Natural attenuation and bioremediation of Prestige fuel oil along the Atlantic coast of Galicia (Spain)

Heavy fuel oil spilled from the oil tanker Prestige in November 2002 affected hundreds of km of Spanish shoreline. We carried out a two year study at two highly contaminated sites in order to monitor natural attenuation of the residues coating shore rocks and to test the effectiveness of bioremediation with an oleophilic fertilizer (S200). The methodology included an innovative approach for oil load calculation (based on image analysis techniques), the analysis of the fate of hydrocarbons by means of chemical biomarkers and different microbiological techniques for isolating and examining hydrocarbon degraders.Considerable hydrocarbon depletion from shorelines (≈100% for light-medium linear alkanes and ≈35% for aromatics such as pyrene) was observed within the first months after the spill. However, this natural attenuation effect dramatically slowed down in the following year, although partial enhancement (especially for the aromatic fraction) was attained as a result of the application of S200 to stimulate indigenous microorganisms. In addition, one of the main outcomes of this work concerns the remarkable hydrocarbon depletion achieved at points where fresh water flowed through the shore rocks. The study of samples collected where this natural attenuation phenomenon took place made it possible to isolate heterotrophic bacteria and fungi that are likely to cooperate with cyanobacteria in hydrocarbon biodegradation. The overall results strongly advocate the implementation of new bioremediation approaches, including alternatives such as the use of natural fresh water to irrigate polluted areas.     

Computer simulation studies of Crystallization under confinement conditions

Crystallization under confinement conditions is a very important process in geochemistry and geophysics. Computer simulations of fluids in nanometer scale pore spaces can provide a unique microscopic insight into the structure, dynamics and forces arising from the crystallization process. We discuss in this paper molecular dynamics computer simulations of crystallization in pores of nanometer dimensions. The crystallization pressure due to the freezing of a model of Argon in a nanopore is computed using molecular dynamics simulations. We also investigate the influence of pore geometry in determining the dynamics of confined fluids, as well as mass separation in binary mixtures. It turns out that the pore geometry reveals itself as an important variable, leading to 1) new mechanisms for fast diffusion in confined spaces, and 2) accumulation of solute in specific regions inside the pore.     

Projecting land-use change processes in the Sierra Norte of Oaxaca, Mexico

The objective of study was to explore short-term trends of processes that determine land-use change in Sierra Norte of Oaxaca (SNO), Mexico. Land use and land cover changes (LULCC) were estimated in a complex mosaic of vegetation in the SNO from 1980 to 2000, and projected them to 2020 through a Markovian model. SNO is highly vulnerable to climatic change according to a 2050 GCM scenario. However, 3% annual rate of tropical and temperate forest deforestation from agriculture and livestock encroachment, suggest the threat from land-use change is higher than that from climatic change for this study site. Productive land-use strategies are needed to reduce such high deforestation rates for tropical regions. Controlling deforestation would also reduce short-term effects of CO₂ emissions to the atmosphere. Because of the necessity to evaluate anthropogenic ecosystem changes, it is imperative to separate short-term influences such as deforestation, from long-term influences such as climatic change.     

Carbon budget for a subtropical seagrass dominated coastal lagoon: How important are seagrasses to total ecosystem net primary production?

It has been assumed that because seagrasses dominate macrophyte biomass in many estuaries they also dominate primary production. We tested this assumption by developing three carbon budgets to examine the contribution of autotrophic components to the total ecosystem net primary production (TENPP) of Lower Laguna Madre, Texas. The first budget coupled average photosynthetic parameters with average daily irradiance to calculate daily production. The second budget used average photosynthetic parameters and hourly in situ irradiance to estimate productivity. The third budget integrated temperature-adjusted photosynthetic parameters (using Q₁₀=2) and hourly in situ irradiance to estimate productivity. For each budget TENPP was calculated by integrating production from each autotroph based on the producers’ areal distribution within the entire Lower Laguna Madre. All budgets indicated that macroalgae account for 33–42% of TENPP and seagrasses consistently accounted for about 33–38%. The contribution by phytoplankton was consistently about 15–20%, and the contribution from the benthic microalgae varied between 8% and 36% of TENPP, although this may have been underestimated due to our exclusion of the within bed microphytobenthos component. The water column over the seagrass beds was net heterotrophic and consequently was a carbon sink consuming between 5% and 22% of TENPP, TENPP ranged between 5.41×10¹⁰ and 2.53×10¹¹ g C yr⁻¹, depending on which budget was used. The simplest, most idealized budget predicted the highest TENPP, while the more realistic budgets predicted lower values. Annual production rates estimated using the third budget forHalodule urightii andThalassia testudinum compare well with field data. Macroalgae and microalgae contribute 50–60% of TENPP, and seagrass may be more important as three-dimensional habitat (i.e., structure) than as a source of organic carbon to the water column in Lower Laguna Madre.     

Sub-wavebase cross-bedded grainstones on a distally steepened carbonate ramp, Upper Miocene, Menorca, Spain

Cross‐bedded grainstones on carbonate ramps and shelves are commonly related to the locus of major wave energy absorption such as shorelines, shoals or shelf breaks. In contrast, on the Early Tortonian carbonate platform of Menorca (Balearic Islands), coarse‐grained, cross‐bedded grainstones are found at a distance from the palaeoshoreline where they were deposited below the wavebase. Excellent exposures along continuous outcrops on the sea cliffs of Menorca reveal the depositional profile and three‐dimensional distribution of the different facies belts of the Tortonian ramp depositional system. Basinward from the palaeoshoreline, fan deltas and beach deposits pass into 5‐km‐wide gently dipping bioturbated dolopackstone (inner and middle ramp), then into 12–20°‐dipping dolograinstone/rudstone clinobeds (ramp slope) and, finally, into subhorizontal fine‐grained basinal dolowackestone to dolopackstone (outer ramp). In this Miocene example, coarse‐grained grainstones exist in five different settings other than beach deposits: (1) on the middle ramp, where cross‐bedded grainstones were deposited by currents roughly parallel to the shoreline at 40–70 m estimated water depth and are interbedded with gently dipping bioturbated dolomitized packstones; (2) on the upper slope, where clinobeds are composed mostly of in situ rhodoliths and red‐algae fragments; (3) on the lower slope, as small‐scale bedforms (small three‐dimensional subaqueous dunes) migrating parallel to the slope; (4) at the transition between the lower slope and the outer ramp, where mollusc‐rich and rhodolithic rudstones and grainstones, interbedded in dolomitized laminated wackestones containing abundant planktonic foraminifera, infill slide/slump scars as upslope‐backstepping bodies (backsets); (5) at the toe of the slope, where coarse skeletal grainstones indicate bedform migration parallel to the platform margin, induced by currents at more than 150 m estimated water depth. This Late Miocene example also illustrates how changes in intrabasinal environmental conditions (nutrients and/or temperature) may produce changes in stratal patterns and facies architecture if they affect the biological system. Two depositional sequences compose the Miocene platform on Menorca, where a reef‐rimmed platform prograded onto an earlier distally steepened ramp. The transition from the ramp to the reef‐rimmed platform was effected by an increase in accommodation space caused by ecological changes, promoting a shift from a grain‐ to a framework‐producing biota.     

Cretaceous and Tertiary terrane accretion in the Cordillera Occidental of the Andes of Ecuador

New field, geochronological, geochemical and biostratigraphical data indicate that the central and northern parts of the Cordillera Occidental of the Andes of Ecuador comprise two terranes. The older (Pallatanga) terrane consists of an early to late (?) Cretaceous oceanic plateau suite, late Cretaceous marine turbidites derived from an unknown basaltic to andesitic volcanic source, and a tectonic mélange of probable late Cretaceous age. The younger (Macuchi) terrane consists of a volcanosedimentary island arc sequence, derived from a basaltic to andesitic source. A previously unidentified, regionally important dextral shear zone named the Chimbo-Toachi shear zone separates the two terranes. Regional evidence suggests that the Pallatanga terrane was accreted to the continental margin (the already accreted Cordillera Real) in Campanian times, producing a tectonic mélange in the suture zone. The Macuchi terrane was accreted to the Pallatanga terrane along the Chimbo-Toachi shear zone during the late Eocene, probably in a dextral shear regime. The correlation of Cretaceous rocks and accretionary events in the Cordillera Occidental of Ecuador and Colombia remains problematical, but the late Eocene event is recognised along the northern Andean margin.     

Upper Oligocene-Lower Miocene shallowing-upwardlacustrine sequences controlled by periodic and non-periodic processes(Ebro Basin, northeastern Spain)

The lacustrine facies from two sections (Candasnos and Fraga) ofthe Oligocene-Miocene Torrente de Cinca lithostratigraphic Unit in thecentral part of the Ebro Basin (Spain) have been analysed to determine theinfluence of orbital parameters in lacustrine sedimentation. The unit ispredominantly composed of limestones and marls, and represents a shallowlacustrine freshwater system. The sedimentological features of the faciesstudied demonstrate that the lower part of the Candasnos section representsoffshore lacustrine subenvironments whereas the upper part, and the whole ofthe Fraga section, characterise marginal lacustrine areas. Series of stratalthickness variations of limestone, marl, and limestone/marl couplets fromboth sections have been analysed using spectral analysis. This shows thatinformation corresponding to periodic cycles only appears in the offshorefacies, that is to say, in the lower part of Candasnos section, and disappearsin the marginal facies where non-periodic cycles exist. Furthermore, thespectral analysis of the offshore facies highlights the existence of a peak inthe power spectrum with a period of around 7 (6.8 to 7.8) that can berecognised in the field as shallowing-upward lacustrine sequences.Magnetostratigraphic data from the Candasnos section allow us to establish atime span of 2,808 years for the limestone/marl couplet from the lower partof this section, and between 19,000 and 22,000 years for the periodic cycleidentified, thus representing the climatic precession cycle. Shallowingsequences from marginal areas do not correspond with any periodiccycle.     

Comparative study of the inelastic response of base isolated buildings

This article presents a numeric comparative study of the inelastic structural response of base isolated buildings. The comparative study includes the following isolation systems: laminated rubber bearings, New Zealand one, pure friction and the frictional pendulum ones. The study is based on obtaining non‐linear response spectra for various design parameters using six earthquake records. Usually the base isolation of a new building seeks to maintain the structure in the linear elastic range. The response of old weak buildings or the response of new ones subjected to extreme earthquakes may not be, necessarily, in the aforementioned ideal elastic range. Consequently, it is important to characterize the response of isolated buildings responding inelastically. A conclusion from this research is that the isolators affect significantly the structural response of weak systems. Rubber isolators seem slightly less sensitive to plastification that may occur in the structure compared to friction isolators. Ductility demands in the structure are affected significantly by friction and neoprene protected systems, in particular sliding ones where larger demands are obtained. Copyright © 2002 John Wiley & Sons, Ltd.