de fond donnent le temps à l'oxydation de la matière organique dans les eaux de fond, ce qui réduit davantage la concentration de l'oxygène.     

Reconstruction of climatic and environmental changes in NW Romania during the early part of the last deglaciation (15,000–13,600 cal yr BP)

High resolution pollen, plant macrofossil, charcoal, mineral magnetic and sedimentary analyses, combined with AMS ¹⁴C measurements, were performed on multiple sediment sequences along a transect through the former crater lake Preluca iganului in northwestern Romania in order to reconstruct the climatic and environmental changes during the early part of the Last Termination. Lake sediments started to accumulate at 14,700 cal yr BP. Initially the upland vegetation consisted of an open forest with mainly Betula and Salix and few Pinus sp., but from 14,500 cal yr BP onwards, Pinus mugo, P. sylvestris and Populus and later on also Larix became established around the lake. Between 14,150 and 13,950 cal yr BP, Pinus cembra seems to have replaced P. mugo and P. sylvestris. At 13,950 cal yr BP the tree cover increased and Picea appeared for the first time, together with Pinus cembra, P. mugo and Larix. From 13,750 cal yr BP onwards, a Picea forest developed around the site. Based on the combined proxy data the following climatic development may be inferred: 14,700–14,500 cal yr BP, cooler and wet/humid; 14,500–14,400 cal yr BP: gradually warmer temperatures, wet/humid with dry summers; 14,400–14,320 cal yr BP: warm and dry; 14,320–14,150 cal yr BP: cooler and wet/humid; 14,150–14,100 cal yr BP: warm and dry; 14,100–13,850 cal yr BP: warmer and wet/humid; <13,850 cal yr BP: warm and dry. The tentative correlation of this development with the North Atlantic region assumes that the period >14,700 cal yr could correspond to GS-2a, the time span between 14,700 and 14,320 to GI-1e, the phase between 14,320 and 14,150 cal yr BP to GI-1d and the time frame between 14,150 and 13,600 cal yr BP to the lower part of GI-1c.     

The impact of technology availability on the timing and costs of emission reductions for achieving long-term climate targets

While most long-term mitigation scenario studies build on a broad portfolio of mitigation technologies, there is quite some uncertainty about the availability and reduction potential of these technologies. This study explores the impacts of technology limitations on greenhouse gas emission reductions using the integrated model IMAGE. It shows that the required short-term emission reductions to achieve long-term radiative forcing targets strongly depend on assumptions on the availability and potential of mitigation technologies. Limited availability of mitigation technologies which are relatively important in the long run implies that lower short-term emission levels are required. For instance, limited bio-energy availability reduces the optimal 2020 emission level by more than 4 GtCO₂eq in order to compensate the reduced availability of negative emissions from bioenergy and carbon capture and storage (BECCS) in the long run. On the other hand, reduced mitigation potential of options that are used in 2020 can also lead to a higher optimal level for 2020 emissions. The results also show the critical role of BECCS for achieving low radiative forcing targets in IMAGE. Without these technologies achieving these targets become much more expensive or even infeasible.     

Changes in water extractable organic matter during incubation of forest floor material in the presence of quartz, goethite and gibbsite surfaces

The release of dissolved organic matter (DOM) from forest floor material constitutes a significant flux of C to the mineral soil in temperate forest ecosystems, with estimates on the order of 120-500 kg C ha⁻¹ year⁻¹. Interaction of DOM with minerals and metals results in sorptive fractionation and stabilization of OM within the soil profile. Iron and aluminum oxides, in particular, have a significant effect on the quantity and quality of DOM transported through forest soils due to their high surface area and the toxic effects of dissolved aluminum on microbial communities. We directly examined these interactions by incubating forest floor material, including native microbiota, for 154 days in the presence of (1) goethite (α-FeOOH), (2) gibbsite (γ-Al(OH)₃), and (3) quartz (α-SiO₂) sand (as a control). Changes in molecular and thermal properties of water extractable organic matter (WEOM, as a proxy for DOM) were evaluated. WEOM was harvested on days 5, 10, 20, 30, 60, 90, and 154, and examined by thermogravimetry/differential thermal analysis (TG/DTA) and diffuse reflectance Fourier transform infrared (DRIFT) spectroscopy. Results indicated significant differences in WEOM quality among treatments, though the way in which oxide surfaces influenced WEOM properties did not seem to change significantly with increasing incubation time. Dissolved organic C concentrations were significantly lower in WEOM from the oxide treatments in comparison to the control treatment. Incubation with goethite produced WEOM with mid-to-high-range thermal lability that was depleted in both protein and fatty acids relative to the control. The average enthalpy of WEOM from the goethite treatment was significantly higher than either the gibbsite or control treatment, suggesting that interaction with goethite surfaces increases the energy content of WEOM. Incubation with gibbsite produced WEOM rich in thermally recalcitrant and carboxyl-rich compounds in comparison to the control treatment. These data indicate that interaction of WEOM with oxide surfaces significantly influences the composition of WEOM and that oxides play an important role in determining the biogeochemistry of forest soil DOM.     

Cyclic tensile-compressive tests on thin concrete boundary elements with a single layer of reinforcement prone to out-of-plane instability

The growing need for residential housing in Latin American countries has led to the construction of reinforced concrete buildings with wall thicknesses as low as 8–10 cm. Such walls have typically only a single layer of vertical rebars and are therefore particularly susceptible to out-of-plane failure. In order to investigate the response of the corresponding wall boundary elements, twelve reinforced concrete members with a single layer of vertical rebars were tested under tension–compression cycles. The objective was to gain insight into the parameters governing wall instability and out-of-plane failure, namely the thickness, reinforcement ratio, and eccentricity of the longitudinal rebars with respect to the member axis. This paper summarises the results of the test program, where the specimens' response is analysed also at the global and local levels. The results show that the crack pattern has an important influence on the out-of-plane behaviour and the conditions leading to out-of-plane failure are described. Furthermore, the differences between members with a single layer of vertical rebars and members with two layers are discussed. The influence of the parameters considered in the experimental program is addressed, showing that sections with small thickness and large reinforcement content are more prone to out-of-plane failures. Finally, predictions given by existing models are compared to the new experimental data. The entire data set is publicly available.     

Seasonal and interannual variability in phytoplankton and nutrient dynamics along Line P in the NE subarctic Pacific

We analysed mixed-layer seasonal and interannual variability in phytoplankton biomass and macronutrient (NO₃ and Si(OH)₄) concentrations from three decades of observations, and nitrogen uptake rates from the 1990s along Line P in the NE subarctic Pacific. Chlorophyll a concentrations near 0.35 mg m⁻³ were observed year-round along Line P except at the nearshore station (P4) where chlorophyll a concentrations in spring were on average 2.4 times the winter values. In contrast, the temporal variability in carbon-to-chlorophyll ratios at the two main end members of Line P (P4 and OSP) was high. Large seasonal and interannual variability in NO₃ and Si(OH)₄ concentration were observed along Line P. Highest upper mixed-layer (top 15 m) nutrient concentrations occurred on the continental shelf in late summer and early fall due to seasonal coastal upwelling. Beyond the shelf, maximum nutrient concentrations increased gradually offshore, and were highest in late winter and early spring due to mixing by winter storms. Interannual variations in upper mixed-layer nutrient concentrations beyond the shelf (>128°W) were correlated with E-W winds and the PDO since 1988 but were not correlated with either climate index between 1973 and 1981. Despite differences in nutrient concentration, nutrient utilization (ΔNO₃ and ΔSi(OH)₄) during the growing season were about 7.5 μM at all offshore stations. Variations in ΔNO₃ were correlated with those of ΔSi(OH)₄. The annual cycle of absolute NO₃ uptake (ρNO₃) and NH₄ uptake (ρNH₄) rates by phytoplankton in the upper mixed-layer showed a weak increasing trend from winter to spring/summer for the period 1992-1997. Rates were more variable at the nearshore station (P4). Rates of ρNO₃ were low along the entire line despite abundant NO₃ and low iron (Fe), at the offshore portion of Line P and sufficient Fe at the nearshore station (P4). As a result, new production contributed on average to only 32 ± 15% of the total nitrogen (N) uptake along Line P. NO₃ utilization in the NE subarctic Pacific is probably controlled by a combination of environmental variables, including Fe, light and ambient NH₄ levels. Elevated ambient NH₄ concentrations seem to decrease the rates of new production (and f-ratios) in surface waters of the oceanic subarctic NE Pacific. Contrary to expectation, phytoplankton biomass, nutrient utilization (ΔNO₃ and ΔSi(OH)₄), and nitrogen uptake (ρNO₃ + ρNH₄) varied relatively little along Line P, despite significant differences in the factors controlling phytoplankton composition assemblages and production. Future studies would benefit from including other variables, especially light limitation, to improve our understanding of the seasonal and interannual variability in phytoplankton biomass and nutrients in this region.     

Late Quaternary palaeoecological and palaeoclimatological reconstruction in the Gutaiului Mountains,northwest Romania

Macrofossil, pollen, lithostratigraphy, mineral magnetic measurements (SIRM and magnetic susceptibility), loss‐on‐ignition, and AMS radiocarbon dating on sediments from two former crater lakes, situated at moderate altitudes in the Gutaiului Mountains of northwest Romania, allow reconstruction of Late Quaternary climate and environment. Shrubs and herbs with steppe and montane affinities along with stands of Betula and Pinus, colonised the surroundings of the sites prior to 14 700 cal. yr BP and the inferred climatic conditions were cold and dry. The gradual transition to open Pinus–Betula forests, slightly higher lake water temperatures, and higher lake productivity, indicate more stable environmental conditions between 14 700 and 14 100 cal. yr BP. This development was interrupted by cooler and drier climatic conditions between 14 100 and 13 800 cal. yr BP, as inferred from a reduction of open forests to patches, or stands, of Pinus, Betula, Larix, Salix and Populus. The expansion of a denser boreal forest, dominated by Picea, but including Pinus, Larix, Betula, Salix, and Ulmus started at 13 800 cal. yr BP, although the forest density seems to have been reduced between 13 400 and 13 200 cal. yr BP. Air temperature and moisture availability gradually increased, but a change towards drier conditions is seen at 13 400 cal. yr BP. A distinct decrease in temperature and humidity between 12 900 and 11 500 cal. yr BP led to a return of open vegetation, with patches of Betula, Larix, Salix, Pinus and Alnus and individuals of Picea. Macrofossils and pollen of aquatic plants indicate rising lake water temperatures and increased aquatic productivity already by ca. 11 800 cal. yr BP, 300 years earlier than documented by the terrestrial plant communities. At the onset of the Holocene, 11 500 cal. yr BP, forests dominated by Betula, Pinus and Larix expanded and were followed by dense Ulmus forests with Picea, Betula and Pinus at 11 250 cal. yr BP. Larix pollen was not found, but macrofossil evidence indicates that Larix was an important forest constituent at the onset of the Holocene. Moister conditions were followed by a dry period starting about 10 600 cal. yr BP, which was more pronounced between 8600 and 8200 cal. yr BP, as inferred from aquatic macrofossils. The maximum expansion of Tilia, Quercus, Fraxinus and Acer between 10 700 and 8600 cal. yr BP may reflect a more continental climate. A drier and/or cooler climate could have been responsible for the late expansion (10 300 cal. yr BP) and late maximum (9300 cal. yr BP) of Corylus. Increased water stress, and possibly cooler conditions around 8600 cal. yr BP, may have caused a reduction of Ulmus, Tilia, Quercus and Fraxinus. After 8200 cal. yr BP moisture increased and the forests included Picea, Tilia, Quercus and Fraxinus. Copyright © 2004 John Wiley & Sons, Ltd.     

Decadal Trends in Oxygen Concentration in Subsurface Waters of the Northeast Pacific Ocean

Previous studies have shown decreasing oxygen concentration (O₂) in subsurface waters of the continental slope from California to Canada since about 1980. With longer time series we show that from southern California to northern Canada increasing O₂ preceded these decreases from 1950 to about 1980. Because there has been no clear trend since 1950, we cannot yet conclude that anthropogenic climate change is the cause of these decreasing trends after 1980. These findings are based mainly on O₂ on the 26.7 potential density (σ_θ) surface in the region north of 30°N and east of 170°W, covering both the continental margin and deep-sea regions. On the continental slope, O₂ increased at most locations by 10 to 20?µmol?kg^?1 to about 1980, followed by declines of similar magnitude in recent years. Changes in O₂ were associated with changes in temperature of the opposite sign south of 37°N, but correlation of temperature and O₂ is irregular in more northerly locations. At all locations, temperature-related solubility change was a minor cause of these O₂ trends. In deep-sea waters, O₂ decreased with time with a more rapid decrease from about 1995 to about 2003. At Ocean Station P (OSP; 50°N, 145°W), which has the longest uninterrupted record of observations, significant linear trends of ?0.4 to ?0.5?µmol?kg^?1?y^?1 were found on the 26.5, 26.7, and 26.9 σ_θ surfaces. In addition, a significant sinusoidal oscillation of period 18.61 years and amplitude of 18?µmol?kg^?1 was found on the 26.9 σ_θ surface at OSP and a station 400?km to the east, which fits reasonably well with the lunar nodal cycle. The phase of this oscillation was identical at both locations. Clear evidence of similar variability did not emerge at other open-ocean locations or along the continental slope.     

Report on the Third IGCP-649 International Workshop on the Mayarí-Baracoa Ophiolites and Chromitites, Cuba

<正>During April 3~(rd)–14~(th),the Third International Ophiolite Workshop of the International Geoscience Programme"Diamonds and Recycled Mantle"(IGCP-649)was successfully held in Havana,Cuba(Fig.1a).After the workshop,participants participated in a field trip to the Mayarí-Baracoa ophiolites and related chromitites in